Theoretical and Experimental Studies of Six-Membered Selenium-Sulfur Nitrides SexS4-xN2 (x = 0-4). Preparation of S4N2 and SeS3N2 by the Reaction of Bis[bis(trimethylsilyl)amino]sulfane with Chalcogen Chlorides

Inorganic Chemistry

Volumn 36, Issue 10, 1997, Pages 2170-2177

  Maaninen, Arto ^a   Siivari, Jari ^a   Suontamo, Reijo J ^b   Konu, Jari ^a   Laitinen, Risto S ^a   Chivers, Tristram ^c  

^a UNIVERSITY OF OULU   (Finland)

^b UNIVERSITY OF JYVÄSKYLÄ   (Finland)

^c UNIVERSITY OF CALGARY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001417929     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9613570     Document Type: Article

References (73)

1. (a) University of Oulu.
2. (b) University of Jyväskylä.
3. The University of Calgary.
4. For reviews on S-N compounds, see: (a) Chivers, T. In The Chemistry of Inorganic Homo- and Heterocycles; Haiduc, I., Sowerby, D. B., Eds.; Academic Press, Inc.: London, 1987; Vol. 2, pp 793-869. (b) Oakley, R. T. Prog. Inorg. Chem. 1988, 36, 299.
5. For reviews on S-N compounds, see: (a) Chivers, T. In The Chemistry of Inorganic Homo- and Heterocycles; Haiduc, I., Sowerby, D. B., Eds.; Academic Press, Inc.: London, 1987; Vol. 2, pp 793-869. (b) Oakley, R. T. Prog. Inorg. Chem. 1988, 36, 299.
6. Adkins, R. R.; Turner, A. G. J. Am. Chem. Soc. 1978, 100, 1383.
7. Palmer, M. H.; Wheeler, J. R.; Findlay, R. H.; Westwood, N. P. C.; Lau, W. M. J. Mol. Struct. 1981, 86, 193.
8. (a) Chivers, T.; Codding, P. W.; Oakley, R. T. J. Chem. Soc., Chem. Commun. 1981, 584.
9. (b) Chivers, T.; Codding, P. W.; Laidlaw, W. G.; Liblong, S. W.; Oakley, R.T.; Trsic, M. J. Am. Chem. Soc. 1983, 105, 1186.
10. (c) Small, R. W. H.; Banister, A. J.; Hauptman, Z. V. J. Chem. Soc., Dalton Trans. 1981, 2188.
11. 4(6) Dehnicke, K.; Schmock, F.; Köhler, K. F.; Frenking, G. Angew. Chem. 1991, 103, 564; Angew. Chem., Int. Ed. Engl. 1991, 30, 577.
12. 4(6) Dehnicke, K.; Schmock, F.; Köhler, K. F.; Frenking, G. Angew. Chem. 1991, 103, 564; Angew. Chem., Int. Ed. Engl. 1991, 30, 577.
13. Vogler, S.; Schafer, M.; Dehnicke, K. Z. Anorg. Allg. Chem. 1991, 606, 73.
14. Kennett, F. A.; MacLean, G. K.; Passmore, J.; Rao, M. N. S. J. Chem. Soc., Dalton Trans. 1982, 851.
15. (a) Siivari, J.; Chivers, T.; Laitinen, R. S. Angew. Chem. 1992, 104, 1539; Angew. Chem., Int. Ed. Engl. 1992, 31, 1518.
16. (a) Siivari, J.; Chivers, T.; Laitinen, R. S. Angew. Chem. 1992, 104, 1539; Angew. Chem., Int. Ed. Engl. 1992, 31, 1518.
17. (b) Siivari, J.; Chivers, T.; Laitinen, R. S. Inorg. Chem. 1993, 32, 4391.
18. Siivari, J.; Chivers, T.; Laitinen, R. S. Inorg. Chem. 1993, 32, 1519.
19. Chivers, T.; Laitinen, R. S.; Maaninen, A.; Pyykkönen, S.; Silvari, J. Univ. of Oulu Rep. Ser. Chem. 1993, 42, P18.
20. (a) Haas, A.; Kasprowski, J.; Angermund, K.; Betz, P.; Krüger, C.; Tsay, Y.-H.; Werner, S. Chem. Ber. 1991, 724, 1895.
21. (b) Haas, A.; Kasprowski, J.; Pryka, M. J. Chem. Soc., Chem. Commun. 1992, 1144.
22. (c) Wolmerhäuser, G.; Brulet, C. R.; Street, G. B. Inorg. Chem. 1978, 17, 3586.
23. (a) Siivari, J.; Laitinen, R. S.; Hiltunen, Y. Phosphorus Sulfur Silicon Relat. Elem. 1992, 65, 177.
24. (b) Siivari, J.; Chivers, T.; Laitinen, R. S. 75th Canadian Chemical Conference and Exhibition, Edmonton, 1992; 336 IN-D5P.
25. 15
26. Siivari, J.; Suontamo, R. J.; Laitinen, R. S.; Chivers, T. Phosphorus Sulfur Silicon Relat. Elem 1994, 93/94, 245.
27. Frisch, M. J.; Trucks, G. W.; Head-Gordon, M.; Gill, P. M. W.; Wong, M. W.; Foresman, J. B.; Johnson, B. G.; Schlegel, H. B.; Robb, M. A.; Replogle, E. S.; Gomperts, R.; Andres, J. L.; Raghavachari, K.; Binkley, J. S.; Gonzales, C.; Martin, R. L.; Fox, D. J.; Defrees, D. J.; Baker, J.; Stewart, J. J. P.; Pople, J. A., Gaussian 92, Revision A Gaussian, Inc., Pittsburgh PA, 1992.
