Alkyne or alkene binding versus hydrogenation in reactions with [Ir2H(CO)2(μ-H)2(Ph2PCH 2PPh2)2] [BF4]. Structure of [Ir2(C2H4)(CO)2(μ-H)(Ph 2PCH2PPh2)2] [BF4]

Inorganica Chimica Acta

Volumn 259, Issue 1-2, 1997, Pages 213-226

  Antwi Nsiah, Fred H ^a   Torkelson, Jeff R ^a   Cowie, Martin ^a  

^a UNIVERSITY OF ALBERTA   (Canada)

Author keywords

Alkene complexes; Alkyne complexes; Crystal structures; Hydrido bridged complexes; Hydrogenation; Iridium complexes

Indexed keywords

ALIPHATIC COMPOUNDS; BINARY ALLOYS; CRYSTAL STRUCTURE; ETHYLENE; HYDROGENATION; IRIDIUM COMPOUNDS; LIGANDS; REACTION INTERMEDIATES; X RAY CRYSTALLOGRAPHY;

ALKYNE COMPLEXES; DIMETHYL ACETYLENEDICARBOXYLATE; DIPHENYLACETYLENE; HYDRIDO-BRIDGED COMPLEXES; IRIDIUM COMPLEX; MONOCLINIC SPACE GROUPS; PARALLEL ORIENTATION; TETRAFLUOROETHYLENE;

IRIDIUM ALLOYS;

EID: 0001434484     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0020-1693(97)05464-9     Document Type: Article

References (81)

