Synthesis and structure of a bis(double helicate) and its cryptatoclathrate

Chemistry - A European Journal

Volumn 2, Issue 11, 1996, Pages 1363-1367

  Saalfrank, Rolf W ^a   Harbig, Roland ^a   Nachtrab, Jochen ^a   Bauer, Walter ^a   Zeller, Klaus Peter ^c   Stalke, Dietmar ^b   Teichert, Markus ^b  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

^b UNIVERSITY OF WÜRZBURG   (Germany)

^c UNIVERSITY OF TÜBINGEN   (Germany)

Author keywords

Clathrates; Cryptates; Helicates; Self assembly; Zinc complexes

Indexed keywords

CLATHRATES; CRYPTATES; HELICATES; INCLUSION COMPOUNDS; ONE-POT SYNTHESIS; SELF ASSEMBLY PROCESS; SELF-RECOGNITION; ZINC COMPLEX;

HYDRATES; KETONES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SELF ASSEMBLY; STEREOCHEMISTRY; X RAY DIFFRACTION;

ZINC;

EID: 0001523742     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.19960021106     Document Type: Article

References (51)

1. R. W. Saalfrank, C.-J. Lurz, K. Schobert, O. Struck, E. Bill, A. X. Trautwein, Angew. Chem. 1991, 103, 1499-1501;
2. Angew. Chem. Int. Ed. Engl. 1991, 30, 1494-1496.
3. a) R. W. Saalfrank, O. Struck, K. Nunn, C.-J. Lurz, R. Harbig, K. Peters, H. G. von Schnering, E. Bill, A. X. Trautwein, Chem. Ber. 1992, 125, 2331-2335;
4. b) R. W. Saalfrank, O. Struck, K. Peters, H. G. von Schnering, Chem. Ber. 1993, 126, 837-840.
5. R. W. Saalfrank, B. Hörner, D. Stalke, Angew. Chem. 1993, 105, 1223-1225;
6. Angew. Chem. Int. Ed. Engl. 1993, 32, 1179-1182.
7. R. W. Saalfrank, R. Burak, S. Reihs, N. Löw, F. Hampel, H.-D. Stachel, L. Lentmaier, K. Peters, E.-M. Peters, H. G. von Schnering, Angew. Chem. 1995. 107, 1085-1087;
8. Angew. Chem. Int. Ed. Engl. 1995, 35, 993-995.
9. R. Harbig, thesis, University of Erlangen-Nürnberg (Germany), 1996.
10. a) P. N. W. Baxter, J.-M. Lehn, J. Fischer, M.-T. Youinou, Angew. Chem. 1994. 106, 2432-2434;
11. Angew. Chem. Int. Ed. Engl. 1994, 33, 2284-2287;
12. b) J.-M. Lehn, Angew. Chem. 1988, 100, 91-116;
13. Angew. Chem. Int. Ed. Engl. 1988, 27. 89-112;
14. c) J.-M. Lehn, Angew. Chem. 1990, 102, 1347-1362;
15. Angew. Chem. Int. Ed. Engl. 1990, 29, 1304-1319;
16. d) J. S. Lindsey, New J. Chem. 1991, 15, 153-180;
17. e) G. M. Whitesides, J. P. Mathias, C. T. Seto, Science 1991, 254, 1312-1319;
18. f) D. Philp, J. F. Stoddart, Angew. Chem. 1996, 108, 1242-1286;
19. Angew. Chem. Int. Ed. Engl. 1996, 35, 1154-1196;
20. g) G. R. Desiraju, Angew. Chem. 1995, 107, 2541-2558;
21. Angew. Chem. Int. Ed. Engl. 1995. 34, 2311-2327.
22. 3 symmetry and (Δ,Δ)-/(Δ,Δ)-fac configuration at the octahedral iron(III) centres. An X-ray structure analysis is being carried out.
