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Volumn 101, Issue 21, 1997, Pages 3910-3917

Phase-transfer model for the dynamics of "micellar autocatalysis"

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0001289591     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9705838     Document Type: Article
Times cited : (38)

References (36)
  • 16
    • 0029794937 scopus 로고    scopus 로고
    • Recently Coveney et al. reported in a purely theoretical paper the simulation of the biphasic hydrolysis of ethyl caprylate by the use of a lattice-gas automaton (Coveney, P. V.; Emerton, A. N.; Boghosian, B. M. J. Am. Chem. Soc. 1996, 118, 10719).
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 10719
    • Coveney, P.V.1    Emerton, A.N.2    Boghosian, B.M.3
  • 17
    • 85033321165 scopus 로고    scopus 로고
    • note
    • A similar model of a surface-controlled reaction has been recently proposed by Mavelli and Luisi for the kinetic description of "autopoietic self-reproduction of vesicles" in a biphasic system (ref 32).
  • 25
    • 85033323542 scopus 로고    scopus 로고
    • note
    • The reaction mixture becomes deeply turbid and gray just before becoming abruptly transparent when the reaction is finished. This observation can be interpreted by the proposed kinetic model as the formation of the micelle - EC complex (MEC); see also section IV.
  • 29
    • 85033324956 scopus 로고    scopus 로고
    • note
    • Experiments show that the influence of stirring affects the induction period but not the shape and the slope of the autocatalytic part of the kinetic curve.
  • 30
    • 85033309823 scopus 로고    scopus 로고
    • note
    • int. i.e., the back-reaction of step I, which is reasonable and which has been verified experimentally. We found that small amounts of sodium caprylate slow down significantly the phase separation of an aqueous/EC system. Nevertheless, the formation of [cover] does not change the capacity of the model to describe the experimentally observed kinetics of the overall system and does not improve the fitting of experimental data. For this reason this process has been omitted in Scheme 1.
  • 33
    • 0003587057 scopus 로고
    • Dunod: Paris, Chapter 4 (ISBN 2-04-0.15487-6)
    • Minoux, M. Programmation Mathématique. Tome 1; Dunod: Paris, 1983; Chapter 4 (ISBN 2-04-0.15487-6).
    • (1983) Programmation Mathématique , vol.1
    • Minoux, M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.