Three-Dimensional Organic/Inorganic Composite Materials: Hydrothermal Synthesis and Structural Characterization of the Open-Framework Oxovanadium Borophosphate [H3NCH2CH2NH3]2[(VO) 5- (H2O){O3POB(O)2OPO3} 2]·1.5H2O

Chemistry of Materials

Volumn 9, Issue 12, 1997, Pages 2694-2696

  Warren, Christopher J ^b   Haushalter, Robert C ^a,b   Rose, David J ^c   Zubieta, Jon ^c  

^a SYMYX TECHNOLOGIES   (United States)

^b NEC LABORATORIES AMERICA   (United States)

^c SYRACUSE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001482009     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm9704286     Document Type: Article

References (32)

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25. 2O (0.081 g, 0.48 mmol) and water (1.5 mL, 83.33 mmol) in the mole ratio 4:4:4:1:175 was placed in a 23 mL Teflon-lined Parr acid digestion bomb and heated at 170°C for 72 h. The product is a 30:70 mixture of blue diamond shaped crystals of VOBOPO-1 and dark purple plates of an unidentified product. Mechanical separation provided VOBOPO-1 in 20% yield based on vanadium.
26. 2 = 0.0623 for 2210 reflections.
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30. Distances in Å, angles in deg: N1-02, 2.92; H1B-O2, 2.20; N1-O4, 2.89; H1B-O4, 2.25; N1-07, 2.89; H1C-O7, 2.23; N1-O11, 2.95; H1C-O11, 2.07; N2-O9, 2.77; H2A-09, 1.98; N2-O10, 2.85; H2B-O10, 2.11; N2-O13, 2.92; H2B-O13, 2.10. 〈N-H⋯O: 139-160.
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