1. J.P. Collman, L.S. Hegedus, J.R. Norton and R.G. Finke, Principles and Applications of Organotransition Metal Chemistry, University Science Books, Mill Valley, CA, 1987, Chs. 6, 7, 10, 11, 17, 18.
2. J.L. Davidson, Reactions of Coordinated Acetylenes, in P.S. Braterman (ed.), Reactions of Coordinated Ligands, Vol. 1, Plenum, New York, 1987, p. 825.
3. (a) R.E. Harman, S.K. Gupta and D.J. Brown, Chem, Rev., 73 (1973) 21;
4. (b) B.R. James, Adv. Organomet. Chem., 17 (1979) 319;
5. J. Halpern, Inorg. Chim. Acta, 50 (1981) 11.
6. (a) R.L. Pruett, Adv. Organomet. Chem., 17 (1979) 1;
7. (b) J.L. Speier, Adv. Organomet. Chem., 17 (1979) 407.
8. See for example: (a) E. Guilmet, A. Maisonnat and R. Poilblanc, Organometallics, 2 (1983) 1123;
9. (b) R.R. Burch, A.J. Shusterman, E.L. Muetterties, R.G. Teller and J.M. Williams, J. Am. Chem. Soc., 105 (1983) 3546;
10. (c) M.D. Fryzuk, T. Jones and F.W.B. Einstein, Organometallics, 3 (1984) 185;
11. (d) B.R. Sutherland and M. Cowie, Organometallics, 4 (1985) 1801;
12. (e) S.R. Hommeltoft, D.H. Berry and R. Eisenberg, J. Am. Chem. Soc., 108 (1986) 5345;
13. (f) M. Rashidi and R.J. Puddephatt, Organometallics, 7 (1988) 1636;
14. (g) B.A. Vaartstra and M. Cowie, Organometallics, 9 (1990) 1594;
15. (h) M.J. Hostetler and R.G. Bergman, J. Am. Chem. Soc., 112 (1990) 8621.
16. R. McDonald, B.R. Sutherland and M. Cowie, Inorg. Chem., 26 (1987) 3333.
17. B.R. Sutherland and M. Cowie, Organometallics, 4 (1985) 1637.
18. N. Walker and D. Stuart, Acta Crystallogr., Sect. A, 39 (1983) 158.
19. G.M. Sheldrick, SHELXL-93, program for crystal structure determination, University of Göttingen, Göttingen, Germany, 1993.
20. See for example: (a) D.M. Antonelli and M. Cowie, Organometallics, 10 (1991) 2173;
21. (b) B.J. Sterenberg, R.W. Hilts, G. Moro, R. McDonald and M. Cowie, J. Am. Chem. Soc., 117 (1995) 245.
22. D.T. Cromer and J.T. Waber, International Tables for Crystallography, Vol. IV, Kynoch Press, Birmingham, UK, 1974, Table 2.2A.
23. R.F. Stewart, E.R. Davidson and W.T. Simpson, J. Chem. Phys., 42 (1965) 3175.
24. D.T. Cromer and D. Liberman, J. Chem. Phys., 53 (1970) 1891.
25. B.A. Vaartstra, Ph.D. Thesis, University of Alberta, 1989, Ch. 6.
26. B.A. Vaartstra, J. Xiao, J.A. Jenkins, R. Verhagen and M. Cowie, Organometallics, 10 (1991) 2708.
27. B.R. Sutherland and M. Cowie, Organometallics, 3 (1984) 1869.
28. J.A. Jenkins and M. Cowie, Organometallics, 11 (1992) 2774.
29. J.T. Mague, Organometallics, 5 (1986) 918.
30. J.T. Mague, C.L. Klein, R.J. Majeste and E.D. Stevens, Organometallics, 3 (1984) 1860.
31. M. Cowie, R.S. Dickson and B.W. Hames, Organometallics, 3 (1984) 1879.
32. (a) R.J. Puddephatt and M.A. Thomson, Inorg. Chem., 21 (1982) 725;
33. (b) Inorg. Chim. Acta, 45 (1980) L281.
34. (a) D.H. Berry and R. Eisenberg, Organometallics, 6 (1987) 1796;
35. (b) J. Am. Chem. Soc., 707 (1985) 7181.
36. J. Xiao and M. Cowie, Organometallics, 12 (1993) 463.
37. (a) L.-S. Wang and M. Cowie, Organometallics, 14 (1995) 2374;
38. (b) Organometallics, 14 (1995) 3040;
39. (c) F.H. Antwi-Nsiah, O. Oke and M. Cowie, Organometallics, 15 (1996) 506.
40. J.M. Bray and R.J. Mawby, J. Chem. Soc., Dalton Trans., (1989) 589.
41. A. Nakamura and S. Otsuka, J. Am. Chem. Soc., 94 (1972) 1886.
42. D.S.A. George, R. McDonald and M. Cowie, Can. J. Chem., 74 (1996) 2289.
43. L.-S. Wang and M. Cowie, Can. J. Chem., 73 (1995) 1058.
44. M.P. Brown, J.R. Fisher, R.H. Hill, R.J. Puddephatt and R.R. Seddon, Inorg. Chem., 20 (1981) 3516.
45. See for example: (a) D.M. Antonelli and M. Cowie, Organometallics, 9 (1990) 1818;
46. (b) Organometallics, 10 (1991) 2550;
47. (c) R. McDonald and M. Cowie, Inorg. Chem., 29 (1990) 1564;
48. (d) D.J. Elliot, G. Ferguson, D.G. Holah, A.N. Hughes, M.C. Jennings, V.R. Magnuson, D. Potter and R.J. Puddephatt, Organometallics, 5 (1986) 918.
49. F.H. Antwi-Nsiah and M. Cowie, Organometallics, 11 (1992) 3157.
50. F.H. Antwi-Nsiah, O. Oke and M. Cowie, Organometallics, 15 (1996) 1042.
51. B.A. Vaartstra and M. Cowie, Organometallics, 8 (1989) 2388.
52. F. Caruso, R. Spagna and L. Zambonelli, Inorg. Chim. Acta, 32 (1979) L23.
53. J.J. Bonnet, R. Mathieu, R. Poilblanc and J.A. Ibers, J. Am. Chem. Soc., 101 (1979) 7487.
54. M. Green, A. Laguna, J.L. Spencer and F.G.A. Stone, J. Chem. Soc., Dalton Trans., (1977) 1010.
55. J.R. Torkelson and M. Cowie, unpublished results.
56. J.R. Torkelson, F.H. Antwi-Nsiah and M. Cowie, manuscript in preparation.
57. M.L.H. Green and L.-L. Wong, J. Chem. Soc., Chem. Commun., (1984) 1442.
58. D.M. Antonelli and M. Cowie, Organometallics, 9 (1990) 1818.
59. J. Halpern and T. Okamoto, Inorg. Chim. Acta, 89 (1984) L53.
60. (a) M.R. Churchill, Perspect. Struct. Chem., 3 (1970) 9;
61. (b) J.A. Connor, Top. Curr. Chem., 71 (1977) 71;
62. (c) J.A. Connor, M.T. Zofurani-Moattar, J. Bickerton, N.I. El Saied, S. Suradi, R. Carson, G. Al Takkir and H.A. Skinner, Organometallics, 1 (1982) 1166;
63. (d) M.I. Bruce, R.C. Wallis, B.W. Skelton and A.H. White, J. Chem. Soc., Dalton Trans., (1981) 2205.
64. (a) M. Cowie, G. Vasapollo, B.R. Sutherland and J.P. Ennett, Inorg. Chem., 25 (1986) 2648;
65. (b) I.R. McKeer, S.J. Sherlock and M. Cowie, J. Organomet. Chem., 352 (1988) 205.
66. (a) T.-F. Mao, Ph.D. Thesis, University of Alberta, 1996;
67. (b) J. Takats, personal communication.
68. See for example: R.S. Dickson, Polyhedron, 10 (1991) 1995.
69. B.A. Vaarstra and M. Cowie, Organometallics, 8 (1989) 2388.
70. (a) W.A. Herrmann, Angew. Chem., Int. Ed. Engl., 21 (1982) 117;
71. (b) R.G. Bergman and K.H. Theopold, Organometallics, 1 (1982) 1571;
72. (c) J.R. Norton, K.M. Motyl, C.K. Schauer and O.P. Anderson, J. Am. Chem. Soc., 104 (1982) 7325;
73. (d) J. Takats and M.R. Burke, J. Am. Chem. Soc., 105 (1983) 4092;
74. (e) P. Vioget, M. Bonivento, R. Roulet and P. Vogel, Helv. Chim. Acta, 67 (1984) 1630;
75. (f) M.R. Burke and J. Takats, J. Organomet. Chem., 302 (1986) C25;
76. (g) C.P. Casey and J.D. Audett, Chem. Rev., 86 (1986) 339;
77. (h) A.J. Poë and C.V. Sekhar, J. Am. Chem. Soc., 108 (1986) 3673;
78. (i) J.R. Norton, R.T. Hembre and C.P. Scott, J. Am. Chem. Soc., 109 (1987) 3468;
79. (j) J. Takats, Polyhedron, 7 (1988) 931;
80. (k) K.A. Johnson and W.L. Gladfelter, Organometallics, 10 (1991) 376;
81. (l) O.P. Anderson, B.R. Bender and J.R. Norton, Organometallics, 10 (1991) 3145.