An unexpected structural principle for crystalline MgBr2· OEt2: Chains of trigonal bipyramids

Chemistry - A European Journal

Volumn 2, Issue 9, 1996, Pages 1112-1114

  Ecker, Achim ^a   Üffing, Christoph ^a   Schnöckel, Hansgeorg ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

Author keywords

Coordination; Crystal structure; Halogen compounds; Magnesium compounds; Structure elucidation

Indexed keywords

BROMINE ATOMS; COORDINATION; CRYSTALLINE FORM; MAGNESIUM BROMIDE; STRUCTURAL DETAILS; STRUCTURE ELUCIDATION; TRIGONAL BIPYRAMIDS; X-RAY TECHNIQUES;

CRYSTAL STRUCTURE; CRYSTALLINE MATERIALS; HALOGEN COMPOUNDS; MAGNESIUM; MAGNESIUM COMPOUNDS;

CHAINS;

EID: 0001597551     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.19960020912     Document Type: Article

References (26)

1. B. N. Menschutkin, Z. Anorg. Chem. 1906, 49, 207.
2. H. H. Rowley, J. Am. Chem. Soc. 1936, 58, 1337.
3. W. V. Evans, H. H. Rowley, J. Am. Chem. Soc. 1930, 52, 3523.
4. G. V. Ravich, I. F. Manucharova, Zh. Strukt. Khim. 1961, 2, 449;
5. G. V. Ravich, I. F. Manucharova, J. Struct. Chem. 1961, 2, 416.
6. J. Kress, J. Guillermet, Spectrochim. Acta 1973, 29, 1717.
7. J. Kress, L. Guibé, Can. J. Chem. 1977, 55, 1515.
8. L. Guibé, M. C. Montabonel, J. Magn. Reson. 1978, 31, 419.
9. H. Schibilla, M.-T. LeBihan, Acta Crystallogr. 1967, 23, 332.
10. Aldrich, Katalog Handbuch Feinchemikalien Deutschland 1994-1995, 1001 (22, 595-9);
11. Fluka, Chemika-Biochemika 1995/96, 960 (63057).
12. M. C. Pérucaud, M. T. LeBihan, Acta Crystallogr. Sect. B 1968, 24, 1502.
13. N. Metzler, H. Nöth, M. Schmidt, A. Treitl, Z. Naturforsch. B 1994, 49, 1448.
14. R. Sarma, F. Ramirez, B. McKeever, Y. F. Chaw, J. F. Marecek, D. Nierman, T. M. McCaffrey, J. Am. Chem. Soc. 1977, 99, 5289.
15. C. E. Hollaway, M. Melnik, J. Organomet. Chem. 1994, 465, 1.
16. K. W. Henderson, R. E. Mulvey, F. B. M. Reinhard, J. Am. Chem. Soc. 1994, 116, 10777;
17. W. Clegg, M. Frank, R. E. Mulvey, P.A. O'Neil, J. Chem. Soc. Chem. Commun. 1994, 97.
18. D. Loos, K. Eichkorn, J. Magull, R. Ahlrichs, H. Schnöckel, Z. Anorg. Allg. Chem. 1995, 621, 1582.
19. Unpublished results.
20. 3Al was isolated. The experimentally determined crystallographic cell was the same as that described in ref. [19].
21. J. J. Jerius, J. M. Hahn, A. F. M. Maqsudur Rahman, O. Mols, W. H. Ilsley, J. P. Oliver, Organometallics 1986, 5, 1812.
22. C. Dohmeier, Dissertation, LMU München, 1994.
23. P. A. Akishin, V. P. Spiridonov, G. A. Sabolev, Zh. Fiz. Khim. 1958, 31, 461;
24. Chem. Abstr. 1957, 51, 15212b.
25. Further details of the crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen (Germany), on quoting the depository numbers CSD 405147 (1) and CSD 405148 (2).
26. A. Ferrari et al., Atti Accad. Naz. Lincei Cl. Sci. Fis. Mat. Nat. Rend. 1929, 9, 1134.