Metalloporphyrins as models for the cytochromes p-450

Coordination Chemistry Reviews

Volumn 108, Issue 2, 1991, Pages 115-161

  Gunter, Maxwell J ^a   Turner, Peter ^a  

^a UNIVERSITY OF NEW ENGLAND   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001322577     PISSN: 00108545     EISSN: None     Source Type: Journal    
DOI: 10.1016/0010-8545(91)84001-L     Document Type: Article

References (235)

1. Key elements of the chemistry of cytochrome P-450: The oxygen rebound mechanism
2. P450 Genes: Structure, Evolution, and Regulation
3. The electronic structure of chromyl chloride: a functional model for cytochrome P-450
4. The separation of the intramolecular isotope effect for the cytochrome P-450 catalyzed hydroxylation of n-octane into its primary and secondary components
5. Suicidal Destruction of Cytochrome P-450 During Oxidative Drug Metabolism
6. Spectroscopic models for cytochrome P-450 derivatives: hyperporphyrin spectra in thiolatoiron(III)?porphyrin complexes
7. Control of axial ligation in mercaptide-chelated porphyrins by conformational and environmental effects: synthetic compounds for cytochrome P-450
8. Unusually stable monothiolate and S/N, S/O mixed ligand complexes of iron(III) tetramesitylporphyrin
9. Organometallic aspects of cytochrome P-450 metabolism
10. Heme model studies related to cytochrome P-450 reactions: preparation of iron porphyrin complexes with carbenes bearing a .beta.-oxygen atom and their transformation into iron-N-alkylporphyrins and iron-metallacyclic complexes
11. Suicidal inactivation of iron-porphyrin catalysts during 1-alkene oxidation. Isolation of a new type of N-alkylporphyrin
12. Model systems for cytochrome P450 dependent mono-oxygenases. Part 1. Oxidation of alkenes and aromatic compounds by tetraphenylporphinatoiron(III) chloride and lodosylbenzene
13. Reaction of iron(III) porphyrins and iodosoxylene. The active oxene complex of cytochrome P-450
14. Iron(IV) porphyrins from iron(III) porphyrin cation radicals
15. NIH shift in haemin?iodosylbenzene-mediated hydroxylations
16. Structures of the ring-opened oxidation products from meso-tetraphenylporphyrin
17. Effect of fluorination of the meso-phenyl groups on selective tetraphenylporphyrinatoiron(III)-catalysed reactions of propane with molecular oxygen
18. Sterically protected hemins with electronegative substituents: efficient catalysts for hydroxylation and epoxidation
19. Asymmetric epoxidation of alkenes catalysed by a ?basket-handle? iron?porphyrin bearing amino acids
20. Sonochemical hot spot
21. Asymmetric hydroxylation by a chiral iron porphyrin
22. Use of the N-oxide of p-cyano-N,N-dimethylaniline as an "oxygen" donor in a cytochrome P-450 model system
23. Kinetics and mechanism of oxygen transfer in the reaction of p-cyano-N,N-dimethylaniline N-oxide with metalloporphyrin salts. 7. Oxygen atom transfer to and from [meso-tetrakis(pentafluorophenylporphinato]iron(III) chloride
24. Kinetics and mechanisms of oxygen transfer in the reaction of p-cyano-N,N-dimethylaniline N-oxide with metalloporphyrin salts. 2. Amine oxidation and oxygen transfer to hydrocarbon substrates accompanying the reaction of p-cyano-N,N-dimethylaniline N-oxide with meso-(tetraphenylporphinato)iron(III) chloride
25. Intermediates in the epoxidation of alkenes by cytochrome P-450 models. 5. Epoxidation of alkenes catalyzed by a sterically hindered (meso-tetrakis(2,6-dibromophenyl)porphinato)iron(III) chloride
26. Metalloporphyrin-Catalyzed Hydroxylation of Cyclohexane by Alkyl Hydroperoxides: Pronounced Efficiency of Iron-Porphyrins
27. Interaction of mono-oxygen donors with porphinatoiron(III)-complexes bearing electron-releasing meso-substituents
28. Kinetics and mechanisms of oxygen transfer in the reaction of p-cyano-N,N-dimethylaniline N-oxide with metalloporphyrin salts. 2. Amine oxidation and oxygen transfer to hydrocarbon substrates accompanying the reaction of p-cyano-N,N-dimethylaniline N-oxide with meso-(tetraphenylporphinato)iron(III) chloride
29. In the presence of imidazole, iron-and manganese-porphyrins catalyse the epoxidation of alkenes by alkyl hydroperoxides
30. Homolytic and heterolytic oxygen-oxygen bond scissions accompanying oxygen transfer to iron(III) porphyrins by percarboxylic acids and hydroperoxides. A mechanistic criterion for peroxidase and cytochrome P-450
