"Vapochromic" Compounds as Environmental Sensors. 2. Synthesis and Near-Infrared and Infrared Spectroscopy Studies of [Pt(arylisocyanide)4][Pt(CN)4] upon Exposure to Volatile Organic Compound Vapors

Chemistry of Materials

Volumn 9, Issue 1, 1997, Pages 363-368

  Daws, Charles A ^a,b   Exstrom, Christopher L ^a,c   Sowa Jr , John R ^a,d   Mann, Kent R ^a  

^a University of Minnesota   (United States)

^b HAMLINE UNIVERSITY   (United States)

^c KENYON COLLEGE   (United States)

^d SETON HALL UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001588390     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm960397z     Document Type: Article

References (49)

1. A literature search produced several thousand references in the general area of sensors published between 1993 and 1996. See for example the description of the "Electronic Nose": (a) Persaud, K.; Dodd, G. H. Nature (London) 1982, 299, 352. (b) Shurmer, H. V. Anal. Proc. Inc. Anal. Comm. 1994, 31, 39.
2. A literature search produced several thousand references in the general area of sensors published between 1993 and 1996. See for example the description of the "Electronic Nose": (a) Persaud, K.; Dodd, G. H. Nature (London) 1982, 299, 352. (b) Shurmer, H. V. Anal. Proc. Inc. Anal. Comm. 1994, 31, 39.
3. The U.S. EPA Environmental Technology Initiative for FY 1994 includes monitoring VOCs as a critical need.
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9. 4], Magnus' green salt: (a) Magnus, G. Pogg. Ann. 1828, 11, 242. (b) Atoji, M.; Richardson, J. W.; Rundle, R. E. J. Am. Chem. Soc. 1957, 79, 3017. Also see: (c) Connely, N. G.; Crossley, J. G.; Orpen, A. G.; Salter, H. J. Chem. Soc., Chem. Commun. 1992, 1564.
10. 4], Magnus' green salt: (a) Magnus, G. Pogg. Ann. 1828, 11, 242. (b) Atoji, M.; Richardson, J. W.; Rundle, R. E. J. Am. Chem. Soc. 1957, 79, 3017. Also see: (c) Connely, N. G.; Crossley, J. G.; Orpen, A. G.; Salter, H. J. Chem. Soc., Chem. Commun. 1992, 1564.
11. 4], Magnus' green salt: (a) Magnus, G. Pogg. Ann. 1828, 11, 242. (b) Atoji, M.; Richardson, J. W.; Rundle, R. E. J. Am. Chem. Soc. 1957, 79, 3017. Also see: (c) Connely, N. G.; Crossley, J. G.; Orpen, A. G.; Salter, H. J. Chem. Soc., Chem. Commun. 1992, 1564.
12. Exstrom, C. L.; Sowa, J. R., Jr.; Daws, C. A.; Janzen, D.; Moore, G. A.; Stewart, F. F.; Mann, K. R. Chem. Mater. 1995, 7, 15.
13. Gliemann, G.; Yersin, H. Struct. Bonding 1985, 62, 87.
14. Miskowski, V. M.; Houlding, V. H. Inorg. Chem. 1991, 30, 4446.
15. 2] (phen = 1,10-phenanthroline) shifts from 537 (dry) to 575 nm.
16. Synthesis of isocyanides: (a) Ugi, I.; Meyer, R.; McKusick, B. C.; Webster, O. W. Org. Synth. 1961, 41, 101. (b) Bringmann, G.; Schneider, S. Angew. Chem., Int. Ed. Engl. 1983, 23, 139.
17. Synthesis of isocyanides: (a) Ugi, I.; Meyer, R.; McKusick, B. C.; Webster, O. W. Org. Synth. 1961, 41, 101. (b) Bringmann, G.; Schneider, S. Angew. Chem., Int. Ed. Engl. 1983, 23, 139.
18. (a) Sorensen, O. W.; Scheibye, S.; Lawesson, S.-O.; Jakobsen, H. J. Org. Magn. Reson. 1981, 16, 322.