28. Sakai, Y.; Tatewaki, H.; Huzinaga, S., J. Comput. Chem. 1982, 3, 6.
29. The need for d-polarization functions for the correct geometry prediction of chalcogen-chalcogen bonds is well established (see, for instance, ref 19)
30. Hinchliffe, A. J. Mol. Struct. 1979, 55, 127.
31. (a) Möller, C.; Plesset, M. S. Phys. Rev. 1934, 46, 618.
32. (b) Binkley, J. S.; Pople, J. A. Int. J. Quantum Chem. 1975, 9, 229.
33. (c) Pople, J. A.; Binkley, J. S.; Seeger, R. Int. J. Quantum Chem. 1976, 10, 1.
34. Pople, J. A.; Schlegel, H. B.; Krishnan, R.; Binkley, J. S.; Frisch, M. J.; Whiteside, R. A.; Hout, R. F.; Hehre, W. J. Int. J. Quantum Chem. Symp. 1981, 15, 269.
35. Fehér, F. In Handbuch der präparativen Anorganischen Chemie, 3rd ed.; Brauer, G., Ed.; Ferdinand Enke Verlag: Stuttgart, 1975, Vol. 1, p 415.
36. 24.
37. 24.
38. Chivers, T.; Oakley, R. T.; Scherer, O. J.; Wolmershäuser, G. Inorg. Chem. 1981, 20, 914.
39. 2 was obtained as dark red crystals.
40. 2 and 7.7% of Se. Anal. Calcd for this mixture: N, 12.7; S, 43.6; Se, 43.6.
41. McIntosh,D. F.; Peterson, M. R. General Vibrational Analyse Programs Utilizing the Wilson GF Matrix Method for a General Unsymmetrized Molecule. QCPE, 1977, 342.
42. Steudel, R.; Mäusle, H.-J. Z. Naturforsch., A 1978, 33, 951.
43. Laitinen, R.; Rautenberg, N.; Steidel, J.; Steudel, R. Z. Anorg. Allg. Chem. 1982, 486, 116.
44. (a) Steudel, R. Z. Naturforsch., A 1981, 36, 850.
45. (b) Steudel, R. J. Phys. Chem. 1977, 81, 343.
46. (c) Steudel, R.; Rose, F. Spectrochim. Acta 1977, 33A, 979.
47. (d) Steudel, R.; Steidel, J.; Rautenberg, N. Z. Naturforsch., 1980, 35, 792.
48. Brooks, W. V. F.; Cameron, S. T.; Parsons, S.; Passmore, J.; Schriver, M. J. Inorg. Chem. 1995, 33, 6230.
49. 34h
50. Pauling, L. The Nature of the Chemical Bond, 3rd ed.; Cornell University Press: Ithaca, NY, 1960; Chapter 7.
51. (a) Coppens, P.; Yang, Y. W.; Blessing, R. H.; Cooper, W. F.; Larsen, F. K. J. Am. Chem. Soc. 1977, 99, 760,
52. (b) Rettig, S. J.; Trotter, J. Acta Crystallogr., Sect. C 1987, 43, 2260.
53. (c) Foust, A. S.; Janickis, V.; Marfy, K. Inorg. Chem. 1980, 19, 1040.
54. (d) Cherin, P.; Unger, P. Acta Crystallogr., Sect. B 1972, 28, 313.
55. (e) Schubert, G.; Kiel, G.; Gattow, G. Z. Anorg. Allg. Chem. 1989, 575, 129.
56. (f) Björgvinsson, M.; Roesky, H. W.; Pauer, F.; Stalke, D.; Sheldrick, G. M. Inorg. Chem. 1990, 29, 5140.
57. (g) Anderson, D. G.; Robertson, H. E.; Rankin, D. W. H.; Woollins, J. D. J. Chem. Soc., Dalton Trans. 1989, 859.
58. (h) Gindl, J.; Björgvinsson, M.; Roesky, H. W.; Freie-Erdbrügger, C.; Sheldrick, G. M. J. Chem. Soc., Dalton Trans. 1993, 811.
59. Laitinen, R.; Pakkanen, T. J. Mol. Struct. (THEOCHEM) 1983, 91, 337.
60. 2 -9699.735 26.
61. 38
62. Fockenberg, F.; Haas, A. Z. Naturforsch. 1986, 41B, 413.
63. Pouchert, C., Ed. The Aldrich Library of NMR Spectra, 2nd ed.; Aldrich: Milwaukee, WI, 1983; Vol. 2, p 995A.
64. 2 exhibits two signals at -55 and -125 ppm. Our resonances at -57 and -121 ppm can therefore be assigned to this species. The resonance at -46 ppm is due to an unknown species that is removed during the purification of the product by distillation, and is therefore unlikely to contain selenium.
65. 4 was produced.
66. Parkin, J. P.; Woollins, J. D.; Belton, P. S. J. Chem. Soc., Dalton Trans. 1990, 511.
67. 2 solution of the recrystallized product.
68. 26
69. -1.
70. Laitinen, R. S.; Pakkanen, T. A. Inorg. Chem. 1985, 26, 2598.
71. (a) Steudel, R.; Plinke, B.; Jensen, D.; Baumgart, F. Polyhedron 1991, 10, 1037.
72. (b) Milne, J. B. Can. J. Chem. 1992, 70, 693.
73. Steudel, R. Z. Naturforsch. 1975, 30A, 1481.