Synthesis of binaphthyl derivatives through radical cation formation

Journal of Organic Chemistry

Volumn 61, Issue 2, 1996, Pages 788-792

  Tanaka, Mutsuo ^a   Nakashima, Hideki ^b   Fujiwara, Masahiro ^a   Ando, Hisanori ^c   Souma, Yoshie ^a  

^a NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

^b OSAKA INSTITUTE OF TECHNOLOGY   (Japan)

^c RESEARCH INSTITUTE OF INNOVATIVE TECHNOLOGY FOR THE EARTH   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001382573     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo950814b     Document Type: Article

References (64)

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62. + reactions seem to proceed through inner- and outer-sphere reactions, respectively (see refs 12, 15, and 18a,e). We are now studying this problem using superacids.
63. 2 occurs to give nitro compounds.
64. +. Therefore, it is difficult to inhibit the nitration of produced binaphthyl derivatives by the addition of superacids because radical cations of binaphthyl derivatives are a secondary product.