F430 Model Chemistry. A Reexamination of the [1,4,7,10,13-Pentaazacyclohexadecane-14,16-dionato(2-)]nickel(II)-Induced Formation of Methane from Methyl Coenzyme-M

Inorganic Chemistry

Volumn 35, Issue 16, 1996, Pages 4649-4655

  Zhang, Zhong ^a   Petersen, Jeffrey L ^a   Stolzenberg, Alan M ^a  

^a WEST VIRGINIA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001431923     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960263n     Document Type: Article

References (61)

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6. Abbreviations: CoM, 2-mercaptoethanesulfonic acid anion; methyl CoM, (2-methylthio)ethanesulfonic acid anion; HS-HTP, (7-mercaptoheptanoyl)threonine phosphate; F430M, the pentamethyl ester of F430; OEiBC, mixture of ttt- and tct-2,3,7,8-tetrahydro-2,3,7,8,12,13,17,18-octaethylporphyrin dianion; L, 1,4,7,10,13-pentaazacyclohexadecane-14,16-dione; L', 1,4,7,10-tetraazacyclotridecane-11,13- dione; dien, diethylenetriamine; trien, triethylenetetramine; tetren. tetraethylenepentamine.
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49. 2) of 147 parameters converged with R1 = 0.0843 and wR2 = 0.1889 for 1482 data with I > 2σ(I) and GOF = 1.008. Typical esds are 0.008 Å for Ni-E bond lengths and 0.3° for E-Ni-E angles (E = O, N).
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58. 2 and of Drain's NiL complex in borate buffer implies that the latter is also in the five-coordinate, amide-deprotonated form at this pH. Given the near pH independence of the reactivity of Drain's NiL toward methyl CoM, this argues against the presence of a ligand that promotes reactivity.
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61. 1/2. where n is the number of reflections and p is the number of parameters varied during the last refinement cycle.