Charge-Transfer Processes in (4-Nitrobenzoate)Re(CO)3(azine)2 Complexes. Competitive Reductions of 4-Nitrobenzoate and Azine in Thermally and Photochemically Induced Redox Processes

Inorganic Chemistry

Volumn 37, Issue 11, 1998, Pages 2806-2810

  Feliz, M ^a   Ferraudi, G ^a  

^a UNIVERSITY OF NOTRE DAME   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001320098     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic971241j     Document Type: Article

References (20)

1. For a review of the subject prior to 1995. see: (a) Ferraudi, G.; Feliz, M.; Wolcan, E.; Hsu, I.; Moya, S. A. Guerrero, J. J. Phys. Chem. 1995, 99, 4929 and references therein, (b) Lees, A. J. J. Chem. Rev. 1987, 87, 711. (c) Geofrey, G. L.; Wrighton, M. S. Organometallic Photochemistry; Academic Press: New York, 1979.
2. For a review of the subject prior to 1995. see: (a) Ferraudi, G.; Feliz, M.; Wolcan, E.; Hsu, I.; Moya, S. A. Guerrero, J. J. Phys. Chem. 1995, 99, 4929 and references therein, (b) Lees, A. J. J. Chem. Rev. 1987, 87, 711. (c) Geofrey, G. L.; Wrighton, M. S. Organometallic Photochemistry; Academic Press: New York, 1979.
3. For a review of the subject prior to 1995. see: (a) Ferraudi, G.; Feliz, M.; Wolcan, E.; Hsu, I.; Moya, S. A. Guerrero, J. J. Phys. Chem. 1995, 99, 4929 and references therein, (b) Lees, A. J. J. Chem. Rev. 1987, 87, 711. (c) Geofrey, G. L.; Wrighton, M. S. Organometallic Photochemistry; Academic Press: New York, 1979.
4. Abbreviations: isoquinoline, isoq; quinoline, q; 1,10-phenanthroline, phen; pyridine, py; 4-phenylpyridine, 4-Phpy; 4-cyanopyridine, 4-C- Npy; ligand-to-ligand charge-transfer state, LLCT; ligand-to-metal charge-transfer state. LMCT; metal-to-ligand charge-transfer state, MLCT; ligand-centered state, IL; metal-centered (ligand field) state, LF.
5. (a) Feliz, M.; Ferraudi, G.; Altmiller, H. J. Phys. Chem. 1992, 96, 257.
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19. - can be expected at lower energies than the HOMO.
20. Murakami Iha, N.; Ferraudi, G. J. Chem. Soc., Dalton Trans 1994, 2565.