Bis-Catecholate, Bis-Dithiocatecholate, and Tetraalkoxy Diborane(4) Compounds: Aspects of Synthesis and Electronic Structure

Inorganic Chemistry

Volumn 37, Issue 20, 1998, Pages 5282-5288

  Lawlor, Fiona J ^a   Norman, Nicholas C ^a,d   Pickett, Nigel L ^a   Robins, Edward G ^a   Nguyen, Paul ^b   Lesley, Gerry ^b   Marder, Todd B ^b,e   Ashmore, Jennifer A ^c   Green, Jennifer C ^c  

^a NEWCASTLE UNIVERSITY   (United Kingdom)

^b UNIVERSITY OF WATERLOO   (Canada)

^c UNIVERSITY OF OXFORD   (United Kingdom)

^d UNIVERSITY OF BRISTOL   (United Kingdom)

^e DURHAM UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001514450     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic980425a     Document Type: Article

References (57)

1. For a brief overview of the synthesis, structure and reactivity of diborane(4) compounds, see: Lesley, G.; Marder, T. B.; Norman, N. C.; Rice, C. R. Main Group Chem. News 1997, 5, 4.
2. Kameda, M.; Driscoll, J. A.; Kodama, G. Inorg. Chem. 1990, 29, 3791 and references therein. See also: Parry, R. W. Phosphorus Sulfur 1994, 87, 177.
3. Kameda, M.; Driscoll, J. A.; Kodama, G. Inorg. Chem. 1990, 29, 3791 and references therein. See also: Parry, R. W. Phosphorus Sulfur 1994, 87, 177.
4. See, for example: (a) Massey, A. G. Adv. Inorg. Chem. Radiochem. 1983, 26, 1.
5. (b) Coyle, T. D.; Ritter, J. J. Adv. Organomet. Chem. 1972, 10, 237.
6. (a) Biffar, W.; Nöth, H.; Pommerening, H. Angew. Chem., Int. Ed. Engl. 1980, 19, 56.
7. (b) Schlüter, K.; Berndt, A. Angew. Chem., Int. Ed. Engl. 1980. 19, 57.
8. (a) Moezzi, A.; Olmstead, M. M.; Power, P. P. J. Am. Chem. Soc. 1992, 114, 2715.
9. (b) Moezzi, A.; Olmstead, M. M.; Bartlett, R. A.; Power, P. P. Organometallics 1992, 11, 2383.
10. Brotherton, R. J.; McCloskey, J. L.; Petterson, L. L.; Steinberg, H. J. Am. Chem. Soc. 1960, 82, 6242.
11. Brotherton, R. J.; McCloskey, J. L.; Bonne, T. L.; Manasevit, H. M. J. Am. Chem. Soc. 1960, 82, 6245.
12. (a) Nguyen, P.; Lesley, G.; Taylor, N. J.; Marder, T. B.; Pickett, N. L.; Clegg, W.; Elsegood, M. R. J.; Norman, N. C. Inorg. Chem. 1994. 33, 4623.
13. (b) Dai, C.; Stringer, G.; Corrigan, J. F.; Taylor, N. J.; Marder, T. B.; Norman, N. C. J. Organomet. Chem. 1996, 513, 237.
14. Dai, C.; Stringer, G.; Marder, T. B.; Baker, R. T.; Scott, A. J.; Clegg, W.; Norman, N. C. Can. J. Chem. 1996, 74, 2026.
15. Dai, C.; Stringer, G.; Marder, T. B.; Scott, A. J.; Clegg, W.; Norman, N. C. Inorg. Chem. 1997, 36, 272.
16. (e) Hartwig, J. F.; He, X. Organometallics 1996, 15, 400,
