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note
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The structures of the Pr, Sm, and Yb complexes of tpa were also determined by X-ray crystallography. The Yb complex has the same structure as Eu, Tb, and Lu. The Pr and Sm complexes have the same metal environment as Nd.
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1842761252
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unpublished results
-
Density functional calculations show the presence of a smaller electron density on the pyrazine nitrogen than on the pyridine nitrogen. They also indicate that tpza has a stronger π-acceptor character than tpa (Maldivi, P., unpublished results).
-
-
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Maldivi, P.1
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