Theory of desorption induced by electronic transitions. II. The strong interaction regime

Journal of Chemical Physics

Volumn 107, Issue 20, 1997, Pages 8627-8636

  Seideman, Tamar ^a,c   Guo, Hua ^b  

^a HARVARD UNIVERSITY   (United States)

^b UNIVERSITY OF TOLEDO   (United States)

^c NATIONAL RESEARCH COUNCIL CANADA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001345391     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.475015     Document Type: Article

References (82)

1. For reviews see (a) Desorption Induced by Electronic Transitions DIET V, edited by A. R. Burns, E. B. Stechel and D. R. Jennison (Springer-Verlag, Berlin, 1993) and earlier volumes (b) Laser Spectroscopy and Photochemistry on Metal Surfaces, edited by H. Dai and W. Ho, Advanced Series in Physical Chemistry (World Scientific, London, 1995), Vol. 5 (c) P. Avouris and R. E. Walkup, Annu. Rev. Phys. Chem. 40, 173 (1989); X.-L. Zhou, X.-Y. Zhu, and J. M. White, Surf. Sci. Rep. 13, 73 (1991); J. A. Misewich, T. F. Heinz, P. Weigand, and A. Kalamarides, in Laser Spectroscopy and Photochemistry on Metal Surfaces, edited by H.-L. Dai and W. Ho (World Scientific, Singapore, 1995).
2. For reviews see (a) Desorption Induced by Electronic Transitions DIET V, edited by A. R. Burns, E. B. Stechel and D. R. Jennison (Springer-Verlag, Berlin, 1993) and earlier volumes (b) Laser Spectroscopy and Photochemistry on Metal Surfaces, edited by H. Dai and W. Ho, Advanced Series in Physical Chemistry (World Scientific, London, 1995), Vol. 5 (c) P. Avouris and R. E. Walkup, Annu. Rev. Phys. Chem. 40, 173 (1989); X.-L. Zhou, X.-Y. Zhu, and J. M. White, Surf. Sci. Rep. 13, 73 (1991); J. A. Misewich, T. F. Heinz, P. Weigand, and A. Kalamarides, in Laser Spectroscopy and Photochemistry on Metal Surfaces, edited by H.-L. Dai and W. Ho (World Scientific, Singapore, 1995).
3. For reviews see (a) Desorption Induced by Electronic Transitions DIET V, edited by A. R. Burns, E. B. Stechel and D. R. Jennison (Springer-Verlag, Berlin, 1993) and earlier volumes (b) Laser Spectroscopy and Photochemistry on Metal Surfaces, edited by H. Dai and W. Ho, Advanced Series in Physical Chemistry (World Scientific, London, 1995), Vol. 5 (c) P. Avouris and R. E. Walkup, Annu. Rev. Phys. Chem. 40, 173 (1989); X.-L. Zhou, X.-Y. Zhu, and J. M. White, Surf. Sci. Rep. 13, 73 (1991); J. A. Misewich, T. F. Heinz, P. Weigand, and A. Kalamarides, in Laser Spectroscopy and Photochemistry on Metal Surfaces, edited by H.-L. Dai and W. Ho (World Scientific, Singapore, 1995).
4. For reviews see (a) Desorption Induced by Electronic Transitions DIET V, edited by A. R. Burns, E. B. Stechel and D. R. Jennison (Springer-Verlag, Berlin, 1993) and earlier volumes (b) Laser Spectroscopy and Photochemistry on Metal Surfaces, edited by H. Dai and W. Ho, Advanced Series in Physical Chemistry (World Scientific, London, 1995), Vol. 5 (c) P. Avouris and R. E. Walkup, Annu. Rev. Phys. Chem. 40, 173 (1989); X.-L. Zhou, X.-Y. Zhu, and J. M. White, Surf. Sci. Rep. 13, 73 (1991); J. A. Misewich, T. F. Heinz, P. Weigand, and A. Kalamarides, in Laser Spectroscopy and Photochemistry on Metal Surfaces, edited by H.-L. Dai and W. Ho (World Scientific, Singapore, 1995).
