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note
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The "solvent effect" in benzene may actually be the result of low concentration of free dissociated halide ions. Please see the related discussion on ligand effect.
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62
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note
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The reactions of the acetate complex 7 with acrolein in the presence of different Li salts give similar results to chloro complex 6. The data are included in Supplementary Table 1 (S-Table 1).
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37049140238
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When we attempted the reaction of acrolein with the vinyl-palladium generated by halopalladation of an alkyne in the presence of excess triphenylphosphine, no acrolein insertion product was detected. Yagupsky, G.; Mowat, W.; Shortland, A.; Wilkinson, G. J. Chem. Soc., Chem. Commun. 1970, 1369. Cross, R. J. In The Chemistry of the Metal-Carbon Bond; Hartley, F. R., Patai, S., Eds.; Wiley: Chichester, 1985; Vol. 2, p 559.
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When we attempted the reaction of acrolein with the vinyl- palladium generated by halopalladation of an alkyne in the presence of excess triphenylphosphine, no acrolein insertion product was detected. Yagupsky, G.; Mowat, W.; Shortland, A.; Wilkinson, G. J. Chem. Soc., Chem. Commun. 1970, 1369. Cross, R. J. In The Chemistry of the Metal-Carbon Bond; Hartley, F. R., Patai, S., Eds.; Wiley: Chichester, 1985; Vol. 2, p 559.
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