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Volumn 103, Issue 27, 1999, Pages 5369-5372

Acceleration of Bimolecular Reactions by Solvent Viscosity

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Indexed keywords


EID: 0001325350     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp991066n     Document Type: Article
Times cited : (32)

References (42)
  • 1
    • 0033583113 scopus 로고    scopus 로고
    • Vibrational Activation V. Paper IV: Catalysis of Claisen Rearrangement by Low-MW Polyethylene
    • Vibrational Activation V. Paper IV: Catalysis of Claisen Rearrangement by Low-MW Polyethylene. Swiss, K. A.; Firestone, R. A. J. Org. Chem. 1999, 64, 2158.
    • (1999) J. Org. Chem. , vol.64 , pp. 2158
    • Swiss, K.A.1    Firestone, R.A.2
  • 19
    • 0042690907 scopus 로고    scopus 로고
    • Our interpretation, not the authors'
    • Our interpretation, not the authors'.
  • 33
    • 0041689081 scopus 로고    scopus 로고
    • To be published in a separate article
    • To be published in a separate article.
  • 34
    • 0042189753 scopus 로고    scopus 로고
    • note
    • The downward slope in rates beyond 1-2 cP in reactions 1 and 2 and under pressure were regarded at first as incursions into the encounter-controlled regime. However, it was pointed out that this ought to occur only at higher viscosity and suggested instead that the viscous solvents limit the relative freedom of movement of the reactants in the microenvironment of the encounter pair while having no critical influence on the diffusion of the reactants in the bulk solution. We thank Dr. Keith U. Ingold for this suggestion.
  • 35
    • 27744467601 scopus 로고
    • Based on comparison of the slope of k vs η for reaction 1 and for P vs η in common solvents with the slope of k vs P in Diels-Alder reactions; for a review of volumes of activation see: Asano, T.; le Noble, W. J. Chem. Rev. 1978, 78, 407.
    • (1978) Chem. Rev. , vol.78 , pp. 407
    • Asano, T.1    Le Noble, W.J.2
  • 36
    • 0000421878 scopus 로고
    • Pauling, L. Nature 1948, 161, 707. Wolfenden, R. Acc. Chem. Res. 1972, 5, 10. Page, M. I. Int. J. Biochem. 1979, 10, 471.
    • (1948) Nature , vol.161 , pp. 707
    • Pauling, L.1
  • 37
    • 0002903441 scopus 로고
    • Pauling, L. Nature 1948, 161, 707. Wolfenden, R. Acc. Chem. Res. 1972, 5, 10. Page, M. I. Int. J. Biochem. 1979, 10, 471.
    • (1972) Acc. Chem. Res. , vol.5 , pp. 10
    • Wolfenden, R.1
  • 38
    • 0018417183 scopus 로고
    • Pauling, L. Nature 1948, 161, 707. Wolfenden, R. Acc. Chem. Res. 1972, 5, 10. Page, M. I. Int. J. Biochem. 1979, 10, 471.
    • (1979) Int. J. Biochem. , vol.10 , pp. 471
    • Page, M.I.1
  • 39
    • 0042690904 scopus 로고    scopus 로고
    • With the possible exception of ref 8a,b,d
    • With the possible exception of ref 8a,b,d.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.