A Novel Bis(azatitanatrane) with a T-Shaped Nitrido Bridging Ligand: Synthesis and Structure of {[N(CH2CH2N-i-Pr)3Ti]2(μ 3-N)Na(THF)}

Inorganic Chemistry

Volumn 35, Issue 18, 1996, Pages 5325-5327

  Duan, Zhibang ^a,b   Verkade, John G ^a  

^a IOWA STATE UNIVERSITY   (United States)

^b YTC America Inc   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001288160     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9606385     Document Type: Article

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39. 2. To these reactants was added 50 mL of THF under argon, and the reaction mixture was refluxed for 134 h. After the reaction was cooled, the volatile components were remove in vacuo and the residue was extracted with copious amounts of pentane. The extract was concentrated to about 5 mL and kept in a freezer for 1 day, which allowed red-orange crystals for form. After filtration at -50 °C and washing with cold pentane, 0.36 g of crystalline 1 was obtained in 46% yield.
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