“In-plane” Coordinated Double Bonds. Molecular Structures, Spectroscopy, and Stability of 5-methylenecyclooctene and 5-methylenecycloheptene Complexes of Platinum(II)

Organometallics

Volumn 6, Issue 6, 1987, Pages 1211-1218

  Rakowsky, Margaret H ^a   Woolcock, John C ^a   Wright, Laura L ^a   Green, David B ^a   Rettig, Michael F ^a   Wing, Richard M ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001420702     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om00149a015     Document Type: Article

References (29)

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23. “Opposite-sign” cis and trans influences of aryl ligands have been observed in platinum-phosphorus coupling constants: Arnold, D. P.; Bennett, M. A. Inorg. Chem. 1984, 23, 2117–2124.
24. Similar NMR parameters for chloro[(1,2,5,6-η4)-cycloocta-1,5-diene] (R)platinum(II): Chisholm, M. H.; Clark, H. C.; Manzer, L. E.; Stothers, J. B.; Ward, J. E. H. J. Am. Chem. Soc. 1975, 97, 721–727. The use of 195Pt NMR to distinguish between similar chloro and bromo complexes is well-established in coordination chemistry; see, e.g.: Harris, R. K.; Mann, B. E. NMR and the Periodic Table; Academic: New York, 1978; Pregosin, P. S. Coord. Chem. Rev. 1982, 44, 247. Pregosin, P. S. Annu. Rep. NMR Spectrosc. 1986, 17, 285 and references cited therein.
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29. The ordering of the first four dienes agrees with that found for Pd(II): Partenheimer, W. Inorg. Chem. 1972. 11, 743.