Synthesis, Spectroscopy, and Redox Behavior of the Binuclear Complex Cation [Ni2(6,6′-spirobi(cyclam))]4+ (cyclam = 1,4,8,11-Tetraazacyclotetradecane): Characteristic of a Transient Ni(II)-Ni(III) Species

Inorganic Chemistry

Volumn 36, Issue 23, 1997, Pages 5376-5383

  McAuley, A ^a   Subramanian, S ^a  

^a UNIVERSITY OF VICTORIA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001378161     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic970327+     Document Type: Article

References (55)

1. (a) Lindvedt, R. L. In Copper Coordination Chemistry: Biochemical and Inorganic Perspectives; Karlin, K. D., Zubieta, J., Eds.; Adenine Press: New York, 1983.
2. (b) Lehn, J.-M. Pure Appl. Chem. 1980, 52, 2441-2459.
3. (c) Busch, D. H. Pure Appl. Chem. 1980, 52, 2477.
4. (a) Ciampolini, M.; Fabbrizzi, L.; Perotti, A.; Poggi, A.; Seghi, B.; Zanobini, F. Inorg. Chem. 1987, 20, 3527.
5. (b) Mandal, S. K.; Thompson, L. K.; Nag, K.; Charland, J.-P.; Gabe, E. J. Inorg. Chem. 1987, 26, 1391.
6. (a) Katsure, M. Bull. Chem. Soc. Jpn. 1988, 61, 1023.
7. (b) Buttafava, A.; Fabbrizzi, L.; Perotti, A.; Seghi, B. J. Chem. Soc., Chem. Commun. 1982, 1166.
8. (c) Reid, G.; Schroder, M. Chem. Soc. Rev. 1990, 19, 239-269.
9. (d) Schneider, R.; Riesen, R.; Kaden, T. A. Helv. Chim. Acta 1986, 69, 53.
10. (e) Murase, I.; Ueno, S.; Kida, S. Inorg. Chim. Acta 1986, 111, 57.
11. (f) Gisselbrechdt, J.-P.; Gross, M.; Albert, A. H.; Lehn, J.-M. Inorg. Chem. 1980, 19, 1386.
12. (g) McAuley, A.; Xu, C. Inorg. Chem. 1992, 31, 549 and references therein.
13. (h) Mochizuki, K.; Manaka, S.; Takeda, I.; Kondo, T. Inorg. Chem. 1996, 35, 5136 and references therein.
14. (a) Bencini, A.; Ganeschi, A.; Dei, A.; Gatteschi, D.; Zanchini, C.; Khan, O. Inorg. Chem. 1986, 25, 1374.
15. (b) Smith, T. D.; Pilbrow, J. R. Coord. Chem. Rev. 1974, 13, 173-278.
16. (a) Cave, R. J.; Skiers, P.; Marcus, R. A. J. Chem. Phys. 1986, 90, 1436.
17. (b) Cave, R.; Klipstein, S. J.; Marcus, R. A. J. Chem. Phys, 1986, 84, 3089.
18. (a) Fabbrizzi, L. Comments Inorg. Chem. 1985, 4 (1). 33 and references therein.
19. (b) Boyd, D. C.; Rodman, G. S.; Mann, K. R. J. Am. Chem. Soc. 1986, 108, 1779.
20. (c) Szalda, D. J.; Fujita, E.; Sanzenbacher, R.; Paulus, H.; Elias, H. Inorg. Chem. 1994, 33, 5855.
21. (a) Thom, V. J.; Boeyens, J. C. A.; McDougall, G. J.; Hancock, R. B. J. Am. Chem. Soc. 1984, 106, 3198.
22. (b) Haines, R. I.; McAuley, A. Coord. Chem. Rev. 1981, 39, 111.
23. (c) Busch, D. H. Pure Appl. Chem. 1980, 52, 2477.
24. (d) Suh, M. P. In Advances Inorg. Chem.; Karlin, K. D., Ed.; Academic Press: San Diego, 1997; Vol. 44, p 93.
25. (e) Hancock. R. D. Acc. Chem. Res. 1990, 23, 253.
26. Weber, E. Angew. Chem., Int. Ed. Engl. 1979, 18, 219.
27. McAuley, A.; Subramanian, S.; Whitcombe, T. W. J. Chem. Soc., Chem. Commun. 1987, 539.
