Novel ruthenium-catalyzed cross-carbonylation of alkynes and 2-norbornenes to hydroquinones

Organometallics

Volumn 17, Issue 4, 1998, Pages 766-769

  Suzuki, Nobuyoshi ^a   Kondo, Teruyuki ^a   Mitsudo, Take Aki ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001399141     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970880z     Document Type: Article

References (25)

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2. For reviews of the Pauson-Khand reaction, see: (a) Schore, N. E. In Comprehensive Organic Synthesis; Trost, B. M., Ed.; Pergamon: Oxford, 1991; Vol. 5, pp 1037-1064. (b) Schore, N. E. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, 1995; Vol. 12, pp 703-739.
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18. We have already found that W-methylpiperidine is the best solvent in several ruthenium-catalyzed reactions. (a) Mitsudo, T.; Zhang, S.-W.; Satake, N.; Kondo, T.; Watanabe, Y. Tetrahedron Lett. 1992, 33, 5533.
19. (b) Zhang, S.-W.; Mitsudo, T.; Kondo, T.; Watanabe, Y. J. Organomet. Chem. 1993, 450, 197. (c) Zhang, S.-W.; Mitsudo, T.; Kondo, T.; Watanabe, Y. J. Organomet. Chem. 1995, 485, 55.
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21. Excess norbornene substrates used in the present reaction can be recovered from the product mixture. For example, 3.1 mmol of 2-norbornene (41%) was recovered after the cross-carbonylation of 4-octyne with 2-norbornene.
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