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2
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0002237394
-
-
For reviews of the chemistry of acylsilanes, sec
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(1974)
Acc. Chem. Res.
, vol.7
, pp. 77
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Brook1
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11
-
-
0000677554
-
Ruthenium-catalyzed synthesis of vinyl carbamates from carbon dioxide, acetylene, and secondary amines
-
For recent examples of the application of acylsilanes in synthesis, see, references cited therein.
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(1987)
The Journal of Organic Chemistry
, vol.52
, pp. 314
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Reich1
Holtan2
Borkowsky3
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13
-
-
84913720774
-
-
For a review of the photochemistry of acylsilanes see, A. Padwa, Marcel Dekker, New York
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(1985)
Organic Photochemistry
, vol.7
, pp. 149-230
-
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Dalton1
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15
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1342317074
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Reaction of 1-trimethylsilylcyclopropyllithium derivatives with dichloromethyl methyl ether. A novel synthesis of cyclopropyl silyl ketones.
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(1986)
Chemistry Letters
, pp. 177
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Nakajima1
Miyaji2
Segi3
Suga4
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18
-
-
0002427539
-
Transition-metal catalyzed decomposition of aliphatic diazo compounds — New results and applications in organic synthesis
-
For recent reviews, see
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(1987)
Top. Curr. Chem.
, vol.137
, pp. 75
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-
Maas1
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25
-
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85022524053
-
Reactions of Organic Anions. LXVII1. Catalytic Synthesis of Cyclopropane Derivatives in Aqueous Medium
-
For recent variants of the McCoy reaction, see
-
(1976)
Synthesis
, pp. 387
-
-
Jonczyk1
Makosza2
-
28
-
-
84986679983
-
Alkylation, Acylation, and Cyclopropanation Reactions ofa-Halo Carboxylic Acid Dianions
-
For recent variants of the McCoy reaction, see
-
(1982)
Synthesis
, pp. 284
-
-
Johnson1
Bade2
-
36
-
-
84918149060
-
-
17 for details see the Experimental Section.
-
-
-
-
44
-
-
0347236151
-
-
For a discussion of “lithium bonding” and its relationship to hydrogen bonding, see, and references cited therein.
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(1986)
J. Chem. Ed.
, vol.63
, pp. 843
-
-
Sannigrahi1
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49
-
-
0003170165
-
-
For recent studies fo the stereochemical course of the Michael reaction, see
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(1985)
J. Org. Chem.
, vol.50
, pp. 3022
-
-
Heathcock1
Oare2
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54
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-
33847087776
-
-
2b has not been observed previously, although an example of the reverse process has been reported by Cohen and Matz
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(1980)
J. Am. Chem. Soc.
, vol.102
, pp. 6900
-
-
Cohen1
Matz2
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57
-
-
84918149059
-
-
Note, however, that the 1-methyl substituted cyclopropanccarboxaldehydes 35a,b could not be decarbonylated under similar conditions.
-
-
-
-
61
-
-
84918149058
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-
Pure bromoacetylsilane 15 could most likely be prepared via low-temperature recrystallizaton according to the procedure described for the purification of the chloro derivative 14.
-
-
-
-
62
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84918149057
-
-
The reaction may also be performed at room temperature for 24 h with similar results.
-
-
-
-
63
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84918149056
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-
A pure sample of 24a could be obtained in 61% yield via the reaction of the α-bromoacylsilane 15 with 5 equiv of diethyl fumarate following the general procedure.
-
-
-
-
64
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-
2242465052
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METHYLENE KETONES AND ALDEHYDES BY SIMPLE, DIRECT METHYLENE TRANSFER: 2-METHYLENE-1-OXO-1,2,3,4-TETRAHYDRONAPHTHALENE
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(1981)
Organic Syntheses
, vol.60
, pp. 88
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Gras1
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