19. (b) Rogers, M. T.; LaPlanche, L. A. J. Phys. Chem. 1965, 69, 3648.
20. (c) Fritz, H.; Kristinsson, H.; Mollenkopf, M.; Winkler, T. Magn. Reson. Chem. 1990, 28, 331.
21. (a) Nagel, C. C. U.S. Patent 4,834,909.
22. (b) Nagel, C. C. U.S. Patent 4,826,774.
23. Related compounds have also been synthesized: (c) Isci, H.; Mason, W. R. Inorg. Chetn. 1974, 13, 1175-1180. (d) Keller, H. J.; Lorenz, R. J. Organomet. Chem. 1975, 102, 119-122. (e) Keller, H. J.; Lorenz, R. Z. Naturforsch. B 1976, 31B, 565-568.
24. Related compounds have also been synthesized: (c) Isci, H.; Mason, W. R. Inorg. Chetn. 1974, 13, 1175-1180. (d) Keller, H. J.; Lorenz, R. J. Organomet. Chem. 1975, 102, 119-122. (e) Keller, H. J.; Lorenz, R. Z. Naturforsch. B 1976, 31B, 565-568.
25. Related compounds have also been synthesized: (c) Isci, H.; Mason, W. R. Inorg. Chetn. 1974, 13, 1175-1180. (d) Keller, H. J.; Lorenz, R. J. Organomet. Chem. 1975, 102, 119-122. (e) Keller, H. J.; Lorenz, R. Z. Naturforsch. B 1976, 31B, 565-568.
26. Mason, W. R.; Gray, H. B. J. Am. Chem. Soc. 1968, 90, 5721.
27. Bullock, J. P.; Mann, K. R. Inorg. Chem. 1989, 28, 4006.
28. It is commonly observed that the energy of the lowest dσ* → pσ transition decreases for elements of the third transition series; see: (a) Smith, T. P. Ph.D. Dissertation, California Institute of Technology, 1982.
29. Many minerals and simple ionic solids that contain transiton-metal ions emit in the NIR spectral region; the following references are for transition-metal complexes: (a) Yao, Q.; Maverick, A. W. Inorg. Chem. 1988, 27, 1669. (b) Reber, C.; Güdel, H. U. J. Lumin. 1988, 42, 1. (c) Massen, S.; Mialocq, J. C.; Perly, B.; Hambright, P. J. Phys. Chem. 1991, 95, 2196. (d) Bilsel, O.; Rodriguez, J.; Milam, S. N.; Gorlin, P. A.; Girolami, G. S.; Suslick, K. S.; Holten, D. J. Am. Chem. Soc. 1992, 114, 6528. (e) Stranger, R.; Moran, G.; Krausz, E.; Dubicki, L.; Güdel, H.; Furer, N. Inorg. Chem. 1992, 31, 2860. (f) Vincze, L.; Friesen, D. A.; Mezyk, S. P.; Waltz, W. L. Inorg. Chem. 1992, 31, 4950. (g) Herren, M.; Güdel, H. U. Inorg. Chem. 1992, 31, 3683. (h) Matsui, K; Nazeeruddin, M. K.; Humphrybaker, R.; Grätzel, M.; Kalyanasundaram, K. J. Phys. Chem. 1992, 96, 10587. (i) Richter, M. M.; Brewer, K. J. Inorg. Chem. 1993, 32, 5762. (j) Davis, M.; Reber, C. J. Lumin. 1994, 60, 1. (k) Juris, A.; Balzani, V.; Campagna, S.; Denti, G.; Serroni, S.; Frei, G.; Güdel, H. U. Inorg. Chem. 1994, 33, 1491. (l) Savoie, C.; Reber, C.; Belanger, S.; Beauchamp, A. L. Inorg. Chem. 1995, 34, 3851.
