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0001216279
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Examples of related complexes showing α-H agostic interactions are: (a) Poole, A. D.; Williams, D. N.; Kenwright, A. M.; Gibson, V. C.; Clegg, W.; Hockless, D. C. R.; O'Neil, P. A. Organometallics 1993, 12, 2549.
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23
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24744434544
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note
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The amount of DME found in the lithium molybdates was strongly dependent upon the source of lithium reagent and workup procedure and could only partly be removed by evaporation.
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24
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24744439869
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note
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2(C-N)R] compounds resulting from ligand exchange reactions. When 8 was heated, always small amounts of 2 were found. When 9 was heated, always small amounts of 2 and 4 were found and small amounts of 1-butene were detected as a result of β-H elimination reacions. When 10 was heated, always small amounts of 2 and 6 were found.
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26
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0029882334
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Schrock, R. R.; Luo, S.; Lee, J. C.; Zanetti, N. C.; Davis, W. M. J. Am. Chem. Soc. 1996, 118, 3883.
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0000382159
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(a) Rijnberg, E.; Jastrzebski, J. T. B. H.; Boersma, J.; Kooijman, H.; Veldman, N.; Spek, A. L.; van Koten, G. Organometallics 1997, 16, 2239.
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32
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24744462251
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note
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We were unable to detect traces of "Mo-H" species during the process of β3-H elimination (monitored by NMR), probably due to the instability of the Mo-H bond.
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-
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33
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24744451563
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note
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After the reaction all volatiles were collected in a cold trap, and the mixture was analyzed by NMR and GC-MS. We were unable to detect any products arising from butyl radicals, even when the reaction was carried out in the presence of a radical trap like TEMPO.
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36
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0003998388
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84988106732
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84989416124
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42
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85088668672
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note
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4I-4] and n-BuLi in toluene.
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43
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0001065336
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45
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85088668400
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note
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13C 2D heteronuclear NMR measurements.
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