Catalytic Disproportionation of Hydrogen Peroxide by the Tetranuclear Manganese Complex [MnII(2-OHpicpn)]4

Inorganic Chemistry

Volumn 35, Issue 6, 1996, Pages 1419-1420

  Gelasco, Andrew ^a   Askenas, Anke ^a   Pecoraro, Vincent L ^a  

^a UNIVERSITY OF MICHIGAN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001598767     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic951035g     Document Type: Article

References (18)

1. (a) Penner-Hahn, J. E. In Manganese Redox Enzymes', Pecoraro, V. L., Ed.; VCH Publishers: New York, 1992; pp 29-45.
2. (b) Waldo, G. S.; Penner-Hahn, J. E. Submitted to Biochemistry.
3. (c) Cavalli, R. C.; Burke, C. J . Soprano, D. R.; Kawamoto, S.; Ash, D. E. Submitted to Biochemistry.
4. (d) Frasch, W. D.; Mei, R. Biochemistry 1987, 26, 7321-7325.
5. Gelasco, A.; Pecoraro, V. L. J. Am. Chem. Soc. 1993, 115, 7928-7929.
6. Larson, E. J.; Pecoraro, V. L. J. Am. Chem. Soc. 1991, 113, 7809-7810.
7. (a) Bossek, U.; Saher, M.; Weyhermuller, T.; Wieghardt, K. J. Chem. Soc., Chem. Commun. 1992, 1780-1782.
8. (b) Sakiyama, H.; Okawa, H.; Isobe, R. J. Chem. Soc., Chem. Commun. 1993, 882-884.
9. (c) Mathur, P.; Crowder, M.; Dismukes, G. C. J. Am. Chem. Soc. 1987, 109, 5227-5233.
10. (d) Pessiki, P. J.; Dismukes, G. C. J. Am. Chem. Soc. 1994, 116, 898-903.
11. Stibrany, R. T., Gorun, S. M. Angew. Chem., Int. Ed. Engl. 1990, 29, 1156-1158.
12. B/Mn.
13. w = 0.103.
14. EPR spectra were collected at 77 K. The spectrum shape was unchanged from 5 mM to 100 μM.
15. 2 and centrifuged at 25 000g for 1 h to remove all solids. An aliquot was removed and reassayed. The activities of these solutions were within 5%.
16. Gelasco, A.; Pecoraro, V. L. Manuscript in preparation.
17. Micklitz, W.; Bott, S. G.; Bentsen, J. G.; Lippard, S. J. J. Am Chem. Soc. 1989, 111, 372-374.
18. Reim, J.; Krebs, B. Angew. Chem., Int. Ed. Engl. 1994, 33, 1969-1971.