메뉴 건너뛰기




Volumn 63, Issue 10, 1998, Pages 3176-3184

Photochemical C-C Bond Cleavage of 1,2-Diarylcyclopropanes Bearing an Acetylphenyl Group. Generation and Observation of Triplet 1,3-Biradicals

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0001455779     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo971111s     Document Type: Article
Times cited : (19)

References (68)
  • 44
    • 85034464585 scopus 로고    scopus 로고
    • Personal Communication
    • Nau, W. M. Personal Communication.
    • Nau, W.M.1
  • 58
    • 85034463184 scopus 로고    scopus 로고
    • note
    • The singlet-triplet gap is expected to affect the isc rate. Unfortunately the calculations we performed are not able to give reliable estimates for S-T gaps. However, we note that there is little difference between the S-T gaps calculated for trimethylene and 1-amino-3-cyanotrimethylene at any geometry. Our calculations thus provide no evidence that differences in the S-T gap with substituent contribute to substituent effects on isc for substituted trimethylenes.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.