Borole derivatives. 23. Reversible carbonylation and Lewis base degradation of the heterocubane [Rh(μ3-I)(C4H4BPh)]4 and of the bis(borole) complex RhI(C4H4BPh)2 and synthesis and structure of the dinuclear complex Cp*Rh(μ-I)3Rh(C4H4BPh)1

Organometallics

Volumn 16, Issue 22, 1997, Pages 4800-4806

  Herberich, Gerhard E ^a   Eckenrath, Hartmut J ^a   Englert, Ulli ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001277960     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9704410     Document Type: Article

References (27)

1. Part 22: See ref 2.
2. Herberich, G. E.; Eckenrath, H. J.; Englert, U. Organometallics 1997, 16, 4292.
3. Eckenrath, H. J. Doctoral Dissertation, Technische Hochschule Aachen, Aachen, Germany, 1997.
4. (a) Herberich, G. E.; Hessner, B.; Boveleth, W.; Lüthe, H.; Saive, R.; Zelenka, L. Angew. Chem., Int. Ed. Engl. 1983, 22, 996; Angew. Chem. Suppl. 1983, 1503.
5. (a) Herberich, G. E.; Hessner, B.; Boveleth, W.; Lüthe, H.; Saive, R.; Zelenka, L. Angew. Chem., Int. Ed. Engl. 1983, 22, 996; Angew. Chem. Suppl. 1983, 1503.
6. (b) Herberich, G. E.; Büschges, U.; Hessner, B.; Lüthe, H. J. Organomet. Chem. 1986, 312, 13.
7. s symmetry is shown.
8. Herberich, G. E.; Boveleth, W.; Hessner, B.; Hostalek, M.; Köffer, D. P. J.; Negele, M. J. Organomet. Chem. 1987, 319, 311.
9. (a) Eisch, J. J.; Hota, N. K.; Kozima, S. J. Am. Chem. Soc. 1969, 91, 4575.
10. (b) Grisdale, P. J.; Walters, J. L. R. J. Organomet. Chem. 1970, 22, C19.
11. Herberich, G. E.; Negele, M. J. Organomet. Chem. 1988, 350, 81.
12. Herberich, G. E.; Hessner, B.; Saive, R. J. Organomet. Chem. 1987, 319, 9.
13. c > 20 °C.
14. Gan, K.-S.; Hor, T. S. A. 1,1′-Bis(diphenylphosphino)ferrocene-Coordination Chemistry, Organic Syntheses, and Catalysis; In Ferrocenes; Togni, A., Hayashi, T., Eds.; VCH: Weinheim, Germany, 1995.
15. Volger, H. C.; Gaasbeek, M. M. P.; Hogeveen, H.; Vrieze, K. Inorg. Chim. Acta 1969, 3, 145.
16. Kang, J. W.; Moseley, K.; Maitlis, P. M. J. Am. Chem. Soc. 1969, 91, 5970.
17. (b) Booth, B. L.; Hazeldine, R. N.; Hill, M. J. Chem. Soc. A 1969, 1299.
18. Spek, A. L. Acta Crystallogr. 1990, A46, C34.
19. Orpen, A. G.; Brammer, L.; Allen, F. H.; Kennard, O.; Watson, D. G.; Taylor, R. J. Chem. Soc., Dalton Trans. 1989, S1.
20. 4B best plane.
21. (a) Herberich, G. E.; Negele, M.; Ohst, H. Chem. Ber. 1991, 124, 25.
22. (b) Herberich, G. E.; Englert, U.; Hostalek, M.; Laven, R. Chem. Ber. 1991, 124, 17.
23. Herberich, G. E.; Eckenrath, H. J.; Englert, U. Manuscript in preparation.
24. North, A. C. T.; Phillips, D. C.; Mathews, F. S. Acta Crystallogr. 1968, A24, 351.
25. Sheldrick, G. M. SHELXS-86, Program for Crystal Structure Solution; University of Göttingen: Göttingen, Germany, 1986.
26. Frenz, B. A. ENRAF-Nonius SDP Version 5.0; ENRAF-Nonius: Delft, The Netherlands, 1989, and local programs.
27. Further details of the crystal structure investigation are available on request from the Fachinformationszentrum Karlsruhe, Gesellschaft für wissenschaftlich-technische Information mbH, D-76344 Eggenstein-Leopoldshafen, Germany, on quoting the depository number CSD-407353 for 15, the names of the authors, and this journal citation.