-
3
-
-
0343490722
-
-
edited by C. A. Croxton, Wiley, Chichester
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See, for example, K. E. Gubbins, in Fluid Interfacial Phenomena, edited by C. A. Croxton (Wiley, Chichester, 1986), p. 469.
-
(1986)
Fluid Interfacial Phenomena
, pp. 469
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-
Gubbins, K.E.1
-
9
-
-
85036212013
-
-
B. Widom, J. Phys. Chem. 100, 13 190 (1996).
-
(1996)
J. Phys. Chem.
, vol.100
, Issue.13
, pp. 190
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-
Widom, B.1
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15
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-
85036145374
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-
For a dielectric ellipsoid oriented at angle (Formula presented) relative to the z axis the dipole dielectric constants (signified by superscript d) perpendicular and parallel to the interface averaged over the azimuthal angle are, respectively, (Formula presented) and (Formula presented), where the hypergeometric function (Formula presented) For each z we can now calculate the dipole dielectric constant averaged over the angular distribution (Formula presented), namely, (Formula presented) Ellipsometry is sensitive to the composition averaged dielectric constant at each z (Formula presented), which can be calculated from the two-component Clausius-Mossotti relationship (Formula presented), where (Formula presented) 13 and (Formula presented) is the local volume fraction of dipoles Eq. (4)
-
For a dielectric ellipsoid oriented at angle (Formula presented) relative to the z axis the dipole dielectric constants (signified by superscript d) perpendicular and parallel to the interface averaged over the azimuthal angle are, respectively, (Formula presented) and (Formula presented), where the hypergeometric function (Formula presented) For each z we can now calculate the dipole dielectric constant averaged over the angular distribution (Formula presented), namely, (Formula presented) Ellipsometry is sensitive to the composition averaged dielectric constant at each z (Formula presented), which can be calculated from the two-component Clausius-Mossotti relationship (Formula presented), where (Formula presented) 13 and (Formula presented) is the local volume fraction of dipoles Eq. (4).
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-
-
-
23
-
-
85036173213
-
-
Estimated from Eqs. (7.1) and (7.2) in 21 using data from 22
-
Estimated from Eqs. (7.1) and (7.2) in 21 using data from 22.
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-
-
-
25
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-
84867907561
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-
edited by R. C. Weast, M. J. Astle, and W. H. Beyer, CRC Press, Boca Raton
-
CRC Handbook of Chemistry and Physics, 66th ed., edited by R. C. Weast, M. J. Astle, and W. H. Beyer (CRC Press, Boca Raton, 1985).
-
(1985)
CRC Handbook of Chemistry and Physics, 66th ed.
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-
-
26
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-
85036183689
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-
Estimated using Eq. (6.35) in 21 where the uv absorption frequency was determined from a Cauchy plot 13 using the refractive index data in 24 and assuming a typical error in this calculation of 10%
-
Estimated using Eq. (6.35) in 21 where the uv absorption frequency was determined from a Cauchy plot 13 using the refractive index data in 24 and assuming a typical error in this calculation of 10%.
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-
-
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27
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-
85036357375
-
-
J. Timmermans, Physico-chemical Constants of Pure Organic Compounds (Elsevier, New York, 1950)
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J. Timmermans, Physico-chemical Constants of Pure Organic Compounds (Elsevier, New York, 1950).
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-
-
-
28
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-
85036223707
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-
Dipole moment in a non-polar solvent estimated using Eq. (8) in 26 using the gas phase dipole moment data in 22
-
Dipole moment in a non-polar solvent estimated using Eq. (8) in 26 using the gas phase dipole moment data in 22.
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-
-
-
30
-
-
85036146580
-
-
Estimated using J. O. Hirschfelder, C. F. Curtiss, and R. B. Bird, Molecular Theory of Gases and Liquids (Wiley, New York, 1954), Sec. 13.2
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Estimated using J. O. Hirschfelder, C. F. Curtiss, and R. B. Bird, Molecular Theory of Gases and Liquids (Wiley, New York, 1954), Sec. 13.2.
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