Living cationic polymerization of p-chlorostyrene and related para-substituted styrene derivatives at room temperature

Macromolecules

Volumn 29, Issue 5, 1996, Pages 1778-1783

  Kanaoka, Shokyoku ^a   Eika, Yoshihiro ^b   Sawamoto, Mitsuo ^b   Higashimura, Toshinobu ^a  

^a UNIVERSITY OF SHIGA PREFECTURE   (Japan)

^b KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001478762     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma951320j     Document Type: Article

References (30)

1. This work was presented in part at the 42nd Annual Meeting of the Society of Polymer Science, Japan, Kyoto, 1993, Paper II-4-08: Eika, Y.; Kanaoka, S.; Sawamoto, M.; Higashimura, T. Polym. Prepr. Jpn., Engl. Ed. 1993, 42 (1), E81.
2. This work was presented in part at the 42nd Annual Meeting of the Society of Polymer Science, Japan, Kyoto, 1993, Paper II-4-08: Eika, Y.; Kanaoka, S.; Sawamoto, M.; Higashimura, T. Polym. Prepr. Jpn., Engl. Ed. 1993, 42 (1), E81.
3. For reviews, see: (a) Sawamoto, M.; Higashimura, T. Encyclopedia of Polymer Science and Engineering, 2nd ed. (Suppl.); John Wiley & Sons: New York, 1989; p 399. (b) Sawamoto, M. Prog. Polym. Sci. 1991, 16, 111. (c) Kennedy, J. P.; Iván, B. Designed Polymers by Carbocationic Macromolecular Engineering: Theory and Practice; Hanser Publishers: Munich, 1992.
4. For reviews, see: (a) Sawamoto, M.; Higashimura, T. Encyclopedia of Polymer Science and Engineering, 2nd ed. (Suppl.); John Wiley & Sons: New York, 1989; p 399. (b) Sawamoto, M. Prog. Polym. Sci. 1991, 16, 111. (c) Kennedy, J. P.; Iván, B. Designed Polymers by Carbocationic Macromolecular Engineering: Theory and Practice; Hanser Publishers: Munich, 1992.
5. For reviews, see: (a) Sawamoto, M.; Higashimura, T. Encyclopedia of Polymer Science and Engineering, 2nd ed. (Suppl.); John Wiley & Sons: New York, 1989; p 399. (b) Sawamoto, M. Prog. Polym. Sci. 1991, 16, 111. (c) Kennedy, J. P.; Iván, B. Designed Polymers by Carbocationic Macromolecular Engineering: Theory and Practice; Hanser Publishers: Munich, 1992.
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28. Under these reaction conditions, living polymerization of styrene was achieved; see ref 11. The polymerizations of pClSt and pAcOMS were carried out at 0°C because their polymerization reactions are very slow at a lower temperature.
29. The polymerization rate followed the order of the Lewis acidity of two tin halides. A similar trend was observed with polymerization of isobutyl vinyl ether (IBVE) using the IBVE-HCl adduct/Lewis acid initiating system. Kamigaito, M.; Maeda, Y.; Sawamoto, M.; Higashimura, T. Macromolecules 1993, 26, 1643.
30. The polymerization reactions were terminated with methanol containing a small amount of ammonia.