Lithium-Iodine Exchange Mediated Atom Transfer Cyclization: Catalytic Cycloisomerization of 6-Iodo-1-hexenes

Journal of Organic Chemistry

Volumn 63, Issue 2, 1998, Pages 361-365

  Bailey, William F ^a   Carson, Matthew W ^a  

^a UNIVERSITY OF CONNECTICUT   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001415863     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo971939e     Document Type: Article

References (27)

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8. 2O is converted to a mixture of all possible coupling products [octane, 1-decene, pentylcyclopentane, 1,11-dodecadiene, 7-cyclopentyl-1-heptene, and 1,2-dicyclopentylethane] in ∼88% yield on standing at 22 °C for 0.5 h.
9. 4b Thus, for example, the half-time for cyclization of 2 in the presence of TMEDA is only 6 min at -30 °C.
10. 2
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