Intramolecular energy transfer to trans-stilbene

Journal of Physical Chemistry A

Volumn 102, Issue 28, 1998, Pages 5577-5584

  Schanze, Kirk S ^a   Lucia, Lucian A ^a   Cooper, Megan ^a   Walters, Keith A ^a   Ji, Hai Feng ^a   Sabina, Osvaldo ^a  

^a University of Florida ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001475162     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp980203y     Document Type: Article

References (54)

1. Saltiel, J.; Hammond, G. S. J. Am. Chem. Soc. 1963, 85, 2515.
2. Hammond, G. S.; Saltiel, J. J. Am. Chem. Soc. 1963, 85, 2516.
3. Herkstroeter, W. G.; Hammond, G. S. J. Am. Chem. Soc. 1966, 88, 4769.
4. Saltiel, J.; D'Agostino, J.; Megarity, E. D.; Metis, L.; Neuberger, K. R.; Wrighton, M. S.; Zafiriou, O. C. Org. Photochem. 1973, 3, 1.
5. Gorman, A. A.; Beddoes, R. L.; Hamblett, S. P.; McNeeney, S. P.; Prescott, A. L.; Unett, D. J. J. Chem. Soc., Chem. Commun. 1991, 963.
6. Forward, P. J.; Gorman, A. A.; Hamblett, I. J. Chem. Soc., Chem. Commun. 1993, 250.
7. Gorman, A. A.; Hamblett, I.; Rushton, F. A. P.; Unett, D. J. J. Chem. Soc., Chem. Commun. 1993, 983.
8. Gorman, A. A. Spectrum 1990. 3, 16-20.
9. Saltiel, J.; Charlton, J. L.; Mueller, W. B. J. Am. Chem. Soc. 1979, 101, 1347.
10. Saltiel, J.; Marchand, G. R.; Kirkor-Kaminska, E.; Smothers, W. K.; Mueller, W. B.; Charlton, J. L. J. Am. Chem. Soc. 1984, 106, 3144.
11. donor).
12. Sandros, K. Acta Chem. Scand. 1964, 18, 2355.
13. Caldwell, R. A.; Riley, S. J.; Gorman, A. A.; McNeeney, S. P.; Unett, D. J. J. Am. Chem. Soc. 1992, 114, 4424.
14. Striplin, D. R.; Crosby, G. A. Chem. Phys. Lett. 1994, 221, 426.
15. Wrighton, M.; Morse, D. L. J. Am. Chem. Soc. 1974, 96, 998.
16. Giordano, P. J.; Wrighton, M. S. J. Am. Chem. Soc. 1979, 101, 2888.
17. MacQueen, D. B.; Schanze, K. S. J. Am. Chem. Soc. 1991, 113, 7470.
18. MacQueen, D. B.; Schanze, K. S. J. Am. Chem. Soc. 1992, 114, 1897.
19. Schanze, K. S.; MacQueen, D. B.; Perkins, T. A.; Cabana, L. A. Coord. Chem. Rev. 1993, 122, 63.
20. Wang, Y.; Schanze, K. S. Inorg. Chem. 1994, 33, 1354.
21. Boens, N.; DeRoeck, T.; Dockx, J.; DeSchryver, F. C. DECAN, Version 1.0; 1991.
22. 20
23. Caspar, J. V.; Kober, E. M.; Sullivan, B. P.; Meyer, T. J. J. Am. Chem. Soc. 1982, 104, 630.
24. Caspar, J. V. Ph.D. Dissertation, University of North Carolina, Chapel Hill, NC, 1982.
25. Worl, L. A.; Duesing, R.; Chen, P.; Della Ciana, L.; Meyer, T. J. J. Chem. Soc., Dalton Trans. 1991, 849.
26. Steady-state photochemistry to detect stilbene photoisomerization was not carried out on 4-ts owing to overlap between the dπ* and stilbene π,π* absorption bands. Because of the overlap, it was not possible to selectively excite the dπ* transition.
27. Görner, H.; Kuhn, H. J. Adv. Photochem. 1995, 19, 1.
28. Saltiel, J.; Khalil, G.-E.; Schanze, K. Chem. Phys. Lett. 1980, 70, 233.
29. Görner, H. J. Phys. Chem. 1989, 93, 1826.
30. Navon, G.; Sutin, N. Inorg. Chem. 1974, 13, 2159.
31. Song, X.; Endicott, J. F. Chem. Phys. Lett. 1993, 204, 400.
32. Hammond, G. S.; Saltiel, J.; Lamola, A. A.; Turro, N. J.; Bradshaw, J. S.; Cowan, D. O.; Counsell, R. C.; Vogt, V.; Dalton, C. J. Am. Chem. Soc. 1964, 86, 3197.
33. Saltiel, J.; Rousseau, A. D.; Thomas, B. J. Am. Chem. Soc. 1983, 105, 7631.
34. Görner, H.; Schulte-Frohlinde, D. J. Phys. Chem. 1981, 85, 1835.
35. Görner, H. J. Chem. Soc., Faraday Trans. 1993, 4027.
36. Binstead, R. A. SIMULATE; University of North Carolina at Chapel Hill: NC, 1992.
37. Hager, G. D.; Crosby, G. A. J. Am. Chem. Soc. 1975, 97, 7031.
38. Caspar, J. V.; Kober. E. M.; Sullivan, B. P.; Meyer, T. J. J. Am. Chem. Soc. 1982, 104, 630.
39. Kober, E. M. Ph.D. Dissertation, University of North Carolina at Chapel Hill, 1982.
40. Ryu, C. K.; Schmehl. R. H. J. Phys. Chem. 1989, 93, 7961.
41. Dexter, D. L. J. Chem. Phys. 1953, 21, 866.
42. Scandola, F.; Balzani, V. J. Chem. Educ. 1983, 60, 814.
43. Orlandi, G.; Monti, S.; Barigelletti, F.; Balzani, V. Chem. Phys. 1980, 313.
44. Sigman, M. E.; Closs, G. L. J. Phys. Chem. 1991, 95, 5012.
45. Lumpkin, R. S.; Meyer, T. J. J. Phys. Chem. 1986, 90, 5307.
46. The separation distance from Re to the center of the trans-stilbene chromophore is ∼12 Å and four σ bonds intervene between the π-orbital systems of the two chromophores.
47. Closs, G. L.; Piotrowiak, P.; MacInnis, J. M.; Fleming, G. R. J. Am. Chem. Soc. 1988, 110, 2652.
48. Closs, G. L.; Johnson, M. D.; Miller, J. R.; Piotrowiak, P. J. Am. Chem. Soc. 1989, 111, 3751.
49. ‡ and VTT.
50. Closs, G. L.; Calcaterra, L. T.; Green, N. J.; Penfield, K. W.; Miller, J. R. J. Phys. Chem. 1986, 90, 3673.
51. Closs, G. L.; Miller, J. R. Science 1988, 240, 440.
52. 47.48
53. The fact that energy transfer is vertical (i.e., not nonvertical) in 2-ts-4-ts is not surprising given that energy transfer is moderately exothermic in these systems. Previous examples of nonvertical energy transfer involve systems in which energy transfer is endothermic.
54. TT(2 bonds).