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Tetrahedron Letters

Volumn 28, Issue 31, 1987, Pages 3547-3550

Biomimetic synthesis of a preclavulone a model

(4) Corey, E J a Ritter, Kurt a Yus, Miguel a Nájera, Carmen a

a HARVARD UNIVERSITY (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001389728 PISSN: 00404039 EISSN: None Source Type: Journal
DOI: 10.1016/S0040-4039(00)95531-X Document Type: Article

Times cited : (38)

References (21)

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3
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4
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5
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- E.J. Corey and S.P.T. Matsuda, Science, in press.

6
- 84919065124
- 2.

7
- 0004623550
- Disparate pathways of prostaglandin biosynthesis in coral and mammalian systems
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8
- 0002371298
- A Convenient Route to (E)-1-Alkenylsilanes via Isomerization of (Z)-1-Alkenylsilanes
- (1980) Synthesis , pp. 803
- Zweifel¹ Ong²

9
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- (1970) J. Org. Chem. , vol.35 , pp. 1839
- Sheng¹ Zajacek²

10
- 0002464862
- (1979) Aldrichim. Acta , vol.12 , pp. 63
- Sharpless¹

11
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- (1980) Tetrahedron , vol.36 , pp. 2269
- Chan¹ Ong²

12
- 0042568413
- (1976) Tetrahedron Letters , pp. 3253
- Chan¹ Ong² Mychajlowskij³

13
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- (1972) J. Am. Chem. Soc. , vol.94 , pp. 6190
- Corey¹ Venkateswarlu²

14
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- 12 were less effective for the transformation of 10 to 11.

15
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- See
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- Kuwajima¹ Nakamura²

16
- 84919065122
- −1 and ultraviolet absorption (hexane) at 218 (ε 4000) and 327 nm. Tlc mobilities on a silica gel plate were nearly the same, Rf 0.36 (20% ether in hexane).

17
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- The conversion of allenes to allene oxides and thence to 2-cyclopentenones via 2-oxidopentadienyl cation species, a zwitterionic version of the Nazarov reation, has been known for some time.
- (1969) Tetrahedron Letters , pp. 3269
- Grimaldi¹ Bertrand²

18
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- Grimaldi¹ Bertrand²

19
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- +), 95 (4%), 81 (5%).

20
- 84919065120
- Although trifluoroacetate is the best anionic leaving group found thus far, mesylate may be superior. The acetate and 2,6-dichlorobenzoate groups were found to be insufficiently activating.

21
- 84919065111
- This research was assisted financially by grants from the National Institutes of Health and the National Science Foundation. A NATO postdoctoral grant to Kurt Ritter is also gratefully acknowledged.

* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.