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Volumn 37, Issue 26, 1998, Pages 6690-6697

Lanthanide(III) Complexes of Tripodal N-Donor Ligands: Structural Models for the Species Involved in Solvent Extraction of Actinides(III)

Author keywords

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Indexed keywords


EID: 0001544333     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic980192n     Document Type: Article
Times cited : (97)

References (53)
  • 20
    • 0003722465 scopus 로고
    • Gschneidner, K. A., Jr., Eyring, L., Choppin, G. R., Lander, G. H. Eds.; Elsevier Science B. V.: Amsterdam
    • Nash, K. L. In Handbook on the Physics and Chemistry of Rare Earths; Gschneidner, K. A., Jr., Eyring, L., Choppin, G. R., Lander, G. H. Eds.; Elsevier Science B. V.: Amsterdam, 1994; Vol. 18.
    • (1994) Handbook on the Physics and Chemistry of Rare Earths , vol.18
    • Nash, K.L.1
  • 21
    • 70350316040 scopus 로고
    • Gschneidner, K. A., Jr., Eyring, L., Choppin, G. R., Lander, G. H., Eds.; Elsevier Science B.V.: Amsterdam
    • Rizkalla, E. N.; Choppin, G. R. In Handbook on the Physics and Chemistry of Rare Earths; Gschneidner, K. A., Jr., Eyring, L., Choppin, G. R., Lander, G. H., Eds.; Elsevier Science B.V.: Amsterdam. 1994; Vol. 18.
    • (1994) Handbook on the Physics and Chemistry of Rare Earths , vol.18
    • Rizkalla, E.N.1    Choppin, G.R.2
  • 22
    • 1842660667 scopus 로고
    • Proceedings of the International Symposium., Honolulu, HI. December 16-22, Choppin, G. R., Navratil, J. D., Schulz, W. W., Eds.; World Scientific: Singapore
    • Musikas, C. In Actinide - Lanthanide Separation; Proceedings of the International Symposium., Honolulu, HI. December 16-22, 1984; Choppin, G. R., Navratil, J. D., Schulz, W. W., Eds.; World Scientific: Singapore, 1985.
    • (1984) Actinide - Lanthanide Separation
    • Musikas, C.1
  • 39
    • 0004150157 scopus 로고
    • Sheldrick, G. M., Ed.; University of Göttingen: Germany
    • Sheldrick, G. M. SHELXTL-Plus, 5th ed.; Sheldrick, G. M., Ed.; University of Göttingen: Germany, 1994.
    • (1994) SHELXTL-Plus, 5th Ed.
    • Sheldrick, G.M.1
  • 40
    • 1842761250 scopus 로고    scopus 로고
    • note
    • The structures of the Pr, Sm, and Yb complexes of tpa were also determined by X-ray crystallography. The Yb complex has the same structure as Eu, Tb, and Lu. The Pr and Sm complexes have the same metal environment as Nd.
  • 53
    • 1842761252 scopus 로고    scopus 로고
    • unpublished results
    • Density functional calculations show the presence of a smaller electron density on the pyrazine nitrogen than on the pyridine nitrogen. They also indicate that tpza has a stronger π-acceptor character than tpa (Maldivi, P., unpublished results).
    • Maldivi, P.1


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