30. Many minerals and simple ionic solids that contain transiton-metal ions emit in the NIR spectral region; the following references are for transition-metal complexes: (a) Yao, Q.; Maverick, A. W. Inorg. Chem. 1988, 27, 1669. (b) Reber, C.; Güdel, H. U. J. Lumin. 1988, 42, 1. (c) Massen, S.; Mialocq, J. C.; Perly, B.; Hambright, P. J. Phys. Chem. 1991, 95, 2196. (d) Bilsel, O.; Rodriguez, J.; Milam, S. N.; Gorlin, P. A.; Girolami, G. S.; Suslick, K. S.; Holten, D. J. Am. Chem. Soc. 1992, 114, 6528. (e) Stranger, R.; Moran, G.; Krausz, E.; Dubicki, L.; Güdel, H.; Furer, N. Inorg. Chem. 1992, 31, 2860. (f) Vincze, L.; Friesen, D. A.; Mezyk, S. P.; Waltz, W. L. Inorg. Chem. 1992, 31, 4950. (g) Herren, M.; Güdel, H. U. Inorg. Chem. 1992, 31, 3683. (h) Matsui, K; Nazeeruddin, M. K.; Humphrybaker, R.; Grätzel, M.; Kalyanasundaram, K. J. Phys. Chem. 1992, 96, 10587. (i) Richter, M. M.; Brewer, K. J. Inorg. Chem. 1993, 32, 5762. (j) Davis, M.; Reber, C. J. Lumin. 1994, 60, 1. (k) Juris, A.; Balzani, V.; Campagna, S.; Denti, G.; Serroni, S.; Frei, G.; Güdel, H. U. Inorg. Chem. 1994, 33, 1491. (l) Savoie, C.; Reber, C.; Belanger, S.; Beauchamp, A. L. Inorg. Chem. 1995, 34, 3851.
31. Many minerals and simple ionic solids that contain transiton-metal ions emit in the NIR spectral region; the following references are for transition-metal complexes: (a) Yao, Q.; Maverick, A. W. Inorg. Chem. 1988, 27, 1669. (b) Reber, C.; Güdel, H. U. J. Lumin. 1988, 42, 1. (c) Massen, S.; Mialocq, J. C.; Perly, B.; Hambright, P. J. Phys. Chem. 1991, 95, 2196. (d) Bilsel, O.; Rodriguez, J.; Milam, S. N.; Gorlin, P. A.; Girolami, G. S.; Suslick, K. S.; Holten, D. J. Am. Chem. Soc. 1992, 114, 6528. (e) Stranger, R.; Moran, G.; Krausz, E.; Dubicki, L.; Güdel, H.; Furer, N. Inorg. Chem. 1992, 31, 2860. (f) Vincze, L.; Friesen, D. A.; Mezyk, S. P.; Waltz, W. L. Inorg. Chem. 1992, 31, 4950. (g) Herren, M.; Güdel, H. U. Inorg. Chem. 1992, 31, 3683. (h) Matsui, K; Nazeeruddin, M. K.; Humphrybaker, R.; Grätzel, M.; Kalyanasundaram, K. J. Phys. Chem. 1992, 96, 10587. (i) Richter, M. M.; Brewer, K. J. Inorg. Chem. 1993, 32, 5762. (j) Davis, M.; Reber, C. J. Lumin. 1994, 60, 1. (k) Juris, A.; Balzani, V.; Campagna, S.; Denti, G.; Serroni, S.; Frei, G.; Güdel, H. U. Inorg. Chem. 1994, 33, 1491. (l) Savoie, C.; Reber, C.; Belanger, S.; Beauchamp, A. L. Inorg. Chem. 1995, 34, 3851.
