Activation of small alkanes on strong solid acids: Mechanistic approaches

Catalysis Today

Volumn 38, Issue 3, 1997, Pages 309-319

  Sommer, Jean ^a   Jost, Roland ^a   Hachoumy, Mohammed ^a  

^a UNIVERSITÉ DE STRASBOURG   (France)

Author keywords

H D exchange; Small alkane transformation; Superacidity

Indexed keywords

EID: 0001531817     PISSN: 09205861     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0920-5861(97)81501-3     Document Type: Article

References (79)

1. H. Pines, The Chemistry of Catalytic Hydrocarbon Conversion, Academic Press, New York, NY, 1981.
2. G.A. Olah and A. Molnar, Hydrocarbon Chemistry, J. Wiley, New York, NY, 1995.
3. G.A. Olah, S.K. Prakash, J. Sommer, Superacids, J. Wiley, New York, NY, 1985.
4. A. Corma, Chem. Rev., 95 (1995) 559.
5. W.E. Farneth and R.J. Gorte, Chem. Rev., 95 (1995) 615.
6. T. Yamaguchi, Appl. Catal., 61 (1990) 1.
7. K. Arata, Appl. Catal. A, 154 (1996) 3.
8. K. Arata, Adv. Catal., 97 (1990) 165.
9. K. Song and A. Sayari, Catal. Rev. Sci. Eng., 38 (1996) 329.
10. R.J. Gillespie, Adv. Phys. Org. Chem., 9 (1972) 1.
11. R. Jost and J. Sommer, Rev. Chem. Intermediates, 9 (1988) 171.
12. In October 1994 the Swedish Royal Academy of Sciences awarded the Nobel Prize to George Olah (USC, Los Angeles) for his contribution to carbocation chemistry.
13. M. Hino and K. Arata, Chem. Lett, (1979) 1259.
14. C.Y. Hsu, C.R. Heimbuch, C.T. Armes and B.C. Gates, J. Chem. Soc., Chem. Commun., (1992) 1645.
15. M. Poutsma, ACS Monograph, 171 (1976) 505.
16. W.O. Haag and R.M. Dessau, Proceedings of the 8th International Congress on Catalysis, Berlin, 1984, Vol. 2, p. 305.
17. L.P. Hammett and A.J. Deyrup, J. Am. Chem. Soc., 54 (1932) 2721.
18. B.S. Umansky and K. Hall, J. Catal., 124 (1990) 97.
19. F. Babou, G. Coudurier and J.C. Védrine, J. Catal., 152 (1995) 341.
20. J.B. Nicholas, J.F. Haw, L.W. Beck, T.R. Krawietz and D.B. Ferguson, J. Am. Chem. Soc., 117 (1994) 12350.
21. L. Heeribout, P. Batamack, C. Doremieux-Morin, R. Vincent and J. Fraissard, Colloids Surf. A: Physicochem. Eng., (1996) 229.
22. J. Sommer, M. Hachoumy, F. Garin and D. Barthomeuf, J. Am. Chem. Soc., 116 (1994) 5491.
23. G.A. Olah, Angew. Chem., Int. Ed. Engl., 12 (1973) 173.
24. J. Sommer, M. Hachoumy, R. Jost and J. Bukala, J. Am. Chem. Soc., 119 (1997) 3274.
25. C.D. Nenitzescu and I.P. Cantuniari, Chem. Ber., 66 (1933) 1097.
26. C.D. Nenitzescu and A. Dragan, Chem. Ber., 66 (1933) 1892.
27. H. Kranni, W.G. Haag and B.C. Gates, J. Catal., 135 (1992) 125.
28. C. Stefanadis, B.C. Gates and W.O. Haag, J. Mol. Catal., 67 (1991) 363.
29. T.K. Cheung and B.C. Gates, J. Chem. Soc., Chem. Commun., (1996) 1937.
30. K.A. Cumming and B.W. Wojciechowski, Catal. Rev.-Sci. Eng., 38 (1996) 101.
31. M. Marczewski, Bull. Chem. Soc. Fr., 5 (1986) 750.
32. M. Marczewski, J. Chem. Soc., Faraday Trans., 82 (1986) 1687.
33. D. Spielbauer, G.A.H. Mekhemer, M.I. Zaki and H. Knšzinger, Catal. Lett., 40 (1996) 71.
34. F. Pinna, M. Signoretto, G. Strukul, G. Cerrato and C. Morterra, Catal. Lett., 26 (1994) 339.
35. J.-C. Culmann and J. Sommer, J. Am. Chem. Soc., 112 (1990) 4057.
36. G.S. Gordon and R.L. Burwell, J. Am. Chem. Soc., 71 (1949) 2355.
37. R. Srinivasan, R.A. Keogh, A. Ghenciu, D. Farcasiu and B.H. Davis, J. Catal., 158 (1996) 502.
38. A. Ghenciu and D. Farcasiu, J. Chem. Soc., Chem. Commun., (1990) 169.
39. D. Farcasiu, A. Ghenciu and Li Jing Qi, J. Catal., 158 (1996) 116.
