Intrinsic non-RRK behavior: Classical trajectory, statistical theory, and diffusional theory studies of a unimolecular reaction

Journal of Chemical Physics

Volumn 105, Issue 5, 1996, Pages 1833-1845

  Shalashilin, Dmitrii V ^a,b   Thompson, Donald L ^a  

^a OKLAHOMA STATE UNIVERSITY   (United States)

^b SEMENOV INSTITUTE OF CHEMICAL PHYSICS   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001409412     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.472057     Document Type: Article

References (44)

1. (a) J, W. Brady, J. D. Doll, and D. L. Thompson, J. Chem. Phys. 73, 2767 (1980)
2. (b) 74, 1026 (1981)
3. (c) R. Viswanathan, D. L. Thompson, and L. M. Raff, ibid. 80, 4230 (1984)
4. (d) I. NoorBatcha, L. M. Raff, and D. L. Thompson, ibid. 84, 4341 (1986)
5. (e) B. M. Rice, L. M. Raff, and D. L. Thompson, ibid. 85, 4392 (1986)
6. (f) H. Gai, D. L, Thompson, and L. M. Raff, ibid. 88, 156 (1988)
7. (g) P. M. Agrawal, D. L. Thompson, and L. M. Raff, ibid. 89, 741 (1988)
8. (h) 92, 1069 (1990)
9. (i) T. D. Sewell and D. L. Thompson, ibid. 93, 4077 (1990)
10. (j) H. W. Schranz, L. M. Raff, and D. L. Thompson, ibid. 94, 4219 (1991)
11. (k) Chem. Phys. Lett. 182, 455 (1991), and references therein
12. (l) T, D. Sewell, H. W. Schranz, D. L. Thompson, and L. M. Raff, J. Chem. Phys, 95, 8089 (1991)
13. (m) D. C. Sorescu, D. L. Thompson, and L. M. Raff, ibid. 101, 3729 (1994)
14. (n) B. M. Rice, G. F. Adams, M. Page, and D, L. Thompson, J. Phys. Chem. 99, 5016 (1995)
15. (o) C. C. Chambers and D. L. Thompson, ibid. 99, 15881 (1995).
16. (a) O. K. Rice and H. C. Ramsperger, J. Am. Chem. Soc. 50, 617 (1928)
17. (b) L. S. Kassel, J. Phys. Chem. 32, 1065 (1928).
18. E. W. Schlag and R. D. Levine, Chem. Phys. Lett. 163, 523 (1989).
19. (a) D. L. Bunker and W. L. Hase, J. Chem. Phys. 59, 4673 (1973);
20. (b) D. L. Bunker and W. L. Hase, ibid. 69, 4711 (1978)
21. (c) W. L. Hase, in Potential Energy Surfaces and Dynamical Calculations, edited by D. G. Truhlar (Plenum, New York, 1981), p. 1
22. (d) W. L. Hase, in Dynamics of Molecular Collisions, edited by W. H. Miller (Plenum, New York, 1976), Vol. VIIB, p. 121.
23. See, for example: W. L. Hase, D. G. Buckowski, and K. N. Swamy, J. Phys. Chem. 87, 2754 (1983).
24. J. D. Doll, J. Chem. Phys. 73, 2760 (1980).
25. J. D. Doll, J. Chem. Phys. 74, 1074 (1981).
26. R. Viswanathan, L. M. Raff, and D. L. Thompson, J. Chem. Phys. 81, 828 (1984).
27. R. Viswanathan, L. M. Raff, and D. L. Thompson, J. Chem. Phys. 81, 3118 (1984).
28. E. E. Nikitin, Theory of Elementary Atomic and Molecular Processes in Gases (Clarendon, Oxford, 1974).
29. (a) G. M. Zaslavskii, R. Z. Sagdeev, Introduction into Nonlinear Physics (Moscow, Nauka, 1988)
30. (b) A. J. Lichtenberg, M. A. Liberman, Regular and Chaotic Dynamics (Springer, New York, 1992).
31. A. N. Kolmogorov, Usp. Mat. Nauk. 5, 5 (1938) (in Russian).
32. M. S. Green, J. Chem. Phys. 20, 1281 (1952).
33. M. S. Green, J. Chem. Phys. 22, 398 (1954).
34. S. E. Nigenda, D. F. McMillen, and D. Golden, J. Phys. Chem. 93, 1124 (1989).
35. Ya. G. Lazarou and P. Papagiannakopoulos, J. Phys. Chem. 94, 7114 (1990).
36. B. G. Sumpter and D. L. Thompson, J. Chem. Phys. 86, 3301 (1987).
37. B. G. Sumpter and D. L. Thompson, J. Chem. Phys. 88, 6889 (1988).
38. C. Trinquecoste, M. Rey-Lafon, and M.-T. Forel, Spectrochim. Acta Part A 30, 813 (1983).
39. N. Metropolis, A. W. Rosenbluth, M. N. Rosenbluth, A. H. Teller, and E. Teller, J. Chem. Phys. 21, 1087 (1953).
40. L. M. Raff and D. L. Thompson, in The Theory of Chemical Reaction Dynamics, edited by Michael Baer (CRC, Boca Raton, FL, 1985), p. 1.
41. J. W. Brady, J. D. Doll, and D. L. Thompson, in Potential Energy Surfaces and Dynamics Calculations, edited by D. G. Truhlar (Plenum, New York, 1979), p. 505.
42. L. M. Raff, R. Viswanathan, and D. L. Thompson, J. Chem. Phys. 80, 6141 (1984).
43. N. B. Slater, Theory of Unimolecular Reactions (Methuen, London, 1959).
44. K. L Bintz, D. L. Thompson, and J. W. Brady, Chem. Phys. Lett. 131, 398 (1986).