Synthesis of highly lodinated icosahedral mono- and dicarbon carboranes

Journal of Organic Chemistry

Volumn 61, Issue 25, 1996, Pages 9041-9044

  Srivastava, Rajiv R ^a   Hamlin, Donald K ^a   Scott Wilbur, D ^a  

^a UNIVERSITY OF WASHINGTON SCHOOL OF MEDICINE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001329148     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo961560c     Document Type: Article

References (36)

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34. N,N-Dimethylamino-l-carbaborane was also periodinated, but a mixture of two compounds was obtained (1:3 ratio by HPLC). Attempts to purify this mixture were unsuccessful. It is likely that the minor product is the monomethyl amine as it is known that demethylation can occur with iodine, and the 'H NMR was consistent with this.
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