Water-in-carbon dioxide microemulsions: An environment for hydrophiles including proteins

Science

Volumn 271, Issue 5249, 1996, Pages 624-626

  Johnston, K P ^a   Harrison, K L ^a   Clarke, M J ^b   Howdle, S M ^b   Heitz, M P ^c   Bright, F V ^c   Carlier, C ^d   Randolph, T W ^d  

^a The University of Texas at Austin   (United States)

^b UNIVERSITY OF NOTTINGHAM   (United Kingdom)

^c UNIVERSITY AT BUFFALO   (United States)

^d UCB 450   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BOVINAE;

EID: 0001561769     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.271.5249.624     Document Type: Article

References (24)

1. J. M DeSimone, Z. Guan, C S. Eisbernd, Science 257, 945 (1992).
2. J M. DeSimone et al., ibid. 265, 356 (1994).
3. F. A. Adamsky and E J, Beckman, Macromolecules 27, 312 (1994).
4. D. J. Dixon, R. A. Bodmeier, K. P. Johnston, AlChE J. 39, 127 (1993)
5. P. G. Jessop, T. Ikariya, R. Noyori, Nature 368, 231 (1994).
6. K. A. Consani and R. D. Smith, J. Supercrit. Fluids 3, 51 (1990).
7. A Iezzi, R. Enick, J Brady, ACS Symp. Ser 406, 122 (1989).
8. E. W. Kaler, J. F. Billman, J. Fulton, R. D. Smith, J. Phys. Chem 95, 458 (1991).
9. D. G. Peck and K. P. Johnston, ibid., p 9549.
10. G. J. McFann and K. P Johnston, ibid., p 4889.
11. T. A. Hoefling, R. M. Enick, E. J. Beckman, ibid., p. 7127
12. O. A. ElSeoud, A. M. Chinelatto, M. R. Shimizu, J. Colloid Interface Sci. 88, 420 (1982).
13. K Harrison, J. Goveas, K. P. Johnston, E. A. O'Rear, Langmuir 10, 3536 (1994)
14. A. Chittofrati et al., Progr. Colloid Polym. Sci. 79, 218 (1989).
15. D A. Newman, T. A. Hoefling, R. R. Beitle, E. J. Beckman, R. M. Enick, J. Supercnt. Fluids 6, 205 (1993).
16. G. Onori and A. Santucci, J. Phys. Chem. 97, 5430 (1993).
17. -1 resolution).
18. M D. Garrison, D. J Iuliano, S S. Saavedra, G. A Truskey, W. M. Reichert, J. Colloid Interface Sci. 148, 415 (1992).
19. R. Wang, S. Sun, E. J Bekos, F. V. Bright, Anal. Chem. 67, 149 (1995).
20. 2
21. J. S. Lundgren, M. P. Heitz, F. V. Bright, Anal. Chem. 67, 3775 (1995).
22. o is somewhat less than that in liquid water (21).
23. The molar ratio of water to 4-hydroxy-TEMPO was -1700:1. Spectra were recorded in a high-pressure . recirculating cell [T. W. Randolph and C Carlier, J. Phys. Chem. 96, 5146 (1992)] at a microwave power of 10 mW, modulation frequency of 100 kHz, and a 10-G modulation amplitude.
24. We gratefully acknowledge financial support from NSF (K.P.J. and TW.R.), the U.S. Environmental Protection Agency (K.P.J.), the U.S Department of Energy (F.V.B.), the Royal Society of Chemistry (S.M.H.), the Separations Research Program at the University of Texas (K P.J.), and Unilever Research (K.P.J.). We thank A. Chittofrati for supplying the PFPE surfactant.