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Volumn 66, Issue 11, 1977, Pages 5054-5058

Laser photoelectron spectrometry of FeO-: Electron affinity, electronic state separations, and ground state vibrations of iron oxide, and a new ground state assignment

(2) Engelking, P C a Lineberger, W C a

a NONE

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001343043 PISSN: 00219606 EISSN: None Source Type: Journal
DOI: 10.1063/1.433811 Document Type: Article

Times cited : (79)

References (23)

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- III obtain this same state ordering with a larger, [formula omitted] state separation (private communication, to be published). They also predict a [formula omitted] symmetry for the negative ion, and a change in bond length of [formula omitted] about that observed
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- Of the 25 transitions in the region [formula omitted] that West and Broida and Bass and Benedict concurrently designate, there is a systematic shift of [formula omitted] to higher wave‐numbers in West and Broida’s data, while about this there is an rms deviation of [formula omitted] If this is taken as the inherent variability of the assignments, and if [formula omitted] is allowed for spin‐orbit splittings, [formula omitted] effects, and the sensitivity of the bandheads to changes in the rotational constants with vibrational levels, [formula omitted] variability in the differences between Deslandres table entries can be tolerated within the data. The actual e‐X (e‐d) Deslandres table (Table IV) gives a fit of [formula omitted] while [formula omitted] The somewhat larger standard deviation on the [formula omitted] reflects a nonnegligible [formula omitted] dependence of vibrational spacing on vibrational quantum number. In fact, fitting the data this way gives [formula omitted] with [formula omitted]

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