32. Many minerals and simple ionic solids that contain transiton-metal ions emit in the NIR spectral region; the following references are for transition-metal complexes: (a) Yao, Q.; Maverick, A. W. Inorg. Chem. 1988, 27, 1669. (b) Reber, C.; Güdel, H. U. J. Lumin. 1988, 42, 1. (c) Massen, S.; Mialocq, J. C.; Perly, B.; Hambright, P. J. Phys. Chem. 1991, 95, 2196. (d) Bilsel, O.; Rodriguez, J.; Milam, S. N.; Gorlin, P. A.; Girolami, G. S.; Suslick, K. S.; Holten, D. J. Am. Chem. Soc. 1992, 114, 6528. (e) Stranger, R.; Moran, G.; Krausz, E.; Dubicki, L.; Güdel, H.; Furer, N. Inorg. Chem. 1992, 31, 2860. (f) Vincze, L.; Friesen, D. A.; Mezyk, S. P.; Waltz, W. L. Inorg. Chem. 1992, 31, 4950. (g) Herren, M.; Güdel, H. U. Inorg. Chem. 1992, 31, 3683. (h) Matsui, K; Nazeeruddin, M. K.; Humphrybaker, R.; Grätzel, M.; Kalyanasundaram, K. J. Phys. Chem. 1992, 96, 10587. (i) Richter, M. M.; Brewer, K. J. Inorg. Chem. 1993, 32, 5762. (j) Davis, M.; Reber, C. J. Lumin. 1994, 60, 1. (k) Juris, A.; Balzani, V.; Campagna, S.; Denti, G.; Serroni, S.; Frei, G.; Güdel, H. U. Inorg. Chem. 1994, 33, 1491. (l) Savoie, C.; Reber, C.; Belanger, S.; Beauchamp, A. L. Inorg. Chem. 1995, 34, 3851.
33. Many minerals and simple ionic solids that contain transiton-metal ions emit in the NIR spectral region; the following references are for transition-metal complexes: (a) Yao, Q.; Maverick, A. W. Inorg. Chem. 1988, 27, 1669. (b) Reber, C.; Güdel, H. U. J. Lumin. 1988, 42, 1. (c) Massen, S.; Mialocq, J. C.; Perly, B.; Hambright, P. J. Phys. Chem. 1991, 95, 2196. (d) Bilsel, O.; Rodriguez, J.; Milam, S. N.; Gorlin, P. A.; Girolami, G. S.; Suslick, K. S.; Holten, D. J. Am. Chem. Soc. 1992, 114, 6528. (e) Stranger, R.; Moran, G.; Krausz, E.; Dubicki, L.; Güdel, H.; Furer, N. Inorg. Chem. 1992, 31, 2860. (f) Vincze, L.; Friesen, D. A.; Mezyk, S. P.; Waltz, W. L. Inorg. Chem. 1992, 31, 4950. (g) Herren, M.; Güdel, H. U. Inorg. Chem. 1992, 31, 3683. (h) Matsui, K; Nazeeruddin, M. K.; Humphrybaker, R.; Grätzel, M.; Kalyanasundaram, K. J. Phys. Chem. 1992, 96, 10587. (i) Richter, M. M.; Brewer, K. J. Inorg. Chem. 1993, 32, 5762. (j) Davis, M.; Reber, C. J. Lumin. 1994, 60, 1. (k) Juris, A.; Balzani, V.; Campagna, S.; Denti, G.; Serroni, S.; Frei, G.; Güdel, H. U. Inorg. Chem. 1994, 33, 1491. (l) Savoie, C.; Reber, C.; Belanger, S.; Beauchamp, A. L. Inorg. Chem. 1995, 34, 3851.