40. J. Scherrer and R.E. Ritter, Ind. Eng. Chem. Prod. Res. Div., 17 (1978) 219.
41. J. Sommer, D. Habermacher, M. Hachoumy, R. Jost and A. Reynaud, Appl. Catal. A, 146 (1996) 193.
42. C. Bearez, F. Chevalier and M. Guisnet, React. Kinet. Catal. Lett., 22 (1983) 405.
43. C. Bearez, F. Avendano, F. Chevalier and M. Guisnet, Bull. Soc. Chim. Fr., 3 (1985) 346.
44. F. Garin, L. Seyfried, P. Girard, G. Maire, A. Abdulsamad and J. Sommer, J. Catal., 151 (1995) 26.
45. A.S. Zarkalis, C.Y. Hsu and B.C. Gates, Catal. Lett., 29 (1994) 235.
46. V. Adeeva, G.D. Lei and W.H.M. Sachtler, Appl. Catal. A, 118 (1994) L11.
47. A.S. Zarkalis, C.Y. Hsu and B.C. Gates, Catal. Lett., 37 (1996) 1.
48. V. Adeeva, G.D. Lei and W.H.M. Sachtler, Catal. Lett., 33 (1995) 135.
49. H. Liu, G.D. Lei and W.H.M. Sachtler, Appl. Catal. A, 137 (1996) L67.
50. J.E. Tabora and R.J. Davis, J. Am. Chem. Soc., 118 (1996) 12240.
51. F. Garin, A. Andriamasinoro, A. Abdulsamad and J. Sommer, J. Catal., 131 (1991) 199.
52. D. Spielbauer, G.A. Mekhemer, E. Bosch and H. Knšzinger, Catal. Lett., 36 (1996) 59.
53. C.K. Ingold, C.G. Raisin and C.L. Wilson, J. Chem. Soc., Chem. Commun., (1936) 1643.
54. G.A. Olah and R.H. Schlosberg, J. Am. Chem. Soc., 90 (1968) 2726.
55. H. Hogeveen and C.J. Gaasbeek, Reel. Trav. Chim. Pays-Bas, 87 (1968) 319.
56. G.A. Olah, Y. Halpern, J. Shen and Y.K. Mo, J. Am. Chem. Soc., 93 (1971) 1251.
57. A. Corma, J. Planelles, J. Sandoz-Marin and F. Thomas, J. Catal., 93 (1985) 30.
58. J. Sommer, M. Hachoumy and J. Bukala, Res. Chem. Intermed., 22 (1996) 753.
59. J. Sommer, M. Hachoumy, J. Bukala, unpublished results.
60. J. Sommer, M. Hachoumy, F. Garin, D. Barthomeuf and J. Vedrine, J. Am. Chem. Soc., 117 (1995) 1135.
61. N. Essayem, D. Habermacher and J. Sommer, Proceedings of the 3th International Symposium on Acid-Base Catalysis, Rolduc, 20-24 April 1997.
62. J.W. Otvos, D.P. Stevenson, C.D. Wagner and O. Beeck, J. Am. Chem. Soc., 73 (1951) 5741.
63. V. Markovnikov, (1838-1904). Born in Russia, Moscow University.
64. N.C. Deno in G.A. Olah and P.v.R. Schleyer (Eds.), Carbonium Ions, Vol. 3, J. Wiley, New York, NY, 1968, Chap. 19.
65. T. Soerensen in G.A. Olah and P.v.R. Schleyer (Eds.), Carbonium Ions, Vol. 3, J. Wiley, New York, NY, 1968, Chap. 18.
66. T. Xu and J.F. Haw, J. Am. Chem. Soc., 116 (1994) 10188.
67. J. Sommer and P. Ahlberg, in preparation.
68. V.B. Kazansky, Acc. Chem. Res., 24 (1991) 379.
69. C.K. Ingold, Structure and mechanism in Organic Chemistry (2nd edn.), Cornell University Press, Ithaca, NY, 1969.
70. G.A. Olah, M.B. Comisarow, C.A. Cupas and C.U. Pittman, J. Am. Chem. Soc., 87 (1965) 2297.
71. M.L. Cano, A. Corma, V. Fornés, H. Garcia, M.A. Miranda, C. Baerlocher and C. Lengauer, J. Am. Chem. Soc., 118 (1996) 11006.
72. M.T. Aronson, R.J. Gorte, W.E. Farneth and D. White, J. Am. Chem. Soc., III (1989) 840.
73. J.F. Haw, B.R. Richardson, I.S. Oshiro, N.D. Lazon and J.A. Speed, J. Am. Chem. Soc., III (1989) 2052.
74. A.G. Stepanov, V.M. Romannikov and K.I. Zamaraev, Catal. Lett., 13 (1992) 395.
75. A.G. Stepanov, Catal. Today, 24 (1995) 341.
76. A.G. Stepanov, K.I. Zamaraev and J.M. Thomas, Catal. Lett., 19 (1992) 407.
77. J.F. Haw, J.B. Nicholas, T. Xu, L.W. Beck and D.B. Ferguson, Acc. Chem. Res., 29 (1996) 259.
78. R.K. Thauer, A.R. Klein and G.C. Hartmann, Chem. Rev., 96 (1996) 3031.
79. J.A. Rabo, Proc. 6th Int. Zeolite Conf., Reno, USA 10-15 July 1983, p. 41.