The chemistry of higher order organocuprates

Tetrahedron

Volumn 40, Issue 24, 1984, Pages 5005-5038

  Lipshutz, Bruce H ^a   Wilhelm, Robert S ^a   Kozlowski, Joseph A ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001606689     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(01)91251-7     Document Type: Article

References (146)

1. Organocopper(I) Compounds and Organocuprates in Synthesis
2. Stoichiometric versus catalytic use of copper(I) salts in the synthetic use of main group organometallics
3. Organocuprates. II. Reaction of trialkylcuprates with saturated and unsaturated carbonyl compounds.
4. R3Cu2M species: Convenient cuprates for the conversion of 1-alkynes into 1-alkenes
5. Conjugate addition of methyl groups of ??-unsaturated aldehydes: use of Me5Cu3Li2
6. 1,2-Addition of dilithium trialkynylcuprates to ??-unsaturated cyclic ketones
7. A convenient method for the stereospecific synthesis of (E)-3-alken-1-ols utilizing the ring-opening reaction of 2,3-dihydrofuran with organocuprates.
8. Unsymmetrical cyano-cuprates as reagents in substitution and addition reactions
9. The Regiospecific Synthesis of Substituted Cyclohex-2-enols from α,β-Epoxycyclohexanones
10. A method for the regiospecific synthesis of enol triflates by enolate trapping
11. Synthesis of arenes from phenols by coupling of aryl triflates with organocopper reagents
12. Reaction of a silyl?copper reagent with acetylenes: a new synthesis of vinylsilanes
13. The silylcupration of acetylenes: a synthesis of vinylsilanes
14. Vinyl copper(I) compounds: Part II: Stereospecific addition of homocuprates to 1-alkynes in tetrahydrofuran
15. Vinyl copper(I) compounds Part I: Stereospecific addition of heterocuprates to 1-alkynes in tetrahydrofuran
16. Reaction of conjugated enones with divinylcopperlithium tri-n-butylphosphine complex. A new preparation of γ,δ-unsaturated ketones
17. A versatile synthesis of allenic hydrocarbons. Evidence for an organocopper(III) intermediate
18. Reaction of trimethyl- and triphenylstannate, (CH3)3Sn- and Ph3Sn-, with optically active 2-octyl bromide, chloride, and tosylate
19. [.beta.-(Trimethylsilyl)ethyl]lithium: a new reagent for carbonyl reductive vinylation
20. Factors governing the thermal stability of organocopper reagents. Two new classes of heterocuprates with greatly improved thermal stability
21. The Mycoticins, Polyene Macrolides fromStreptomyces ruber
22. Efficient Synthesis of (R)-(—)-g-Benzyloxymethyl-g-butyrolactone from (D)-(+)-Mannitol
23. Improved Preparation of (E)-3-Trimethylsilyl-2-Buten-1-OL
24. Nature of soluble copper(I) hydride
25. Synthesis and molecular geometry of hexameric triphenylphosphinocopper(I) hydride and the crystal structure of H6Cu6(PPh3)6. HCONMe2 [hexameric triphenylphosphino copper(I) hydride dimethylformamide]
26. A novel copper-containing hydride species and its application to the reduction of organic substances
27. Preparation of the first stable complex metal hydride of copper, LiCuH2