28. (a) Bernhardt, P. V.; Comba, P.; Gahan, L. R.; Lawrence, G. A. Aust. J. Chem. 1990, 43, 2035.
29. (b) Don Levy, T. M.; Gahan, L. R.; Hambley, T. W.; Hanson, G. R.; Markiewicz, A.; Murray, K. S.; Swann, I. L.; Pickering, S. R. Aust. J. Chem. 1990, 43, 1407.
30. (c) Kim, J.; Lindoy, L. F.; Matthews, O. A.; Meehan, G. V.; Nachbaur, J.; Saini, V. Aust. J. Chem. 1995, 48, 1917-1924.
31. Czugler, M.; Weber, E. J. Chem. Soc., Chem. Commun. 1981, 472.
32. 4 have been prepared and characterized by LSIMS and microanalysis. A. McAuley and S. Subramanian, unpublished results.
33. (a) Desper, J. M.; Gellman, S. H.; Wolf, R. E., Jr.; Cooper, S. R. J. Am. Chem. Soc. 1991, 113, 8663.
34. (b) Hares, G. B.; Fernelius, W. C.; Douglas. B. E. J. Am. Chem. Soc. 1956, 78, 1816.
35. (c) Newman, M. S.; Busch, D. H.; Cheney, G. E.; Gustafson, C. R. Inorg. Chem. 1972, 11, 2890.
36. McAuley, A.; Beveridge, K.; Subramanian, S.; Whitcombe, T. W. Can. J. Chem. 1989, 67, 1657.
37. Sawyer, D. T.; Roberts, J. L., Jr. Experimental Electrochemistry for Chemists; John Wiley and Sons: New York, 1979.
38. Fabbrizzi, L.; Montagna, L.; Poggi, A; Kaden, Th. A.; Siegfried, L. C. J. Chem. Soc., Dalton Trans. 1987, 2631.
39. Gagne, R. R.; Koval, C. A.; Smith, T. J. J. Am. Chem. Soc. 1979, 101, 4571.
40. (a) Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamentals and Applications; John-Wiley and Sons: New York, 1987; pp 215-219.
41. (b) Geiger, W. E. In Progress in Inorganic Chemistry; Lippard, S. J., Ed.; John Wiley and Sons: New York, 1985; Vol. 33, pp 275-352.
42. Richardson, D. E.; Taube, H. Inorg. Chem. 1981, 20, 1279.
43. Anchini, A.; Fabbrizzi, L.; Paoletti, P.; Clay, R. M. Inorg. Chim. Acta 1977, 24, L21.
44. (a) Shachter, A. M.; Fleischer, E. B.; Haltiwartger, R. C. J. Chem Soc., Chem. Commun. 1988. 960.
45. (b) McAuley, A.; Subramanian, S.; Zaworotko, M. J. J. Chem. Soc., Chem. Commun. 1992, 1321.
46. (c) Kimura E.; Haruta, M.; Shionoya, M.; Takenouchi, K.; Iitaka, Y. Inorg. Chem. 1993, 32, 2779.
47. McAuley, A.; Beveridge, K.; Subramanian, S.; Whitcombe, T. W. J. Chem. Soc., Dalton Trans. 1991, 1821.
48. Buxton, G. V.; McAuley, A.; Subramanian, S. Unpublished results.
49. Buttafava, A.; Fabbrizzi, L.; Perotti, A.; Poli, G.; Seghi, B. Inorg. Chem. 1986, 25, 1456.
50. Sanzenbacher, R.; Elias, H. Inorg. Chim. Acta 1996, 246, 267.
51. Flanagan, J. B.; Margel, S.; Bard, A. J.; Anson, F. C. J. Am. Chem. Soc. 1978, 100, 4248.
52. Bond, A. M.; Oldham, K. B. J. Phys. Chem. 1983, 87C, 2493.
53. (a) Gagne, R. R.; Koval, C. A.; Lisensky, G. C. Inorg. Chem. 1980, 19, 2854.
54. (b) Sutton, J. E.; Sutton, P. M.; Taube, H. Inorg. Chem. 1979, 18, 1017.
55. 4+ species under identical conditions. McAuley, A.; Subraraanian, S. Unpublished results.