34. Many minerals and simple ionic solids that contain transiton-metal ions emit in the NIR spectral region; the following references are for transition-metal complexes: (a) Yao, Q.; Maverick, A. W. Inorg. Chem. 1988, 27, 1669. (b) Reber, C.; Güdel, H. U. J. Lumin. 1988, 42, 1. (c) Massen, S.; Mialocq, J. C.; Perly, B.; Hambright, P. J. Phys. Chem. 1991, 95, 2196. (d) Bilsel, O.; Rodriguez, J.; Milam, S. N.; Gorlin, P. A.; Girolami, G. S.; Suslick, K. S.; Holten, D. J. Am. Chem. Soc. 1992, 114, 6528. (e) Stranger, R.; Moran, G.; Krausz, E.; Dubicki, L.; Güdel, H.; Furer, N. Inorg. Chem. 1992, 31, 2860. (f) Vincze, L.; Friesen, D. A.; Mezyk, S. P.; Waltz, W. L. Inorg. Chem. 1992, 31, 4950. (g) Herren, M.; Güdel, H. U. Inorg. Chem. 1992, 31, 3683. (h) Matsui, K; Nazeeruddin, M. K.; Humphrybaker, R.; Grätzel, M.; Kalyanasundaram, K. J. Phys. Chem. 1992, 96, 10587. (i) Richter, M. M.; Brewer, K. J. Inorg. Chem. 1993, 32, 5762. (j) Davis, M.; Reber, C. J. Lumin. 1994, 60, 1. (k) Juris, A.; Balzani, V.; Campagna, S.; Denti, G.; Serroni, S.; Frei, G.; Güdel, H. U. Inorg. Chem. 1994, 33, 1491. (l) Savoie, C.; Reber, C.; Belanger, S.; Beauchamp, A. L. Inorg. Chem. 1995, 34, 3851.
35. Many minerals and simple ionic solids that contain transiton-metal ions emit in the NIR spectral region; the following references are for transition-metal complexes: (a) Yao, Q.; Maverick, A. W. Inorg. Chem. 1988, 27, 1669. (b) Reber, C.; Güdel, H. U. J. Lumin. 1988, 42, 1. (c) Massen, S.; Mialocq, J. C.; Perly, B.; Hambright, P. J. Phys. Chem. 1991, 95, 2196. (d) Bilsel, O.; Rodriguez, J.; Milam, S. N.; Gorlin, P. A.; Girolami, G. S.; Suslick, K. S.; Holten, D. J. Am. Chem. Soc. 1992, 114, 6528. (e) Stranger, R.; Moran, G.; Krausz, E.; Dubicki, L.; Güdel, H.; Furer, N. Inorg. Chem. 1992, 31, 2860. (f) Vincze, L.; Friesen, D. A.; Mezyk, S. P.; Waltz, W. L. Inorg. Chem. 1992, 31, 4950. (g) Herren, M.; Güdel, H. U. Inorg. Chem. 1992, 31, 3683. (h) Matsui, K; Nazeeruddin, M. K.; Humphrybaker, R.; Grätzel, M.; Kalyanasundaram, K. J. Phys. Chem. 1992, 96, 10587. (i) Richter, M. M.; Brewer, K. J. Inorg. Chem. 1993, 32, 5762. (j) Davis, M.; Reber, C. J. Lumin. 1994, 60, 1. (k) Juris, A.; Balzani, V.; Campagna, S.; Denti, G.; Serroni, S.; Frei, G.; Güdel, H. U. Inorg. Chem. 1994, 33, 1491. (l) Savoie, C.; Reber, C.; Belanger, S.; Beauchamp, A. L. Inorg. Chem. 1995, 34, 3851.
36. Many minerals and simple ionic solids that contain transiton-metal ions emit in the NIR spectral region; the following references are for transition-metal complexes: (a) Yao, Q.; Maverick, A. W. Inorg. Chem. 1988, 27, 1669. (b) Reber, C.; Güdel, H. U. J. Lumin. 1988, 42, 1. (c) Massen, S.; Mialocq, J. C.; Perly, B.; Hambright, P. J. Phys. Chem. 1991, 95, 2196. (d) Bilsel, O.; Rodriguez, J.; Milam, S. N.; Gorlin, P. A.; Girolami, G. S.; Suslick, K. S.; Holten, D. J. Am. Chem. Soc. 1992, 114, 6528. (e) Stranger, R.; Moran, G.; Krausz, E.; Dubicki, L.; Güdel, H.; Furer, N. Inorg. Chem. 1992, 31, 2860. (f) Vincze, L.; Friesen, D. A.; Mezyk, S. P.; Waltz, W. L. Inorg. Chem. 1992, 31, 4950. (g) Herren, M.; Güdel, H. U. Inorg. Chem. 1992, 31, 3683. (h) Matsui, K; Nazeeruddin, M. K.; Humphrybaker, R.; Grätzel, M.; Kalyanasundaram, K. J. Phys. Chem. 1992, 96, 10587. (i) Richter, M. M.; Brewer, K. J. Inorg. Chem. 1993, 32, 5762. (j) Davis, M.; Reber, C. J. Lumin. 1994, 60, 1. (k) Juris, A.; Balzani, V.; Campagna, S.; Denti, G.; Serroni, S.; Frei, G.; Güdel, H. U. Inorg. Chem. 1994, 33, 1491. (l) Savoie, C.; Reber, C.; Belanger, S.; Beauchamp, A. L. Inorg. Chem. 1995, 34, 3851.
