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Catalysis of photochemical reactions has been reviewed; see: G.G. Wubbels, Acc. Chem. Res. 16, 285 (1983). Species which enhance the reactivity of photocatalysts may be called "co- catalysts" of photocatalysts; see: S. Fukuzumi and S. Itoh, Advances in Photochemistry, D.C. Neckers, D.H. Volma, G. von Bünau (Eds.), John Wiley, Vol. 25, 1999, in press.
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22
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Protonated flavins have also been used for the photosensitized monomerization of the cis-cisoid cyclobutane dimer of 1,3-dimethylthymine; see: C. Pac, K. Miyake, Y. Masaki, S. Yanagida, T. Ohno, and A. Yoshimura, J. Am. Chem. Soc. 114, 10756 (1992).
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85034547937
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note
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The amount of hydrogen peroxide becomes smaller than that of benzaldehyde at longer irradiation time, probably because of the photodecomposition of hydrogen peroxide.
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33
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0029903531
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The ab initio MO calculations indicate that N(1) is the site of protonation of flavin; see: Y.-J. Zheng and R.L. Ornstein, J. Am. Chem. Soc. 118, 9402 (1996).
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Whether the substituents Cl- and Br- are electron-withdrawing or -donating are sensitive to the system; see: S. Fukuzumi and J.K. Kochi, J. Am. Chem. Soc. 103, 7240 (1981).
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85034554449
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45
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53
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(a) S. Fukuzumi, K. Hironaka, N. Nishizawa, and T. Tanaka, Bull. Chem. Soc. Jpn. 56, 2220 (1983).
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58
-
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85034538351
-
-
note
-
4, no fluorescence of flavin analogues (Fl, dFl and RFl) has been observed.
-
-
-
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59
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0011705801
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(a) R. Traber, E. Volgelmann, S. Schreiner, T. Werner, and H.E.A. Kramer, Photochem. Photobiol. 33, 41 (1981).
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64
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37049098065
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+); see P.F. Heelis, B.J. Parsons, B. Thomas, and G.O. Phillips, J. Chem. Soc., Chem. Commun. 954 (1985).
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67
-
-
85034532049
-
-
note
-
•) may be disregarded since it is difficult to explain the selective photocatalytic oxidation (as observed in Figure 9) by such a radical chain mechanism.
-
-
-
-
68
-
-
85034531960
-
-
note
-
2+ complex by a benzyl alcohol derivative has been reported (Ref. 6).
-
-
-
-
69
-
-
0016662393
-
-
+ is taken as 29 μs, which is assumed to be the same as that of a protonated lumiflavin triplet state; see S. Schreiner, U. Steiner, and H.E.A. Kramer, Photochem. Photobiol. 21, 81 (1975).
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73
-
-
85034535487
-
-
note
-
•) is involved in the reactants or products (see Ref. 26a).
-
-
-
-
74
-
-
85034537436
-
-
note
-
+ (0.19 V, reported in Ref. 32a).
-
-
-
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79
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0000007016
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(b) D.-H. Chin, G. Chiericato, Jr., E.J. Nanni, Jr., and D.T. Sawyer, J. Am. Chem. Soc. 104, 1296 (1982).
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86
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