Competitive nucleophilic attack at CO and Cβ of the allenyl group in [Fe2(CO)6(μ-PPh2)(μ-η 1:η2-(H)Cα=Cβ=C γH2)]. X-ray crystal structures of [Fe2 (CO)5(μ-PPh2)

Organometallics

Volumn 15, Issue 12, 1996, Pages 2688-2691

  Doherty, Simon ^a   Elsegood, Mark R J ^a   Clegg, William ^a   Waugh, Mark ^a  

^a NEWCASTLE UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001350219     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960079+     Document Type: Article

References (34)

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8. For recent comprehensive reviews see: (a) Wojcicki, A. New. J. Chem. 1994, 18, 61. (b) Doherty, S.; Corrigan, J. F.; Carty, A. J.; Sappa, E. Adv. Organomet. Chem. 1995, 37, 39. For Pd, Pt complexes: (c) Wouters, J. M. A.; Klein, R. A.; Elsevier, C. J.; Haming, L.; Stam, C. H. Organometallics 1994, 13, 4586. (d) Blosser, P. W.; Schimpff, D. G.; Gallucci, J. C.; Wojcicki, A. Organometallics 1993, 12, 1993. (e) Plantevin, V.; Blosser, P. W.; Gallucci, J. C.; Wojcicki, A. Organometallics 1994, 13, 3651. (f) Su, C.-C.; Chen, J.-T.; Lee, G.-H.; Wang, Y. J. Am. Chem. Soc. 1994, 116, 4999. For Pb complexes: (g) Seyferth, D.; Son, D. Y.; Shah, S. Organometallics 1994, 13, 2105. For binuclear complexes: (h) Nucciarone, D.; Taylor, N. J.; Carty, A. J. Organometallics 1986, 5, 1179. (i) Seyferth, D.; Womack, G. B.; Archer, C. M.; Dewan, J. C. Organometallics 1989, 8, 430. (j) Seyferth, D.; Archer, C. M.; Rushke, D. P.; Cowie, M.; Hilts, R. W. Organometallics 1991, 10, 3363.
9. For recent comprehensive reviews see: (a) Wojcicki, A. New. J. Chem. 1994, 18, 61. (b) Doherty, S.; Corrigan, J. F.; Carty, A. J.; Sappa, E. Adv. Organomet. Chem. 1995, 37, 39. For Pd, Pt complexes: (c) Wouters, J. M. A.; Klein, R. A.; Elsevier, C. J.; Haming, L.; Stam, C. H. Organometallics 1994, 13, 4586. (d) Blosser, P. W.; Schimpff, D. G.; Gallucci, J. C.; Wojcicki, A. Organometallics 1993, 12, 1993. (e) Plantevin, V.; Blosser, P. W.; Gallucci, J. C.; Wojcicki, A. Organometallics 1994, 13, 3651. (f) Su, C.-C.; Chen, J.-T.; Lee, G.-H.; Wang, Y. J. Am. Chem. Soc. 1994, 116, 4999. For Pb complexes: (g) Seyferth, D.; Son, D. Y.; Shah, S. Organometallics 1994, 13, 2105. For binuclear complexes: (h) Nucciarone, D.; Taylor, N. J.; Carty, A. J. Organometallics 1986, 5, 1179. (i) Seyferth, D.; Womack, G. B.; Archer, C. M.; Dewan, J. C. Organometallics 1989, 8, 430. (j) Seyferth, D.; Archer, C. M.; Rushke, D. P.; Cowie, M.; Hilts, R. W. Organometallics 1991, 10, 3363.
10. For recent comprehensive reviews see: (a) Wojcicki, A. New. J. Chem. 1994, 18, 61. (b) Doherty, S.; Corrigan, J. F.; Carty, A. J.; Sappa, E. Adv. Organomet. Chem. 1995, 37, 39. For Pd, Pt complexes: (c) Wouters, J. M. A.; Klein, R. A.; Elsevier, C. J.; Haming, L.; Stam, C. H. Organometallics 1994, 13, 4586. (d) Blosser, P. W.; Schimpff, D. G.; Gallucci, J. C.; Wojcicki, A. Organometallics 1993, 12, 1993. (e) Plantevin, V.; Blosser, P. W.; Gallucci, J. C.; Wojcicki, A. Organometallics 1994, 13, 3651. (f) Su, C.-C.; Chen, J.-T.; Lee, G.-H.; Wang, Y. J. Am. Chem. Soc. 1994, 116, 4999. For Pb complexes: (g) Seyferth, D.; Son, D. Y.; Shah, S. Organometallics 1994, 13, 2105. For binuclear complexes: (h) Nucciarone, D.; Taylor, N. J.; Carty, A. J. Organometallics 1986, 5, 1179. (i) Seyferth, D.; Womack, G. B.; Archer, C. M.; Dewan, J. C. Organometallics 1989, 8, 430. (j) Seyferth, D.; Archer, C. M.; Rushke, D. P.; Cowie, M.; Hilts, R. W. Organometallics 1991, 10, 3363.
