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Volumn 32, Issue 4, 1993, Pages 394-399

Picosecond Excited-State Dynamics in Octahedral Cobalt(III) Complexes: Intersystem Crossing versus Internal Conversion

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EID: 0001533472     PISSN: 00201669     EISSN: 1520510X     Source Type: Journal    
DOI: 10.1021/ic00056a010     Document Type: Article
Times cited : (21)

References (34)
  • 9
    • 33845374324 scopus 로고
    • For a review of some of these reactions, see
    • For a review of some of these reactions, see: Balzani, V.; Sabbatini, N.; Scandola, F. Chem. Rev. 1986, 86, 319.
    • (1986) Chem. Rev. , vol.86 , pp. 319
    • Balzani, V.1    Sabbatini, N.2    Scandola, F.3
  • 26
    • 85022495456 scopus 로고
    • The excited-state features for this compound were also examined by singular-valued decomposition (SVD). This matrix method of processing data generates a basis set of trial spectra, temporal profiles, and eigenvalues (weighting factors) to reconstruct kinetic data. It is useful in identifying hidden spectral features which may be overlooked in doing the more conventional, single-wavelength kinetic trace. SVD analysis showed that all of the temporal characteristics of the transient decay, i.e., the biphasic nature of the decay, is accounted for by the single absorption spectrum. For more on SVD, see, Ph.D. Dissertation, University of California, San Diego
    • The excited-state features for this compound were also examined by singular-valued decomposition (SVD). This matrix method of processing data generates a basis set of trial spectra, temporal profiles, and eigenvalues (weighting factors) to reconstruct kinetic data. It is useful in identifying hidden spectral features which may be overlooked in doing the more conventional, single-wavelength kinetic trace. SVD analysis showed that all of the temporal characteristics of the transient decay, i.e., the biphasic nature of the decay, is accounted for by the single absorption spectrum. For more on SVD, see: Walda, K. Ph.D. Dissertation, University of California, San Diego, 1992.
    • (1992)
    • Walda, K.1
  • 27
    • 0009320394 scopus 로고
    • 1, since the commonly employed assumption that C = 4B is not very accurate. See
    • 1, since the commonly employed assumption that C = 4B is not very accurate. See: Hauser, A. J. Chem. Phys. 1991, 94, 2741.
    • (1991) J. Chem. Phys. , vol.94 , pp. 2741
    • Hauser, A.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.