Chemically initiated electron exchange luminescence of silyloxyaryl-substituted spiroadamantyl dioxetanes: Kinetics and excited state yields

Photochemistry and Photobiology

Volumn 63, Issue 4, 1996, Pages 463-467

  Trofimov, Alexei V ^a,b   Mielke, Karsten ^b   Vasil'ev, Rostislav F ^a   Adam, Waldemar ^b  

^a EMANUEL INSTITUTE OF BIOCHEMICAL PHYSICS   (Russian Federation)

^b UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001611760     PISSN: 00318655     EISSN: None     Source Type: Journal    
DOI: 10.1111/j.1751-1097.1996.tb03070.x     Document Type: Article

References (16)

1. Adam, W., A. Beinhauer and H. Hauer (1989) Activation parameters and excitation yields of 1,2-dioxetane chemiluminescence. In Handbook of Organic Photochemistiy. Vol. 2 (Edited by J. C. Scaiano), pp. 271-327. CRC Press, Inc., Boca Raton, FL.
2. Koo, J.-Y. and G. B. Schuster (1977) Chemically initiated electron exchange luminescence. A new chemiluminescent reaction path for organic peroxides. J. Am. Chem. Soc. 99, 6107-6109.
3. Adam, W. and O. Cueto (1979) Fluorescer-enhanced chemiluminescence of α-peroxy lactones via electron exchange. J. Am. Chem. Soc. 101, 6511-6515.
4. Adam, W., K. Zinner, A. Krebs and H. Schmalstieg (1981) Electron exchange chemiluminescence from a sterically stabilized cyclobutadiene-1,2-dioxetane. Tetrahedron Lett. 22, 4567-4570
5. Schaap, A. P., T.-S. Chen, R. S. Handley, R. DeSilva and B. P. Gin (1987) Chemical and enzymatic triggering of 1,2-dioxetanes. 2: Fluoride-induced chemiluminescence from tert-butyldimethylsilyloxy-substituted dioxetanes. Tetrahedron Lett. 28, 1155-1158.
6. Trofimov, A. V., R. F. Vasil'ev, W. Adam and K. Mielke (1995) Energy transfer-enhanced chemiluminescence of adamantanone (n,π*) and ester (π,π*) singlet and triplet excited states in the thermolysis of silyloxyaryl-substituted spiroadamantyl dioxetanes. Photochem. Photobiol. 62, 35-43.
7. Rauhut, G., T. Clark and T Steinke (1993) A numerical selfconsistent reaction field (SCRF) model for ground and excited states in NDDO-based methods. J. Am. Chem. Soc. 115, 9174-9181.
8. Dewar, M. J. S., E. G. Zoebisch, E. F. Healy and J. J. P. Stewart (1985) AMI: a new general purpose quantum mechanical molecular model. J. Am. Chem. Soc. 107, 3902-3909.
9. Rauhut, G., J. Chandrasekhar, A. Alex, T. Steinke and T. Clark (1993) VAMP 5.0. University of Erlangen-Numberg, Germany.
10. Clark, T. (1993) Semiempirical molecular orbital theory: facts, myths and legends. In Recent Experimental and Computational Advances in Molecular Spectroscopy (Edited by R. Fausto), pp. 369-380. Kluwer Academic Publishers, Norwell, MA.
11. Schulz, M. (1993) Untersuchungen zur induzierten Elektronen-Transfer Chemilumineszenz von 1,2-Dioxetanen. Ph.D. thesis, University of Würzburg, Germany.
12. Hastings, J. W. and G. Weber (1963) Total quantum flux of isotropic sources. J. Opt. Am. Soc. 53, 1410-1415.
13. Campbell, A. K. (1988) Chemiluminescence. VCH Verlagsgemeinschaft, Weinheim.
14. Bronstein, L. R. R. Juo, J. C. Voyta and B. Edwards (1991) Novel chemiluminescent adamantyl 1,2-dioxetane enzyme substrates. In Bioluminescence and Chemiluminescence (Edited by P. E. Stanley and L. J. Kricka), pp. 74-82. John Wiley & Sons, Chichester.
15. Bronstein, I., J. C. Voyta, B. Edwards, A. Sparks and R. R. Juo (1994) Enhanced Chemiluminescence from 1,2-dioxetane enzyme substrates: membrane effects, macromolecular enhancement and structure modification. The Spectrum 7/2, 10-15.
16. Turro, N. J. (1991) Modern Molecular Photochemistry, Chapter 5. University Science Books: Mill Valley, CA.