Isomerism of amides coordinated to platinum - X-ray crystal structure of O-bonded acetamide in a platinum(II) complex

European Journal of Inorganic Chemistry

Volumn , Issue 9, 1998, Pages 1305-1312

  Cini, Renzo ^a   Intini, Francesco P ^b   Maresca, Luciana ^b   Pacifico, Concetta ^b   Natile, Giovanni ^b  

^a UNIVERSITY OF SIENA   (Italy)

^b UNIVERSITY OF BARI   (Italy)

Author keywords

Atropisomers; O coordinated amides; O to N isomerization; Platinum

Indexed keywords

ACETONE; COORDINATION REACTIONS; CRYSTAL STRUCTURE; INDIUM COMPOUNDS; ISOMERIZATION; ISOMERS; PLATINUM COMPOUNDS; PROTONATION; RATE CONSTANTS; SOLVENTS; STEREOCHEMISTRY; X RAY DIFFRACTION;

ACETONE SOLUTION; AMIDATE; AMIDE COMPLEXES; ATROPISOMERS; ISOMERISATION; O-COORDINATED AMIDE; O-TO-N ISOMERIZATION; PYRIDONES; SOLVOLYSES; X RAY CRYSTAL STRUCTURES;

AMIDES;

EID: 0001276172     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0682(199809)1998:9<1305::AID-EJIC1305>3.0.CO;2-9     Document Type: Article

References (38)