37. Many minerals and simple ionic solids that contain transiton-metal ions emit in the NIR spectral region; the following references are for transition-metal complexes: (a) Yao, Q.; Maverick, A. W. Inorg. Chem. 1988, 27, 1669. (b) Reber, C.; Güdel, H. U. J. Lumin. 1988, 42, 1. (c) Massen, S.; Mialocq, J. C.; Perly, B.; Hambright, P. J. Phys. Chem. 1991, 95, 2196. (d) Bilsel, O.; Rodriguez, J.; Milam, S. N.; Gorlin, P. A.; Girolami, G. S.; Suslick, K. S.; Holten, D. J. Am. Chem. Soc. 1992, 114, 6528. (e) Stranger, R.; Moran, G.; Krausz, E.; Dubicki, L.; Güdel, H.; Furer, N. Inorg. Chem. 1992, 31, 2860. (f) Vincze, L.; Friesen, D. A.; Mezyk, S. P.; Waltz, W. L. Inorg. Chem. 1992, 31, 4950. (g) Herren, M.; Güdel, H. U. Inorg. Chem. 1992, 31, 3683. (h) Matsui, K; Nazeeruddin, M. K.; Humphrybaker, R.; Grätzel, M.; Kalyanasundaram, K. J. Phys. Chem. 1992, 96, 10587. (i) Richter, M. M.; Brewer, K. J. Inorg. Chem. 1993, 32, 5762. (j) Davis, M.; Reber, C. J. Lumin. 1994, 60, 1. (k) Juris, A.; Balzani, V.; Campagna, S.; Denti, G.; Serroni, S.; Frei, G.; Güdel, H. U. Inorg. Chem. 1994, 33, 1491. (l) Savoie, C.; Reber, C.; Belanger, S.; Beauchamp, A. L. Inorg. Chem. 1995, 34, 3851.
38. Many minerals and simple ionic solids that contain transiton-metal ions emit in the NIR spectral region; the following references are for transition-metal complexes: (a) Yao, Q.; Maverick, A. W. Inorg. Chem. 1988, 27, 1669. (b) Reber, C.; Güdel, H. U. J. Lumin. 1988, 42, 1. (c) Massen, S.; Mialocq, J. C.; Perly, B.; Hambright, P. J. Phys. Chem. 1991, 95, 2196. (d) Bilsel, O.; Rodriguez, J.; Milam, S. N.; Gorlin, P. A.; Girolami, G. S.; Suslick, K. S.; Holten, D. J. Am. Chem. Soc. 1992, 114, 6528. (e) Stranger, R.; Moran, G.; Krausz, E.; Dubicki, L.; Güdel, H.; Furer, N. Inorg. Chem. 1992, 31, 2860. (f) Vincze, L.; Friesen, D. A.; Mezyk, S. P.; Waltz, W. L. Inorg. Chem. 1992, 31, 4950. (g) Herren, M.; Güdel, H. U. Inorg. Chem. 1992, 31, 3683. (h) Matsui, K; Nazeeruddin, M. K.; Humphrybaker, R.; Grätzel, M.; Kalyanasundaram, K. J. Phys. Chem. 1992, 96, 10587. (i) Richter, M. M.; Brewer, K. J. Inorg. Chem. 1993, 32, 5762. (j) Davis, M.; Reber, C. J. Lumin. 1994, 60, 1. (k) Juris, A.; Balzani, V.; Campagna, S.; Denti, G.; Serroni, S.; Frei, G.; Güdel, H. U. Inorg. Chem. 1994, 33, 1491. (l) Savoie, C.; Reber, C.; Belanger, S.; Beauchamp, A. L. Inorg. Chem. 1995, 34, 3851.
