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For [2 + 2 + 2] cycloaddition of acetylene with norbornene, see: (a) Suzuki, H.; Itoh, K.; Ishii, Y.; Simon, K.; Ibers, J. A. J. Am. Chem. Soc. 1976, 98, 8494. (b) Brown, L. D.; Itoh, K.; Suzuki, H.; Hirai, K.; Ibers, J. A. J. Am. Chem. Soc. 1978, 100, 8232.
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85034279413
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note
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The lower yield of 3e may be ascribable to its thermal unstability. The isolated 3e slowly decomposed even at -15 °C.
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