17. (f) Hartwig, J. F.; Xe, H. Angew. Chem., Int. Ed. Engl. 1996, 35, 315.
18. (g) Sakaki, S.; Kikuno, T. Inorg. Chem. 1997, 30, 226.
19. (h) Clegg, W.; Lawlor, F. J.; Lesley, G.; Marder, T. B.; Norman, N. C.; Orpen, A. G.; Quayle, M. J.; Rice, C. R.; Scott, A. J.; Souza, F. E. S. J. Organomet. Chem. 1998, 550, 183.
20. Clegg, W.; Lawlor, F. J.; Marder, T. B.; Nguyen, P.; Norman, N. C.; Orpen, A. G.; Quayle, M. J.; Rice, C. R.; Robins, E. G.; Scott, A. J.; Souza, F. E. S.; Stringer, G.; Whittell, G. R. J. Chem. Soc., Dalton Trans. 1998, 301.
21. (j) Kerr, A.; Marder, T. B.; Norman, N. C.; Orpen, A. G.; Quayle, M. J.; Rice, C. R.; Timms, P. L.; Whittell, G. R. J. Chem. Soc., Chem. Commun. 1998, 319.
22. (k) See also: Marder, T. B.; Norman, N. C.; Rice, C. R.; Robins, E. G. Chem. Commun. 1997, 53.
23. (a) Lshiyarna, T.; Matsuda, N.; Miyaura, N.; Suzuki, A. J. Am. Chem. Soc. 1993, 115, 11018.
24. (b) Ishiyama, T.; Matsuda, N.; Murata, M.; Ozawa, F.; Suzuki, A.; Miyaura, N. Organometallics 1996, 15, 713.
25. Iverson, C. N.; Smith, M. R., III. J. Am. Chem. Soc. 1995, 117, 4403.
26. Iverson, C. N.; Smith, M. R., III. Organometallics 1996, 15, 5155.
27. (e) Lesley, G.; Nguyen, P.; Taylor, N. J.; Marder, T. B.; Scott, A. J.; Clegg, W.; Norman, N. C. Organometallics 1996, 15, 5137.
28. (f) Cui, Q.; Musaev, D. G.; Morokuma, K. Organometallics 1997, 16, 1355.
29. (g) Cui, Q.; Musaev, D. G.; Morokuma, K. Organometallics 1998, 17, 742.
30. (h) Cui, Q.; Musaev, D. G.; Morokuma, K. Organometallics 1998, 17, 1383.
31. Siebert, W.; Pritzkow, H.; Maderna, A. Angew. Chem., Int. Ed. Engl. 1996, 35, 1501,
32. (j) Clegg, W.; Scott, A. J.; Lesley, G.; Marder, T. B.; Norman, N. C. Acta Crystallogr. 1996, C52, 1989 and 1991.
33. (a) For a review of metal-catalyzed diborations and related reactions, see; Marder, T. B.; Norman, N. C. In Topics in Catalysis; Leitner, W., Blackmond, D. G., Eds.; Baltzer Science Publishers: Amsterdam, 1998; Vol. 5, p 63.
34. (b) For metal-catalyzed diboration of dienes, see: Ishiyama, T.; Yamamoto, M.; Miyaura, N. Chem. Commun. 1996, 2073. Clegg, W.; Johann, T. R. F.; Marder, T. B.; Norman, N. C.; Orpen, A. G.; Peakman, T. M.; Quayle, M. J.; Rice, C. R.; Scott, A. J. J. Chem, Soc., Dalton Trans. 1998, 1431.
35. (b) For metal-catalyzed diboration of dienes, see: Ishiyama, T.; Yamamoto, M.; Miyaura, N. Chem. Commun. 1996, 2073. Clegg, W.; Johann, T. R. F.; Marder, T. B.; Norman, N. C.; Orpen, A. G.; Peakman, T. M.; Quayle, M. J.; Rice, C. R.; Scott, A. J. J. Chem, Soc., Dalton Trans. 1998, 1431.