5. For reviews see (a) Desorption Induced by Electronic Transitions DIET V, edited by A. R. Burns, E. B. Stechel and D. R. Jennison (Springer-Verlag, Berlin, 1993) and earlier volumes (b) Laser Spectroscopy and Photochemistry on Metal Surfaces, edited by H. Dai and W. Ho, Advanced Series in Physical Chemistry (World Scientific, London, 1995), Vol. 5 (c) P. Avouris and R. E. Walkup, Annu. Rev. Phys. Chem. 40, 173 (1989); X.-L. Zhou, X.-Y. Zhu, and J. M. White, Surf. Sci. Rep. 13, 73 (1991); J. A. Misewich, T. F. Heinz, P. Weigand, and A. Kalamarides, in Laser Spectroscopy and Photochemistry on Metal Surfaces, edited by H.-L. Dai and W. Ho (World Scientific, Singapore, 1995).
6. O. L. Bourne, D. Hart, D. M. Rayner, and P. A. Hackett, J. Vac. Sci. Technol. B 11, 556 (1993).
7. T. Seideman, J. Chem. Phys. 106, 2881 (1997); T. Seideman, Phys. Rev. A (in press).
8. T. Seideman, J. Chem. Phys. 106, 2881 (1997); T. Seideman, Phys. Rev. A (in press).
9. J. W. Gadzuk, Phys. Rev. B 44, 13 466 (1991); J. W. Gadzuk and S. Holloway, Phys. Scr. 32, 413 (1985).
10. J. W. Gadzuk, Phys. Rev. B 44, 13 466 (1991); J. W. Gadzuk and S. Holloway, Phys. Scr. 32, 413 (1985).
11. J. W. Gadzuk, L. J. Richter, S. A. Buntin, D. S. King, and R. R. Cavanagh, Surf. Sci. 235, 317 (1990).
12. 6(a) J. W. Gadzuk, Phys. Rev. Lett. 76, 4234 (1996)
13. (b) J. W. Gadzuk, Surf. Sci. 342, 342 (1995).
14. 7(a) W. Brenig, Z. Phys. B 23, 361 (1976)
15. (b) P. Schuck and W. Brenig, ibid. 46, 137 (1982).
16. Z. W. Gortel, R. Teshima, and H. J. Kreuzer, Phys. Rev. B 37, 3183 (1988).
17. P. Saalfrank, Chem. Phys. 193, 119 (1995).
18. P. Saalfrank, Chem. Phys. 211, 267 (1996).
19. 11(a) T. Klüner, H. J. Freund, J. Freitag, and V. Staemmler, J. Chem. Phys. 104, 10 030 (1996)
20. (b) T. Klüner (private communication).
21. E. Hasselbrink, Chem. Phys. Lett. 170, 329 (1990).
22. J. A. Misewich, T. F. Heinz, and D. M. Newns, Phys. Rev. Lett. 68, 3737 (1992).
23. D. M. Newns, T. F. Heinz, and J. A. Misewich, Prog. Theo. Phys. Supp 106, 441 (1991).
24. M. Brandbyge, P. Hedegard, T. F. Heinz, J. A. Misewich, and D. M. Newns, Phys. Rev. B 52, 6042 (1995).
25. E. B. Stechel, D. R. Jennison, and A. R. Burns, in Desorption Induced by Electronic Transitions, DIET III, edited by R. H. Stulen and M. L. Knotek (Springer-Verlag, Berlin, 1988), pp. 136.
26. 17(a) P. Saalfrank, R. Baer, and R. Kosloff, Chem. Phys. Lett. 230, 463 (1994)
27. (b) P. Saalfrank and R. Kosloff, J. Chem. Phys. 105, 2441 (1996).
28. C. Springer, M. Head-Gordon, and J. C. Tully, Surf. Sci. 320, L57 (1994).
29. N. Chakrabarti, V. Balasubramanian, N. Sathyamurthy, and J. W. Gadzuk, Chem. Phys. Lett. 242, 490 (1995).
30. S. M. Harris, S. Holloway, and G. R. Darling, J. Chem. Phys. 102, 8235 (1995)
31. H. Guo, Chem. Phys. Lett. 240, 393 (1995).
32. P. Saalfrank, S. Holloway, and G. R. Darling, J. Chem. Phys. 103, 6720 (1995).
33. H. Guo and T. Seideman, J. Chem. Phys. 103, 9062 (1995).
34. L. Liu, H. Guo, and T. Seideman, J. Chem. Phys. 104, 8757 (1996).
35. H. Guo, J. Chem. Phys. 106, 1967 (1997).
36. H. Guo and L. Liu, Surf. Sci. 372, 337 (1997).
37. T. Seideman, J. Chem. Phys. 106, 417 (1997).
38. S. A. Buntin, L. J. Richter, R. R. Cavanagh, and D. S. King, Phys. Rev. Lett. 61, 1321 (1988); L. J. Richter, S. A. Buntin, R. R. Cavanagh, and D. S. King, J. Chem. Phys. 89, 5344 (1988); S. A. Buntin, L. J. Richter, D. S. King and R. R. Cavanagh, ibid. 91, 6429 (1989).