39. Many minerals and simple ionic solids that contain transiton-metal ions emit in the NIR spectral region; the following references are for transition-metal complexes: (a) Yao, Q.; Maverick, A. W. Inorg. Chem. 1988, 27, 1669. (b) Reber, C.; Güdel, H. U. J. Lumin. 1988, 42, 1. (c) Massen, S.; Mialocq, J. C.; Perly, B.; Hambright, P. J. Phys. Chem. 1991, 95, 2196. (d) Bilsel, O.; Rodriguez, J.; Milam, S. N.; Gorlin, P. A.; Girolami, G. S.; Suslick, K. S.; Holten, D. J. Am. Chem. Soc. 1992, 114, 6528. (e) Stranger, R.; Moran, G.; Krausz, E.; Dubicki, L.; Güdel, H.; Furer, N. Inorg. Chem. 1992, 31, 2860. (f) Vincze, L.; Friesen, D. A.; Mezyk, S. P.; Waltz, W. L. Inorg. Chem. 1992, 31, 4950. (g) Herren, M.; Güdel, H. U. Inorg. Chem. 1992, 31, 3683. (h) Matsui, K; Nazeeruddin, M. K.; Humphrybaker, R.; Grätzel, M.; Kalyanasundaram, K. J. Phys. Chem. 1992, 96, 10587. (i) Richter, M. M.; Brewer, K. J. Inorg. Chem. 1993, 32, 5762. (j) Davis, M.; Reber, C. J. Lumin. 1994, 60, 1. (k) Juris, A.; Balzani, V.; Campagna, S.; Denti, G.; Serroni, S.; Frei, G.; Güdel, H. U. Inorg. Chem. 1994, 33, 1491. (l) Savoie, C.; Reber, C.; Belanger, S.; Beauchamp, A. L. Inorg. Chem. 1995, 34, 3851.
40. Many minerals and simple ionic solids that contain transiton-metal ions emit in the NIR spectral region; the following references are for transition-metal complexes: (a) Yao, Q.; Maverick, A. W. Inorg. Chem. 1988, 27, 1669. (b) Reber, C.; Güdel, H. U. J. Lumin. 1988, 42, 1. (c) Massen, S.; Mialocq, J. C.; Perly, B.; Hambright, P. J. Phys. Chem. 1991, 95, 2196. (d) Bilsel, O.; Rodriguez, J.; Milam, S. N.; Gorlin, P. A.; Girolami, G. S.; Suslick, K. S.; Holten, D. J. Am. Chem. Soc. 1992, 114, 6528. (e) Stranger, R.; Moran, G.; Krausz, E.; Dubicki, L.; Güdel, H.; Furer, N. Inorg. Chem. 1992, 31, 2860. (f) Vincze, L.; Friesen, D. A.; Mezyk, S. P.; Waltz, W. L. Inorg. Chem. 1992, 31, 4950. (g) Herren, M.; Güdel, H. U. Inorg. Chem. 1992, 31, 3683. (h) Matsui, K; Nazeeruddin, M. K.; Humphrybaker, R.; Grätzel, M.; Kalyanasundaram, K. J. Phys. Chem. 1992, 96, 10587. (i) Richter, M. M.; Brewer, K. J. Inorg. Chem. 1993, 32, 5762. (j) Davis, M.; Reber, C. J. Lumin. 1994, 60, 1. (k) Juris, A.; Balzani, V.; Campagna, S.; Denti, G.; Serroni, S.; Frei, G.; Güdel, H. U. Inorg. Chem. 1994, 33, 1491. (l) Savoie, C.; Reber, C.; Belanger, S.; Beauchamp, A. L. Inorg. Chem. 1995, 34, 3851.
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