1. H. Sigel, R. B. Martin, Chem. Rev 1982, 82, 385.
2. D. P. Fairlie, H. Taube, Inorg. Chem. 1985, 24, 3199.
3. R. L. Angel, D. P. Fairlie, W. G. Jackson, Inorg. Chem. 1990, 29, 20.
4. N. J. Curtis, G. A. Lawrence, A. M. Sargeson, Aust. J. Chem. 1983, 36, 1495.
5. D. P. Fairlie, Y. Ilan, H. Taube, Inorg. Chem. 1997, 38, 1029.
6. N. J. Curtis, N. E. Dixon, A. M. Sargeson, J. Am. Chem. Soc. 1983, 105, 5347.
7. F. R. Hartley, The Chemistry of Platinum and Palladium, Applied Sciences Publishers, London, New York, 1973.
8. Our considerations will be restricted to monodentate amides and will not include bridging amide complexes for which the reader may refer to the following papers: J. K. Barton, H. N. Rabinowitz, D. J. Szulda, S. J. Lippard, J. Am. Chem. Soc. 1977, 99, 2827. - T. V. O'Halloran, P. K. Masharak, I. D. Williams, M. M. Roberts, S. J. Lippard, Inorg. Chem. 1987, 26, 1261. -F. D. Rochon, P. C. Kong, R. Melanson, Inorg. Chem. 1990, 29, 1352 . B. Lippert, Prog. Inorg. Chem. 1989, 37, 1.
9. Our considerations will be restricted to monodentate amides and will not include bridging amide complexes for which the reader may refer to the following papers: J. K. Barton, H. N. Rabinowitz, D. J. Szulda, S. J. Lippard, J. Am. Chem. Soc. 1977, 99, 2827. - T. V. O'Halloran, P. K. Masharak, I. D. Williams, M. M. Roberts, S. J. Lippard, Inorg. Chem. 1987, 26, 1261. -F. D. Rochon, P. C. Kong, R. Melanson, Inorg. Chem. 1990, 29, 1352 . B. Lippert, Prog. Inorg. Chem. 1989, 37, 1.
10. Our considerations will be restricted to monodentate amides and will not include bridging amide complexes for which the reader may refer to the following papers: J. K. Barton, H. N. Rabinowitz, D. J. Szulda, S. J. Lippard, J. Am. Chem. Soc. 1977, 99, 2827. - T. V. O'Halloran, P. K. Masharak, I. D. Williams, M. M. Roberts, S. J. Lippard, Inorg. Chem. 1987, 26, 1261. -F. D. Rochon, P. C. Kong, R. Melanson, Inorg. Chem. 1990, 29, 1352 . B. Lippert, Prog. Inorg. Chem. 1989, 37, 1.
11. Our considerations will be restricted to monodentate amides and will not include bridging amide complexes for which the reader may refer to the following papers: J. K. Barton, H. N. Rabinowitz, D. J. Szulda, S. J. Lippard, J. Am. Chem. Soc. 1977, 99, 2827. - T. V. O'Halloran, P. K. Masharak, I. D. Williams, M. M. Roberts, S. J. Lippard, Inorg. Chem. 1987, 26, 1261. -F. D. Rochon, P. C. Kong, R. Melanson, Inorg. Chem. 1990, 29, 1352 . B. Lippert, Prog. Inorg. Chem. 1989, 37, 1.
12. D. B. Brown, M. B. Robin, R. D. Burbank, J. Am. Chem. Soc. 1968, 90, 5621. - D. B. Brown, R. D. Burbank, M. B. Robin, J. Am. Chem. Soc. 1969, 91, 2895.
13. D. B. Brown, M. B. Robin, R. D. Burbank, J. Am. Chem. Soc. 1968, 90, 5621. - D. B. Brown, R. D. Burbank, M. B. Robin, J. Am. Chem. Soc. 1969, 91, 2895.
14. R. Cini, F. P. Fanizzi, F. P. Intini, G. Natile, J. Am. Chem. Soc. 1991, 113, 7805.
15. R. Cini, F. P. Fanizzi, F. P. Intini, G. Natile, J. Am. Chem Soc. 1993, 115, 5123.
16. R. Cini, F. P. Intini, G. Natile, C. Pacifico, J. Chem. Soc., Dalton Trans. 1994, 3753.
17. R. Cini, F. P. Fanizzi, F. P. Intini, G. Natile, C. Pacifico. Inorg. Chim. Acta 1996, 251, 111.
18. R. Cini, F. P. Fanizzi, F. P. Intini, C. Pacifico, G. Natile, Inorg. Chim. Acta 1997, 264, 279.
19. A. Erxleben, I. Mutikainen, B. Lippert, J. Chem. Soc., Dalton Trans. 1994, 3667.
20. J. Zabicky, The Chemistry of Amides, J. Wiley-Interscience, New York, 1970, chapter 1, p. 1.
21. J. S. Kerrison, P. J. Sadler, J. Chem. Soc., Chem. Commun. 1981, 61.
22. T. C. Woon, D. P. Fairlie, Inorg. Chem. 1992, 31, 4069.
23. T. P. Pitner, R. B. Martin, J. Am Chem. Soc. 1971, 93, 4400.
24. S.-H. Kim, R. B. Martin, Inorg. Chim. Acta 1984, 91, 11.
25. W. H. Baddley, F. Basolo, J. Am. Chem. Soc. 1966, 88, 2944.
26. B. A. Markies, P. Wijkens, J. Boersma, H. Kooijman, N. Veldman, A. L. Spak, G. van Koten, Organometallics 1994, 13, 3244.
27. B. A. Markies, P. Wijkens, H. Kooijman, A. L. Spek, J. Boersma, G. van Koten, J. Chem. Soc. Chem. Commun 1992, 1420.
28. L. S. Hollis, S. J. Lippard, Inorg. Chem. 1983, 22, 2600.
29. L. S. Hollis, S. J. Lippard, J. Am. Chem. Soc. 1983, 105, 3494.
30. M. E. Stone, B. E. Robertson, E. Stanley, J Chem. Soc A 1971, 3632.
31. F. H. Allen, O. Kennard, D. G. Watson, L. Brammer, G. Orpen, R. Taylor, J. Chem. Soc., Perkin Trans. 2 1987, S1.
32. A. Bondi, J. Phys Chem. 1964, 68, 441.
33. F. P. Intini, C. Pacifico, G. Natile, unpublished results.
34. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Center as supplementary publication no. CCDC-101247. Copies of the data may be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK [fax: (internat.) + 44(0)1223/336033; e-mail: deposit@ccdc.cam.ac.uk].
35. N. Walker, D. Stuart, "DIFABS", Acta Crystallogr., Sect A. 1983, 39, 158.
36. G. M. Sheldrick, SHELXS-86, University of Göttingen, 1986.
37. G. M. Sheldrick, SHELXL-93, University of Göttingen, 1993.
38. M. Nardelli, PARST 97, University of Parma, 1996.