Synthesis and reactions of neutral hypercoordinate allylsilicon compounds having a tropolonato ligand

Organometallics

Volumn 15, Issue 25, 1996, Pages 5335-5341

  Kira, Mitsuo ^a   Zhang, Luo Cheng ^a   Kabuto, Chizuko ^a   Sakurai, Hideki ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001454484     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960557g     Document Type: Article

References (44)

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2. For reviews, see: (a) Colvin, E. W.; Silicon in Organic Synthesis; Butterworth: London, 1981. (b) Weber W. P. Silicon Reagents for Organic Synthesis; Springer: New York, 1982. (c) Schinzer, D. Synthesis 1988, 263. (d) Chuit, C.; Corriu, R. J. P.; Reye, C.; Young, J. C. Chem. Rev. 1993, 93, 1371. (e) Masse, C. E.; Panek, J. S. Chem. Rev. 1995, 95, 1293.
3. For reviews, see: (a) Colvin, E. W.; Silicon in Organic Synthesis; Butterworth: London, 1981. (b) Weber W. P. Silicon Reagents for Organic Synthesis; Springer: New York, 1982. (c) Schinzer, D. Synthesis 1988, 263. (d) Chuit, C.; Corriu, R. J. P.; Reye, C.; Young, J. C. Chem. Rev. 1993, 93, 1371. (e) Masse, C. E.; Panek, J. S. Chem. Rev. 1995, 95, 1293.
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25. w = 0.067. All calculations were performed by an ACOS-2200 computer at Tohoku University with the applied library program UNICS III (Sakurai, T.; Kobayashi, K. Rikagaku Kenkyusho Hokoku 1979, 55, 69).
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35. In contrast to this, pentacoordinate allylsilatrane reacts with aldehydes only in the presence of Lewis acids: Gerveau, G.; Chuit, C.; Corriu, R. J. P.; Reyè, C. J. Organomet. Chem. 1987, 328, C17.
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39. A number of allylation of tropolone are reported: (a) Nozoe, T.; Mukai, T.; Murata, I. Proc. Jpn. Acad. 1953, 29, 169. (b) Nozoe, T.; Mukai, T.; Asao, T. Bull. Chem. Soc. Jpn. 1960, 33, 1452. (c) Goldshmidt, Z.; Antebi, S. Tetrahedron Lett. 1978, 1225.
40. A number of allylation of tropolone are reported: (a) Nozoe, T.; Mukai, T.; Murata, I. Proc. Jpn. Acad. 1953, 29, 169. (b) Nozoe, T.; Mukai, T.; Asao, T. Bull. Chem. Soc. Jpn. 1960, 33, 1452. (c) Goldshmidt, Z.; Antebi, S. Tetrahedron Lett. 1978, 1225.
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