36. For metal-catalyzed M-diboration of α,β-unsaturated ketones, see; Lawson, Y. G.; Lesley, M. J. G.; Marder, T. B.; Norman, N. C.; Rice, C. R. Chem. Commun. 1997, 2051.
37. 2O), see: Ishiyama, T.; Murata, N.; Miyaura, N. J. Org. Chem. 1995, 60, 7508. Ishiyama, T.; Itoh, Y.; Kitano, T.; Miyaura, N. Tetrahedron Lett. 1997, 38, 3447.
38. 2O), see: Ishiyama, T.; Murata, N.; Miyaura, N. J. Org. Chem. 1995, 60, 7508. Ishiyama, T.; Itoh, Y.; Kitano, T.; Miyaura, N. Tetrahedron Lett. 1997, 38, 3447.
39. (a) Baker, R. T.; Nguyen, P.; Marder, T. B.; Westcott, S. A. Angew. Chem., Int. Ed. Engl. 1995, 34, 1336.
40. (b) Ishiyama, T.; Yamamoto, M.; Miyaura, N. Chem. Commun. 1997, 689.
41. Iverson C. N.; Smith, M. R., III. Organometallics 1997, 16, 2757.
42. Marder, T. B.; Norman, N. C.; Rice, C. R. Tetrahedron Lett. 1998, 39, 155.
43. (e) Dai, C.; Robins, E. G.; Scott, A. J.; Clegg, W.; Yufit, D. S.; Howard, J. A. K.; Marder, T. B. Chem. Commun., in press.
44. Clegg, W.; Elsegood, M. R. J.; Lawlor, F. J.; Norman, N. C.; Pickett, N. L.; Robins, E. G.; Scott, A. J.; Nguyen, P.; Taylor, N. J.; Marder, T. B. Inorg. Chem. 1998, 37, 5289.
45. (a) Nguyen, P.; Dai, C.; Taylor, N. J.; Power, W. P.; Marder, T. B.; Pickett, N. L.; Norman, N. C. Inorg. Chem. 1995, 34, 4290.
46. (b) Clegg, W.; Dai, C.; Lawlor, F. J.; Marder, T. B.; Nguyen, P.; Norman, N. C.; Pickett, N. L.; Power, W. P.; Scott, A. J. J. Chem. Soc., Dalton Trans. 1997, 839.
47. Nöth, H. Z. Naturforsch., Teil B 1984, 39, 1463.
48. Nöth, H.; Meister, W. Z. Naturforsch., Teil B 1962, 17, 714.
49. Malhotra, S. C. Inorg. Chem. 1964, 3, 862.
50. (a) Lynaugh, N.; Lloyd, D. R.; Guest, M. F.; Hall M. B.; Hillier, I. H.; J. Chem. Soc., Faraday Trans. 2 1972, 68, 2192.
51. (b) Lloyd, D. R.; Lynaugh, N. J. Chem. Soc., Chem. Commun. 1971, 627.
52. Cetinkaya, B.; King, G. H.; Krishnaumurthy, S. S.; Lappert, M. F.; Pedley, J. B. J. Chem. Soc., Chem. Commun. 1971, 1370.
53. (a) Brain, P. T.; Downs, A. J.; MacCallum, P.; Rankin, D. W. H.; Robinson, H. E.; Forsyth, G. A. J. Chem. Soc., Dalton Trans. 1991, 1195.
54. (b) Brain, P. T. D.Phil. Thesis, University of Oxford, 1991.
55. Kimura, K.; Katsumatra, S.; Achiba, Y.; Yamazaki, T.; Iwata, S.; Handbook of He I Photoelectron Spectra of Fundamental Organic Molecules', Japan Scientific Societies Press: Tokyo, 1981.
56. Yen, J.-J. Atomic Calculation of Photoionisation Cross-Sections and Asymmetry Parameters; Gordon and Breach Science Publishers S.A.: Newark, NJ, 1993.
57. Hoffmann, R. J. Chem. Phys, 1963, 39, 1397.