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LP polymerize (above or below some critical temperature) starting from an imposed density of initiators by reversible addition of monomers on active chain ends. They are held together by (strong) covalent carbon-to-carbon bonds, hence, they do not break in the middle of the polymer chain. Neither do LP combine together to make larger LP or to form rings. For a recent review see S. C. Greer, Adv. Chem. Phys. 96, 261 (1996).
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47
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22244485450
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note
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This is rather unfortunate the relaxation times being much faster using the full 108 bonds available and no difference having been observed in the static properties where the (extremely unlikely) crossed bonds do not contribute. However, the rare event of fixed monomers (in the limit of high barrier B where crossed bonds cannot be broken sufficiently fast) changes completely the dynamic properties from Rouse to Reptation behavior (due to the view artificial fixed obstacles) as obvious from the mean-square displacement (Ref. 32). We are indebted to Y. Rouault and M. Müller for pointing our attention on this technical difficulty related to the lattice nature of the underlying BFM.
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