39. S. A. Buntin, L. J. Richter, R. R. Cavanagh, and D. S. King, Phys. Rev. Lett. 61, 1321 (1988); L. J. Richter, S. A. Buntin, R. R. Cavanagh, and D. S. King, J. Chem. Phys. 89, 5344 (1988); S. A. Buntin, L. J. Richter, D. S. King and R. R. Cavanagh, ibid. 91, 6429 (1989).
40. S. A. Buntin, L. J. Richter, R. R. Cavanagh, and D. S. King, Phys. Rev. Lett. 61, 1321 (1988); L. J. Richter, S. A. Buntin, R. R. Cavanagh, and D. S. King, J. Chem. Phys. 89, 5344 (1988); S. A. Buntin, L. J. Richter, D. S. King and R. R. Cavanagh, ibid. 91, 6429 (1989).
41. M. Wolf, S. Nettesheim, J. M. White, E. Hasselbrink, and G. Ertl, J. Chem. Phys. '94, 4609 (1991).
42. 30I. Harrison, V. A. Ukraintsev, and A. N. Artsyukhovich, SPIE Proc. 2125 Laser Techniques for Surface Science, edited by H.-L. Dai and S. J. Sibener, 285 (1994).
43. D. P. Masson, E. J. Lanzendorf, and A. C. Kummel, J. Chem. Phys. 102, 9096 (1995).
44. X.-Y. Zhu and J. M. White, Phys. Rev. Lett. 68, 3359 (1992); X.-Y. Zhu, M. Wolf, T. Huett and J. M. White, J. Chem. Phys. 97, 5868 (1992).
45. X.-Y. Zhu and J. M. White, Phys. Rev. Lett. 68, 3359 (1992); X.-Y. Zhu, M. Wolf, T. Huett and J. M. White, J. Chem. Phys. 97, 5868 (1992).
46. F. M. Zimmermann and W. Ho, Surf. Sci. Rep. 22, 127 (1995).
47. T. Hertel, M. Wolf, and G. Ertl, J. Chem. Phys. 102, 3414 (1995).
48. W. Nessler, K.-H. Bornscheuer, T. Hertel, and E. Hasselbrink, Chem. Phys. 205, 205 (1996).
49. 36(a) J. A. Prybyla, T. F. Heinz, J. A. Misewich, M. M. T. Loy, and J. H. Glownia, Phys. Rev. Lett. 64, 1537 (1990)
50. (b) F. Budde, T. F. Heinz, M. M. T. Loy, J. A. Misewich, F. de Rougemont, and H. Zacharias, Phys. Rev. Lett. 66, 3024 (1991)
51. F. Budde, T. F. Heinz, A. Kalamarides, M. M. T. Loy, and J. A. Misewich, Surf. Sci. 283, 143 (1993).
52. J. A. Prybyla, W. K. Tom, and G. D. Aumiller, Phys. Rev. Lett. 68, 503 (1992).
53. J. A. Misewich, A. Kalamarides, T. F. Heinz, U. Höfer, and M. M. T. Loy, J. Chem. Phys. 100, 736 (1994).
54. 39(a) S. Deliwala, R. J. Finlay, J. R. Goldman, T.-H. Her, W. D. Mieher, and E. Mazur, Chem. Phys. Lett. 242, 617 (1995)
55. (b) R. J. Finlay, S. Deliwala, J. R. Goldman, T.-H. Her, W. D. Mieher, C. Wu, and E. Mazur, SPIE Proc. 2547, 218 (1995)
56. R. J. Finlay, T.-H. Her, S. Deliwala, W. D. Mieher, C. Wu, and E. Mazur, in Femtochemistry: Ultrafast Chemical and Physical Processes in Molecular Systems, edited by M. Chergui (World Scientific, Singapore, 1996), p. 457
57. R. J. Finlay, T.-H. Her, C. Wu, and E. Mazur (submitted).
58. 40(a) F.-J. Kao, D. G. Busch, D. Gomes da Costa, and W. Ho, Phys. Rev. Lett. 70, 4098 (1993)
59. (b) F.-J. Kao, D. G. Busch, D. Cohen, D. Gomes da Costa, and W. Ho, Phys. Rev. Lett. 71, 2094 (1993)
60. D. G. Busch, S. Gao, R. A. Pelak, M. F. Booth, and W. Ho, Phys. Rev. Lett. 75, 673 (1995)
61. R. A. Pelak, M. F. Booth, D. G. Busch, S. Gao, and W. Ho, SPIE Proc. 2547, 62 (1995)
62. (e) D. G. Busch, and W. Ho, Phys. Rev. Lett. 77, 1338 (1996).
63. An exception is discussed by Th. Mull, B. Baumeister, M. Menges, H.-J. Freund, D. Weide, C. Fischer and P. Andresen, J. Chem. Phys. 96, 7108 (1992), who observed substrate-mediated desorption of NO from a NiO surface.
