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Volumn 18, Issue 14, 1999, Pages 2633-2641

Organomolybdenum(VI) and lithium organomolybdate(VI) and -(V) complexes with C,N-chelating aminoaryl ligands

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0001367979     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9900364     Document Type: Article
Times cited : (23)

References (50)
  • 23
    • 24744434544 scopus 로고    scopus 로고
    • note
    • The amount of DME found in the lithium molybdates was strongly dependent upon the source of lithium reagent and workup procedure and could only partly be removed by evaporation.
  • 24
    • 24744439869 scopus 로고    scopus 로고
    • note
    • 2(C-N)R] compounds resulting from ligand exchange reactions. When 8 was heated, always small amounts of 2 were found. When 9 was heated, always small amounts of 2 and 4 were found and small amounts of 1-butene were detected as a result of β-H elimination reacions. When 10 was heated, always small amounts of 2 and 6 were found.
  • 32
    • 24744462251 scopus 로고    scopus 로고
    • note
    • We were unable to detect traces of "Mo-H" species during the process of β3-H elimination (monitored by NMR), probably due to the instability of the Mo-H bond.
  • 33
    • 24744451563 scopus 로고    scopus 로고
    • note
    • After the reaction all volatiles were collected in a cold trap, and the mixture was analyzed by NMR and GC-MS. We were unable to detect any products arising from butyl radicals, even when the reaction was carried out in the presence of a radical trap like TEMPO.
  • 42
    • 85088668672 scopus 로고    scopus 로고
    • note
    • 4I-4] and n-BuLi in toluene.
  • 45
    • 85088668400 scopus 로고    scopus 로고
    • note
    • 13C 2D heteronuclear NMR measurements.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.