Formation of bridging nitride versus terminal oxovanadium promoted by a vanadium(II) macrocyclic complex

Chemistry - A European Journal

Volumn 2, Issue 7, 1996, Pages 767-771

  Jubb, Jayne ^a   Scoles, Ludmila ^a   Jenkins, Hilary ^a   Gambarotta, Sandro ^a  

^a UNIVERSITY OF OTTAWA   (Canada)

Author keywords

Bridging ligands; Dinitrogen reduction; Nitrides; Vunadium complexes

Indexed keywords

BRIDGING LIGANDS; DEOXYGENATIONS; DIMERIC SPECIES; DINITROGEN; MACROCYCLIC COMPLEX; NITROGEN ATOM; TETRAMETHYLETHYLENEDIAMINE; VUNADIUM COMPLEXES;

CHEMICAL REACTIONS; CHLORINE COMPOUNDS; NITRIDES;

LITHIUM;

EID: 0001467091     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.19960020707     Document Type: Article

References (52)

1. A. D. Allen, C. V. Senoff, J. Chem. Soc. Chem. Commun. 1965, 621
2. C. V. Senoff, J. Chem. Educ. 1990, 67, 368
3. M. E. Vol'pin, Dokl. Akad. Nauk. SSSR 1964, 156, 1102.
4. D. Rehder, C. Woitha, W. Priebsch, H. Gailus, J. Chem. Soc. Chem. Commun. 1992, 364
5. J. K. F. Buijink, A. Meetsma, J. H. Teuben, Organometallics 1993, 12, 2004
6. J. J. H. Edema, A. Meetsma, S. Gambarotta, J. Am. Chem. Soc. 1989, 111, 6878
7. G. J. Leigh, A. Prieto-Alcon, J. Sanders, J. Chem. Soc. Chem. Commun. 1991, 921
8. R. Ferguson, E. Solari, C. Floriani, A. Chiesi-Villa, C. Rizzoli, Angew. Chem. Int. Ed. Engl. 1993, 32, 396
9. P. Berno, S. Hao, R. Minhas, S. Gambarotta, J. Am. Chem. Soc. 1994, 116, 7417
10. J. I. Song, P. Berno, S. Gambarotta, ibid. 1994, 116, 6927.
11. a) N. T. Denisov, O. N. Efimov, N. I. Shuvalova, A. K. Shilova, A. E. Shilov, Zh. Fiz. Khim. 1970, 44, 2694; C. A. 1971, 74, 35950 p;
12. b) A. E. Shilov, D. N. Denisov, O. M. Efimov, N. F. Shuvalov, N. I. Shuvalova, A. E. Shilova, Nature (London) 1971, 231, 460;
13. c) N. P. Luneva, L. A. Nikonova, A. E. Shilov, Kinet. Katal. 1980, 21, 1041;
14. d) S. I. Zones, T. M. Vickery, J. G. Palmer, G. N. Schrauzer, J. Am. Chem. Soc. 1976, 98, 1289
15. e) G. N. Schrauzer, N. Strampach, L. A. Hughes, Inorg. Chem. 1982, 21, 2184;f)
16. G. N. Schrauzer, M. R. Palmer, J. Am. Chem. Soc. 1981, 103, 2659;
17. g) S. I. Zones, M. R. Palmer, J. G. Palmer, J. G. Doemeny, G. N. Schrauzer, ibid. 1978, 100, 2113;
18. h) N. Luneva, S. A. Mironova, A. E. Shilov, M. Y. Antipin, Y. T. Struchkov, Angew. Chem. Int. Ed. Engl. 1993, 23, 1178.
19. a) P. E. Bishop, D. M. L. Jarlenski, D. R. Hetherington, J. Bacteriol. 1982, 150, 1244;
20. b) R. L. Robson, R. R. Eady, T. H. Richardson, R. W. Miller, M. Hawkins, J. R. Postgate, Nature (London) 1986, 322, 388;
21. c) J. M. Arber, B. R. Dobson, R. R. Eady, P. Stevens, S. S. Hasnain, C. D. Garner, B. E. Smith, ibid. 1986, 325, 372.
22. a) G. N. George, C. L. Coyle, B. J. Hales, S. P. Cramer, J. Am. Chem. Soc. 1988, 110, 4057;
23. b) J. E. Morningstar, B. J. Hales, ibid. 1987, 109, 6854.
24. C. E. Laplaza, C. C. Cummins, Science 1995, 268, 861.
