Synthesis and characterization of (aminotroponiminato)titanium(IV) dialkyl complexes: Control of reactivity by ligand design

Organometallics

Volumn 18, Issue 20, 1999, Pages 3959-3961

  Steinhuebel, Dietrich P ^a   Lippard, Stephen J ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001508146     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9904347     Document Type: Article

References (24)

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10. Steinhuebel, D. P.; Lippard, S. J. Submitted for publication.
11. See the Supporting Information for experimental procedures and spectral and analytical data for all compounds.
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13. -1; T = 188 K, crystal dimensions 0.35 mm × 0.3 mm × 0.2 mm. The structure was solved by direct methods using XS and then refined by full-matrix least squares and Fourier techniques using SHELXTL-PLUS. Nonhydrogen atoms were refined anisotropically, and hydrogen atoms were located in difference Fourier maps and refined isotropically. The 3890 observed reflections (I > 2σ(I)) were collected on a Bruker CCD-detector-based diflractometer (1.87° < θ < 28.22°), corrected for absorption by using the SADABS program, and refined to a conventional R1 value of 0.0259 (wR2 = 0.0632). Crystallographic data for all structures, including bond distances and angles in addition to positional and thermal parameters (excluding structure factors), can be found in the Supporting Information.
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