64. For an experimental review of photochemistry on insulator surfaces see, for instance, J. C. Polanyi and H. Rieley, in Dynamics of Gas-Surface Interactions, edited by C. T. Rettner and M. N. R. Ashfold (The Royal Society of Chemistry, Cambridge, 1991). For a theoretical review see, for instance, H. Guo and J. V. Setzler, Hetero. Chem. Rev. 2, 17 (1995).
65. For an experimental review of photochemistry on insulator surfaces see, for instance, J. C. Polanyi and H. Rieley, in Dynamics of Gas-Surface Interactions, edited by C. T. Rettner and M. N. R. Ashfold (The Royal Society of Chemistry, Cambridge, 1991). For a theoretical review see, for instance, H. Guo and J. V. Setzler, Hetero. Chem. Rev. 2, 17 (1995).
66. An exception is discussed by K. Watanabe, K. Sawabe, and Y. Matsumoto, Phys. Rev. Lett. 76, 1751 (1996), who observe direct excitation in photodesorption of methane from a Pt surface.
67. D. Menzel and R. Gomer, J. Chem. Phys. 41, 3311 (1964); P. A. Redhead, Can. J. Phys. 42, 886 (1964).
68. D. Menzel and R. Gomer, J. Chem. Phys. 41, 3311 (1964); P. A. Redhead, Can. J. Phys. 42, 886 (1964).
69. P. R. Antoniewicz, Phys. Rev. B 21, 3811 (1980).
70. For a review of ESD see R. D. Ramsier and J. T. Yates, Jr., in Dynamics of Gas-Surface Interactions, edited by C. T. Rettner and M. N. R. Ashfold (The Royal Society of Chemistry, Cambridge, 1991), p. 257.
71. C. Klauber, M. D. Alvey, and J. T. Yates, Jr., Surf. Sci 154, 139 (1985).
72. A. R. Burns, E. B. Stechel and D. R. Jennison, Phys. Rev. Lett. 58, 250 (1987); A. R. Burns, D. R. Jennison, E. B. Stechel and Y. S. Li, ibid. 72, 3895 (1994); A. R. Burns, E. B. Stechel, D. R. Jennison and Y. S. Li, J. Chem. Phys. 101, 6318 (1994).
73. A. R. Burns, E. B. Stechel and D. R. Jennison, Phys. Rev. Lett. 58, 250 (1987); A. R. Burns, D. R. Jennison, E. B. Stechel and Y. S. Li, ibid. 72, 3895 (1994); A. R. Burns, E. B. Stechel, D. R. Jennison and Y. S. Li, J. Chem. Phys. 101, 6318 (1994).
74. A. R. Burns, E. B. Stechel and D. R. Jennison, Phys. Rev. Lett. 58, 250 (1987); A. R. Burns, D. R. Jennison, E. B. Stechel and Y. S. Li, ibid. 72, 3895 (1994); A. R. Burns, E. B. Stechel, D. R. Jennison and Y. S. Li, J. Chem. Phys. 101, 6318 (1994).
75. P. Feulner, D. Menzel, H. J. Kreuzer, and Z. W. Gortel, Phys. Rev. Lett. 53, 671 (1984).
76. P. B. Corkum, F. Brunel, N. K. Sherman, and T. Srinivasan-Rao, Phys. Rev. Lett. 61, 2886 (1988).
77. S. I. Anisimov, B. L. Kapeliovich and T. L. Perel'man, Sov. Phys.-JETP 39, 375 (1974).
78. It is worth distinguishing between electronically direct vs resonance-mediated dynamics and vibrationally direct vs resonance-mediated dynamics. The electronically excited resonance decays on a femtosecond time scale while vibrationally excited resonances, when present, decay on a picosecond time scale.
79. R. L. Lingle, Jr., N.-H. Ge, R. E. Jordan, J. D. McNeil, and C. B. Harris, Chem. Phys. 205, 191 (1996).
80. T.-C. Shen, C. Wang, G. C. Abeln, J. R. Tucker, J. W. Lyding, Ph. Avouris, and R. E. Walkup, Science 268, 1590 (1995).
81. W. S. Fann, R. Storz, H. W. K. Tom, and J. Bokor, Phys. Rev. Lett. 68, 2834 (1992).
82. F. Weik, A. de Meijere, and E, Hasselbrink, J. Chem. Phys. 99, 682 (1993).