11. For recent comprehensive reviews see: (a) Wojcicki, A. New. J. Chem. 1994, 18, 61. (b) Doherty, S.; Corrigan, J. F.; Carty, A. J.; Sappa, E. Adv. Organomet. Chem. 1995, 37, 39. For Pd, Pt complexes: (c) Wouters, J. M. A.; Klein, R. A.; Elsevier, C. J.; Haming, L.; Stam, C. H. Organometallics 1994, 13, 4586. (d) Blosser, P. W.; Schimpff, D. G.; Gallucci, J. C.; Wojcicki, A. Organometallics 1993, 12, 1993. (e) Plantevin, V.; Blosser, P. W.; Gallucci, J. C.; Wojcicki, A. Organometallics 1994, 13, 3651. (f) Su, C.-C.; Chen, J.-T.; Lee, G.-H.; Wang, Y. J. Am. Chem. Soc. 1994, 116, 4999. For Pb complexes: (g) Seyferth, D.; Son, D. Y.; Shah, S. Organometallics 1994, 13, 2105. For binuclear complexes: (h) Nucciarone, D.; Taylor, N. J.; Carty, A. J. Organometallics 1986, 5, 1179. (i) Seyferth, D.; Womack, G. B.; Archer, C. M.; Dewan, J. C. Organometallics 1989, 8, 430. (j) Seyferth, D.; Archer, C. M.; Rushke, D. P.; Cowie, M.; Hilts, R. W. Organometallics 1991, 10, 3363.
12. For recent comprehensive reviews see: (a) Wojcicki, A. New. J. Chem. 1994, 18, 61. (b) Doherty, S.; Corrigan, J. F.; Carty, A. J.; Sappa, E. Adv. Organomet. Chem. 1995, 37, 39. For Pd, Pt complexes: (c) Wouters, J. M. A.; Klein, R. A.; Elsevier, C. J.; Haming, L.; Stam, C. H. Organometallics 1994, 13, 4586. (d) Blosser, P. W.; Schimpff, D. G.; Gallucci, J. C.; Wojcicki, A. Organometallics 1993, 12, 1993. (e) Plantevin, V.; Blosser, P. W.; Gallucci, J. C.; Wojcicki, A. Organometallics 1994, 13, 3651. (f) Su, C.-C.; Chen, J.-T.; Lee, G.-H.; Wang, Y. J. Am. Chem. Soc. 1994, 116, 4999. For Pb complexes: (g) Seyferth, D.; Son, D. Y.; Shah, S. Organometallics 1994, 13, 2105. For binuclear complexes: (h) Nucciarone, D.; Taylor, N. J.; Carty, A. J. Organometallics 1986, 5, 1179. (i) Seyferth, D.; Womack, G. B.; Archer, C. M.; Dewan, J. C. Organometallics 1989, 8, 430. (j) Seyferth, D.; Archer, C. M.; Rushke, D. P.; Cowie, M.; Hilts, R. W. Organometallics 1991, 10, 3363.
13. For recent comprehensive reviews see: (a) Wojcicki, A. New. J. Chem. 1994, 18, 61. (b) Doherty, S.; Corrigan, J. F.; Carty, A. J.; Sappa, E. Adv. Organomet. Chem. 1995, 37, 39. For Pd, Pt complexes: (c) Wouters, J. M. A.; Klein, R. A.; Elsevier, C. J.; Haming, L.; Stam, C. H. Organometallics 1994, 13, 4586. (d) Blosser, P. W.; Schimpff, D. G.; Gallucci, J. C.; Wojcicki, A. Organometallics 1993, 12, 1993. (e) Plantevin, V.; Blosser, P. W.; Gallucci, J. C.; Wojcicki, A. Organometallics 1994, 13, 3651. (f) Su, C.-C.; Chen, J.-T.; Lee, G.-H.; Wang, Y. J. Am. Chem. Soc. 1994, 116, 4999. For Pb complexes: (g) Seyferth, D.; Son, D. Y.; Shah, S. Organometallics 1994, 13, 2105. For binuclear complexes: (h) Nucciarone, D.; Taylor, N. J.; Carty, A. J. Organometallics 1986, 5, 1179. (i) Seyferth, D.; Womack, G. B.; Archer, C. M.; Dewan, J. C. Organometallics 1989, 8, 430. (j) Seyferth, D.; Archer, C. M.; Rushke, D. P.; Cowie, M.; Hilts, R. W. Organometallics 1991, 10, 3363.
