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Tetrahedron Letters

Volumn 30, Issue 16, 1989, Pages 2079-2082

Enantioselective synthesis of siloxycyclopropanes and of ???-oxocarboxylates by asymmetric catalysis

(2) Kunz, Thomas a Reissig, Hans Ulrich a

a DARMSTADT UNIVERSITY OF TECHNOLOGY (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001368954 PISSN: 00404039 EISSN: None Source Type: Journal
DOI: 10.1016/S0040-4039(01)93716-5 Document Type: Article

Times cited : (33)

References (23)

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11
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13
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- Semicorrin metal complexes as enantioselective catalysts. Part 2. Enantioselective cyclopropane formation from olefins with diazo compounds catalyzed by chiral (semicorrinato)copper complexes
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- Synthesis and ring cleavage of racemic 2 and 3
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16
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- Ringöffnungsreaktionen von 2-Siloxycyclopropancarbonsäuremethylestern zu 4-Oxoalkansäurederivaten
- It has been shown that no epimerization at centres α to carbonyl groups occurs during ring cleavage
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17
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20
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- R-Configuration at C-3 for both cyclopropane diastereomers of 2c should give an ee of 40% for 3c [0.75.46% + 0.25.26% = 40%]. S-Configuration at C-3 in the minor diastereomer should give an ee of only 28% [0.75.46% − 0.25.26% = 28%]. The analog calculations led to the other assignments given in the table.

21
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.