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Tetrahedron Letters
Volumn 25, Issue 46, 1984, Pages 5319-5322
A new synthesis of allylic alcohols or their derivatives via reductive elimination from γ-phenylthio-β-nitroalcohols with tributyltinhydride
Author keywords

[No Author keywords available]
Indexed keywords

EID: 0001542311     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(01)81593-8     Document Type: Article
Times cited : (31)
References (11)
  • 1
    • 33846686268 scopus 로고
    • Free radical chain elimination reaction (ERC1). Conversion of vicinal dinitro compounds or .BETA.-nitro sulfones to olefins with tributyltin hydride.
    • β-Nitro sulfones and vicinal dinitro compounds undergo similar radical elimination on treatment with tin radicals.
    • (1981) Chemistry Letters , pp. 1139
    • Ono1    Miyake2    Tamurad3    Kaji4
  • 7
    • 85065130803 scopus 로고
    • Stereoselective Synthesis of Trisubstituted Olefins
    • The structure of β-nitro sulfones was determined by X-ray analysis, and the structure of olefins was determined by NMR., It turns out that trans-elimination is favored over cis-elimination. So E-rich olefins may be produced from diasteromer A. Details of the stereochemisty of the present reaction will be published elsewhere.
    • (1971) Synthesis , pp. 175
    • Faulker1
  • 8
    • 84918427491 scopus 로고    scopus 로고
    • 1, As thiophenoxy radicals are better leaving groups than phenylsulfonyl radicals, higher specificity will be expected in the elimination of β-nitro sulfides if the reaction proceeds via β-phenylthio radicals.
  • 11
    • 84918427490 scopus 로고    scopus 로고
    • One of possible routes is presented here.

* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.