23. See also: a) Frontiers in Supramolecular Organic Chemistry and Photochemistry (Eds.: H.-J. Schneider, H. Dürr), VCH, Weinheim, 1991;
24. b) C. Seel, F. Vögtle, Angew. Chem. 1992, 104, 542-563;
25. Angew. Chem. Int. Ed. Engl. 1992, 31, 528-549;
26. c) P. Timmerman, W. Verboom, F. C. J. M. van Veggel, J. P. M. van Duynhoven, D. N. Reinhoudt, Angew. Chem. 1994, 106, 2437-2440;
27. Angew. Chem. Int. Ed. Engl. 1994, 33, 2345-2348.
28. For further examples see: a) R. Krämer, J-M. Lehn, A. De Cian, J. Fischer, Angew. Chem. 1993, 105, 764-767;
29. Angew. Chem. Int. Ed. Engl. 1993, 32, 703-706;
30. b) E. C. Constable, Tetrahedron 1992, 48, 10013-10059.
31. a) D. Sellmann, H. Friedrich, F. Knoch, Z. Naturforsch. 1993, 48b, 1675-1680;
32. b) F. A. L. Anet, S. S. Miura, J. Siegel, K. Mislow, J. Am. Chem. Soc. 1983. 105, 1419-1426.
33. For the classification and nomenclature of host-guest-type compounds, see: a) E. Weber, H.-P. Josel, J. Incl. Phenom. 1983, 1, 79-85;
34. b) E. Weber in Topics in Current Chemistry, Vol. 140 (Eds.: M. J. S. Dewar, J. D. Dunitz, K. Hafner, E. Heilbronner, S. Ito, J.-M. Lehn, K. Niedenzu, K. N. Raymond, C. W. Rees, F. Vögtle, G. Wittig), Springer, Berlin, 1987, p. 14 ff.
35. For recent studies on inclusion compound chemistry, see: a) C. D. Gutsche in Calixarenes (Ed.: J. F. Stoddart), Royal Society of Chemistry, Cambridge, 1992, ch. 6, p. 149 ff;
36. b) R. Ungaro, A. Pochini, G. D. Andreetti, P. Domiano, J. Chem. Soc. Perkin Trans. II 1985, 197-201;
37. c) P. Timmerman, K. G. A. Nierop, E. A. Brinks, W. Verboom, F. C. J. M. van Veggel, W. P. van Hoorn, D. N. Reinhoudt, Chem. Eur. J. 1995, 1, 132-143;
38. d) M. Perrin, F. Gharnati, D. Oehler, R. Perrin, S. Lecocq, J. Inclusion Phenom. 1992, 14, 257-270;
39. e) D. J. Cram, J. M. Cram in Container Molecules and Their Guests (Ed.: J. F. Stoddart), Royal Society of Chemistry, Cambridge, 1994, ch. 6, p. 107 ff;
40. f) D. J. Cram. H.-J. Choi, J. A. Bryant, C. B. Knobler, J. Am. Chem. Soc. 1992, 114, 7748-7765;
41. g) C. Valdés, U. P. Spitz, S. W. Kubik, J. Rebek. Jr., Angew. Chem. 1995, 107, 2031-2033;
42. Angew. Chem. Int. Ed. Engl. 1995, 34, 1885-1887.
43. a) R. T. Chakrasali, H. Ila, H. Junjappa, Synthesis 1988, 453-455;
44. b) A. Kumar, V. Aggarwal, H. Junjappa, Synthesis 1980, 748-751;
45. c) W. D. Rudorf, A. Schierhorn, M. Augustin, Tetrahedron 1979, 35, 551-556;
46. d) R. Gompper, H. Schaefer, Chem. Ber. 1967, 100, 591-604.
47. T. Kottke, D. Stalke, J. Appl. Crystallogr. 1993, 26, 615-619.
48. G. M. Sheldrick, Acta Crystallogr. Sect. A. 1990, 46, 467-473.
49. G. M. Sheldrick, SHELXL 93, University of Göttingen, 1993.
50. a) A. L. Spek, PLUTON93 graphics program, University of Utrecht, 1993;
51. b) A. L. Spek, Acta Crystallogr. Sect. A 1990, 46, C 34.