31. The mechanism of oxidation of alkanes by peroxo complexes of iron porphyrins in the presence of acylating agents: a model for activation of O2 by cytochrome P-450
32. The mechanism of stereoselective epoxidation of alkenes by oxo-iron porphyrins
33. An intermediate-spin iron(III) porphyrin complex with a vinylidene group inserted into a iron-nitrogen bond: paramagnetic susceptibility, EPR, and Moessbauer properties
34. Photochemistry of (5,10,15,20-tetraphenylporphyrinato)iron(III) halide complexes, Fe(TPP)(X)
35. Iron meso-tetra(2,6-dichlorophenyl)porphyrin as a very efficient catalyst for the photoreduction of carbon tetrachloride by alcohols
36. Olefin epoxidation catalyzed by sterically bulky metalloporphyrins(metal=Fe,Mn) by use of sodium hypochlorite as an oxygen source. A kinetic study.
37. Oxidations catalyzed by stable metallo-tetraaryl porphyrins under aqueous-organic two-phase conditions
38. Steric and electron-withdrawing effects of substituents governing chemical stability and catalytic activity of Mn(III)-tetraarylporphyrins in HOCl/ClO− alkene expoxidations
39. Mono-oxigenase-like dioxygen activation leading to alkane hydroxylation and olefin epoxidation by an Mn III (porphyrin)?ascorbate biphasic system
40. Models for haemoglobin?myoglobin: studies with loosely and tightly strapped imidazole ligands
41. A very efficient alkene epoxidation by magnesium monoperoxyphthalate catalysed by manganese porphyrins
42. Monooxygenase-like oxidation of hydrocarbons by hydrogen peroxide catalyzed by manganese porphyrins and imidazole: selection of the best catalytic system and nature of the active oxygen species
43. Influence of the proximal ligand in the dismutation of hydrogen peroxide catalysed by manganese? and iron?porphyrin complexes
44. Mechanism of alkene epoxidation by a cytochrome P-450 model. Effect of additives
45. Synergistic effect of lipophilic carboxylic acids and heterocyclic axial ligands in alkene epoxidation by hydrogen peroxide catalysed by manganese(III) tetra-aryl porphyrins
46. Manganese "picnic basket" porphyrins: Cytochrome P-450 active site analogues.
47. Tosylamidation of cyclohexane by a cytochrome P-450 model
48. Metal complexes with tetrapyrrole ligands. 30. The manganese-nitrogen triple bond. Synthesis and molecular stereochemistry of (5,15-dimethyl-2,3,7,8,12,13,17,18-octaethyl-5H,15H-porphinato)nitridomanganese(V)
49. Preparation of an oxoporphyrinatomanganese(IV) complex
50. Syntheses, ground electronic state, and crystal and molecular structure of the monomeric manganese(VI) porphyrin complex dimethoxy(5,10,15,20-tetraphenylporphinato)manganese(IV)
51. Isolation, purification, and characterization of high-valent complexes from a manganese porphyrin based catalytic hydrocarbon activation system. Crystal and molecular structure of .mu.-oxo-bis[azido(tetraphenylporphinato)manganese(IV)]
52. Isolation, purification, and characterization of intermediate (iodosylbenzene)metalloporphyrin complexes from the (tetraphenylporphinato)manganese(III)-iodosylbenzene catalytic hydrocarbon functionalization system
53. Synthesis, characterization, and reaction chemistry of a bis(iodosylbenzene)metalloporphyrin complex, [PhI(OAc)O]2MnIVTPP. A complex possessing a five-electron oxidation capability
54. Hydrocarbon functionalization by the (iodosylbenzene)manganese(IV) porphyrin complexes from the (tetraphenylporphinato)manganese(III)-iodosylbenzene catalytic hydrocarbon oxidation system. Mechanism and reaction chemistry
55. Synthesis, structure, and superconductivity of single crystals of high-Tc La1.85Sr0.15CuO4, a lanthanum strontium copper oxide
56. Generation and characterization of highly reactive oxo-transfer intermediates and related species derived from (tetraarylporphinato)manganese(III) complexes
57. Chemistry of a high-oxidation-level manganese porphyrin in aqueous solution
58. Ab-initio calculations on oxomanganese porphyrin chloride. II. An explanation of its reactions with alkenes
59. Temperature-dependent valence isomerization in a manganese tetraphenylporphyrin
60. The contribution of tunnelling to high values of kinetic isotope effect in aliphatic hydroxylation by a cytochrome P-450 model