New synthetic route, X-ray structure, and molecular orbital analysis for trans,transdichlorobis(triphenylphosphine)(phenyl)-rhodium(III). Do agostic Rh⋯H(PPh3), hydrogen-bond (Rh)Cl⋯H(PPh3), or steric intramolecular interactions prevail?

Inorganic Chemistry

Volumn 38, Issue 16, 1999, Pages 3751-3754

  Cini, Renzo ^a   Cavaglioni, Alessandro ^a,b  

^a UNIVERSITY OF SIENA   (Italy)

^b Laboratorio di Analisi   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001435063     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9900760     Document Type: Article

References (8)

1. Matsubara, T.; Koga, N.; Musaev, D. G.; Morokuma, K. J. Am. Chem. Soc. 1998, 120, 12692.
2. Tempel, D. J.; Brookhart, M. Organometallics 1998, 17, 2290.
3. Shaw, M. J.; Geiger, W. E.; Hyde, J.; White, C. Organometallics 1998, 17, 5486.
4. Yi, C. S.; Liu, N. Organometallics 1998, 17, 3158.
5. Vigalok, A.; Uzan, O.; Shimon, L. J. W.; Ben-David, Y.; Martin, J. M. L.; Milstein, D. J. Am. Chem. Soc. 1998, 120, 12539.
6. Cooper, A. C.; Clot, E.; Huffman, J. C.; Streib, W. E.; Maseras, F.; Eisenstein, O.; Caulton, K. G. J. Am. Chem. Soc. 1998, 120, 97.
7. Crabtree, R. H. The Organometallic Chemistry of the Transition Metals; Wiley-Interscience: New York, 1988.
8. (b) Braga, D.; Grepioni, F.; Desiraju, G. R. Chem. Rev. 1998, 98, 1375.