14. For recent comprehensive reviews see: (a) Wojcicki, A. New. J. Chem. 1994, 18, 61. (b) Doherty, S.; Corrigan, J. F.; Carty, A. J.; Sappa, E. Adv. Organomet. Chem. 1995, 37, 39. For Pd, Pt complexes: (c) Wouters, J. M. A.; Klein, R. A.; Elsevier, C. J.; Haming, L.; Stam, C. H. Organometallics 1994, 13, 4586. (d) Blosser, P. W.; Schimpff, D. G.; Gallucci, J. C.; Wojcicki, A. Organometallics 1993, 12, 1993. (e) Plantevin, V.; Blosser, P. W.; Gallucci, J. C.; Wojcicki, A. Organometallics 1994, 13, 3651. (f) Su, C.-C.; Chen, J.-T.; Lee, G.-H.; Wang, Y. J. Am. Chem. Soc. 1994, 116, 4999. For Pb complexes: (g) Seyferth, D.; Son, D. Y.; Shah, S. Organometallics 1994, 13, 2105. For binuclear complexes: (h) Nucciarone, D.; Taylor, N. J.; Carty, A. J. Organometallics 1986, 5, 1179. (i) Seyferth, D.; Womack, G. B.; Archer, C. M.; Dewan, J. C. Organometallics 1989, 8, 430. (j) Seyferth, D.; Archer, C. M.; Rushke, D. P.; Cowie, M.; Hilts, R. W. Organometallics 1991, 10, 3363.
15. For recent comprehensive reviews see: (a) Wojcicki, A. New. J. Chem. 1994, 18, 61. (b) Doherty, S.; Corrigan, J. F.; Carty, A. J.; Sappa, E. Adv. Organomet. Chem. 1995, 37, 39. For Pd, Pt complexes: (c) Wouters, J. M. A.; Klein, R. A.; Elsevier, C. J.; Haming, L.; Stam, C. H. Organometallics 1994, 13, 4586. (d) Blosser, P. W.; Schimpff, D. G.; Gallucci, J. C.; Wojcicki, A. Organometallics 1993, 12, 1993. (e) Plantevin, V.; Blosser, P. W.; Gallucci, J. C.; Wojcicki, A. Organometallics 1994, 13, 3651. (f) Su, C.-C.; Chen, J.-T.; Lee, G.-H.; Wang, Y. J. Am. Chem. Soc. 1994, 116, 4999. For Pb complexes: (g) Seyferth, D.; Son, D. Y.; Shah, S. Organometallics 1994, 13, 2105. For binuclear complexes: (h) Nucciarone, D.; Taylor, N. J.; Carty, A. J. Organometallics 1986, 5, 1179. (i) Seyferth, D.; Womack, G. B.; Archer, C. M.; Dewan, J. C. Organometallics 1989, 8, 430. (j) Seyferth, D.; Archer, C. M.; Rushke, D. P.; Cowie, M.; Hilts, R. W. Organometallics 1991, 10, 3363.
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17. Huang, T.-M.; Hsu, R.-H.; Yang, C.-S.; Chen, J.-T.; Lee, G.-H.; Wang, Y. Organometallics 1994, 13, 3657.
18. Breckenridge, S. M.; Taylor, N. J.; Carty, A. J. Organometallics 1991, 10, 837.
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22. Carleton, N.; Corrigan, J. F.; Doherty, S.; Pixneur, R.; Sun, Y.; Taylor, N. J.; Carty, A. J. Organometallics 1994, 13, 4179.
23. Blenkiron, P.; Corrigan, J. F.; Doherty, S.; Taylor, N. J.; Carty, A. J. Unpublished results.
24. Ogoshi, S.; Tsutsumi, K.; Ooi, M.; Kurosawa, H. J. Am. Chem. Soc. 1995, 117, 10415.
25. Doherty, S.; Elsegood, M. R. J.; Clegg, W.; Scanlan, T. H. J. Chem. Soc., Chem. Commun., submitted for publication.
26. Breckenridge, S. M.; MacLaughlin, S. A.; Taylor, N. J.; Carty, A. J. J. Chem. Soc., Chem. Commun. 1991, 1718.
27. d=C).
28. 3N: C, 54.01; H, 4.54; N, 4.35. Found: C, 53.60; H, 4.32; N, 4.21.
29. -3, close to Fe atoms.
30. (a) Hogarth, H.; Lavender, M. H. J. Chem. Soc., Dalton Trans. 1994, 3389.
31. MacLaughlin, S. A.; Doherty, S.; Taylor, N. J.; Carty, A. J. Organometaliics 1992, 11, 4315.
32. Tseng, T.-W.; Wu, I.-Y.; Tsai, J.-H.; Lin, Y.-C.; Cheng, D.-J.; Lee, G.-H.; Chen, M.-C.; Wang, Y. Organometallics 1994, 13, 3963.
33. Cherkas, A. A.; Breckenridge, S. M.; Carty, A. J. Polyhedron 1992, 11, 107.
34. -3, racemic twinning indicated by absolute structure parameter of 0.560-(10) (Flack, H. D. Acta Crystallogr., Sect. A 1983, 39, 876).