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An efficient carbonylative coupling of 1,2-disubstituted imidazoles with alkenes catalyzed by a ruthenium species has recently been reported, in which initial C-H bond activation at the 4-position of the imidazoles seems to take place selectively and the site is acylated: N. Chatani, T. Fukuyama, F. Kakiuchi, and S. Murai, J. Am. Chem. Soc., 118, 493 (1996).
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