25. a) J. Jubb, S. Gambarotta, J. Am. Chem. Soc. 1993, 115, 10410;
26. b) J. Jubb, S. Gambarotta, Inorg. Chem. 1994, 33, 2503;
27. c) J. Jubb, S. Gambarotta, R. Duchateau, J. H. Teuben, J. Chem. Soc. Chem. Commun. 1994, 2641.
28. J. Jubb, S. Gambarotta, J. Am. Chem. Soc. 1994, 116, 4477.
29. L. E. Manzer, Inorg. Synth. 1982, 21, 138.
30. J. J. H. Edema, W. Stauthamer, S. Gambarotta, A. Meetsma, F. van Bolhuis, Inorg. Chem. 1990, 29, 1302.
31. a) H. Fischer, O. Orth, Die Chemie des Pyrrols, Akademische Verlagsgesellschaft, Leipzig, 1934;
32. b) A. Baeyer, Ber. Dtsch. Chem. Ges. 1886, 19, 2184;
33. c) M. Dennstadt, J. A. Zimmermann, ibid. 1887, 20, 850;
34. d) M. Dennstadt, J. A. Zimmermann, ibid. 1887, 20, 2449.
35. D. Jacoby, C. Floriani, A. Chiesi-Villa, C. Rizzoli, J. Am. Chem. Soc. 1993, 115, 3595 and references cited therein.
36. M.B. Mabbs, D.J. Machin, Magnetism and Transition Metal Complexes, Chapman and Hall, London, 1973.
37. G. Foese, C. J. Gorter, L. J. Smits, Constantes Selectionnées Diamagnetisme, Paramagnetisme, Relaxation Paramagnetique, Masson, Paris, 1957.
38. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-1220-10. Copies of the data can be obtained free of charge on application to the Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (Fax: Int. code +(1223)336-033; e-mail: teched@chemcrys.cam.ac.uk).
39. D. T. Cromer, J. T. Waber, International Tables for X-ray Crystallography, Kynoch, Birmingham (UK), 1974.
40. Crystal data for 2b: C135H232V2O4Li2N16, Mr =1082.04. monoclinic P21/c, a = 25.7116(9) Å, b = 26.5726(9) Å, c = 20.262(1) Å, β = 96.782(7)°, V = 13746(8) Å3, Z = 4, dcaled = 0.979 gcm-1, μ = 2.70 cm-1, F(000) = 4027, R = 0.132 (Rw = 0.149) for 1277 parameters and 8826 unique reflections. Non-hydrogen atom positions were refined anisotropically. Further details are available from the author on request.
41. a) V.L. Goedken, C. Ercolani, J. Chem. Soc. Chem. Commun. 1984, 378;
42. b) L. A. Bottomley, J. N. Gorce, V. L. Goedken, C. Ercolani, Inorg. Chem. 1985, 24, 3733;
43. c) W. R. Scheidt, D. A. Summerville, I. A. Cohen, J. Am. Chem. Soc. 1976, 98, 6623;
44. d) D. F. Bocian, E. W. Findsen, J. A. Hoffmann, G. A. Schick, D. R. English, D. N. Hendrickson, K. S. Suslick, Inorg. Chem. 1984, 23, 800;
45. e) V. L. Goedken, J. A. Ladd, J. Chem. Soc. Chem. Commun. 1981, 910;
46. f) K. L. Sorensen, M. E. Lerchen, J. W. Ziller, N. M. Doherty, Inorg. Chem. 1992, 31, 2679;
47. g) D. B. Sable, W. H. Armstrong, Inorg. Chem. 1992, 31, 161;
48. h) T. S. Haddad, A. Aistars, J. W. Ziller, N.M. Doherty, Organometallics 1993, 2, 2420;
49. i) P. Berno, S. Gambarotta, Angew. Chem. Int. Ed. Engl. 1995, 34, 822.
50. a) Vogel's Textbook of Quantitative Chemical Analysis, 5th ed., Longman, London, 1989, p. 193;
51. b) D. Boltz, Colorimetric Determination of Non-Metals, Wiley, New York, 1978, p. 205.
52. G. T. Richardson, J. A. Davies, J. G. Edwards, Fresenius Z. Anal. Chem. 1991, 340, 392.